Platinum Nickel Nanowires as Methanol Oxidation Electrocatalysts

Alia, Shaun M.; Pylypenko, Svitlana; Neyerlin, Kenneth C.; Kocha, Shyam S.; Pivovar, Bryan S.

doi:10.1149/2.0231512jes

Title: Platinum Nickel Nanowires as Methanol Oxidation Electrocatalysts

Journal Article · Thu Aug 27 00:00:00 EDT 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0231512jes· OSTI ID:1225971

Alia, Shaun M. ^[1]; Pylypenko, Svitlana ^[2]; Neyerlin, Kenneth C. ^[1]; Kocha, Shyam S. ^[1]; Pivovar, Bryan S. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)
Colorado School of Mines, Golden, CO (United States)

We investigated platinum(Pt) nickel (Ni) nanowires (PtNiNWs) as methanol oxidation reaction (MOR) catalysts in rotating disk electrode (RDE) half-cells under acidic conditions. Pt-ruthenium (Ru) nanoparticles have long been the state of the art MOR catalyst for direct methanol fuel cells (DMFCs) where Ru provides oxophilic sites, lowering the potential for carbon monoxide oxidation and the MOR onset. Ru, however, is a precious metal that has long term durability concerns. Ni/Ni oxide species offer a potential to replace Ru in MOR electrocatalysis. PtNiNWs were investigated for MOR and oxygen annealing was investigated as a route to improve catalyst performance (mass activity 65% greater) and stability to potential cycling. Our results presented show that PtNiNWs offer significant promise in the area, but also result in Ni ion leaching that is a concern requiring further evaluation in fuel cells.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1225971

Report Number(s):: NREL/JA-5900-65338

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 12; Related Information: Journal of the Electrochemical Society; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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Catalytic activities for methanol oxidation on ultrathin CuPt ₃ wavy nanowires with/without smart polymer Fu, Gengtao; Yan, Xiaoxiao; Cui, Zhiming Chemical Science, Vol. 7, Issue 8 https://doi.org/10.1039/c6sc01501h	journal	January 2016
TePbPt alloy nanotube as electrocatalyst with enhanced performance towards methanol oxidation reaction Yang, Long; Li, Guoqiang; Ge, Junjie Journal of Materials Chemistry A, Vol. 6, Issue 35 https://doi.org/10.1039/c8ta04132f	journal	January 2018
Synthesis of Pt@TiO ₂ nanocomposite electrocatalysts for enhanced methanol oxidation by hydrophobic nanoreactor templating Unmüssig, Tobias; Melke, Julia; Fischer, Anna Physical Chemistry Chemical Physics, Vol. 21, Issue 25 https://doi.org/10.1039/c9cp00502a	journal	January 2019

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