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Title: EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

Technical Report ·
DOI:https://doi.org/10.2172/1225362· OSTI ID:1225362

EOS7CA is a TOUGH2 module for mixtures of a non-condensible gas (NCG) and air with or without a gas tracer, an aqueous phase, and water vapor. The user can select the NCG as being CO2, N2, or CH4. EOS7CA uses a cubic equation of state with a multiphase version of Darcy’s Law to model flow and transport of gas and aqueous phase mixtures over a range of pressures and temperatures appropriate to shallow subsurface porous media systems. The limitation to shallow systems arises from the use of Henry’s Law for gas solubility which is appropriate for low pressures but begins to over-predict solubility starting at pressures greater than approximately 1 MPa (10 bar). The components modeled in EOS7CA are water, brine, NCG, gas tracer, air, and optional heat. The real gas properties module (ZEVCA) has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. This user guide provides instructions for use and two sample problems as verification and demonstration of EOS7CA.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1225362
Report Number(s):
LBNL-175204; ir:175204
Country of Publication:
United States
Language:
English