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Title: Molecular Chromophore–Catalyst Assemblies for Solar Fuel Applications

Journal Article · · Chemical Reviews
 [1];  [1];  [2];  [1];  [1];  [1];  [1]
  1. Department of Chemistry, University of North Carolina at Chapel Hill, CB 3290, Chapel Hill, North Carolina 27599, United States
  2. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, United States

As the world’s population increases, the U.S. Department of Energy has estimated that energy consumption will increase with it, increasing from 5.7 × 1020 J in 2012 to 8.1 × 1020 J in 2040. This projection takes into account population growth, average gross domestic product per capita, and globally averaged energy intensity. At the same time, there is an increased understanding of the importance of integrating good environmental practices with stimulating economic growth and leadership provided by international organizations, such as the Organization for Economic Cooperation and Development. Most of the increases in energy consumption will come from emerging economies in Asia, Africa, and South America where goals, priorities, and challenges are diverse. To meet these demands there is a need to develop alternate energy sources. Although renewable and nuclear energy are growing by 2.5% a year, fossil fuels are still projected to make up at least 80% of the global energy supply in 2040.

Research Organization:
University of North Carolina, Chapel Hill, NC (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001011
OSTI ID:
1224664
Alternate ID(s):
OSTI ID: 1386778
Journal Information:
Chemical Reviews, Journal Name: Chemical Reviews Vol. 115 Journal Issue: 23; ISSN 0009-2665
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 367 works
Citation information provided by
Web of Science

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Alternative energy technologies journal November 2001
Thermal electron transfer reactions in polar solvents journal October 1974
Visible Light-Driven Water Splitting in Photoelectrochemical Cells with Supramolecular Catalysts on Photoanodes journal May 2014
Solar Water Splitting Cells journal November 2010
Medium Dependence of Intramolecular Vibrational Modes Coupled to MLCT Transitions in Metal Polypyridyl Complexes journal May 2002
Improving Photosynthetic Efficiency for Greater Yield journal June 2010
Photoinduced Ultrafast Dynamics of Coumarin 343 Sensitized p-Type-Nanostructured NiO Films journal October 2005
Strategies for the Development of Visible-light-driven Photocatalysts for Water Splitting journal December 2004
Diffusion-Limited Interfacial Electron Transfer with Large Apparent Driving Forces journal September 1999
Dye Stabilization and Enhanced Photoelectrode Wettability in Water-Based Dye-Sensitized Solar Cells through Post-assembly Atomic Layer Deposition of TiO 2 journal July 2013
Rate Constants for Charge Injection from Excited Sensitizer into SnO2, ZnO, and TiO2 Semiconductor Nanocrystallites journal August 1995
Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices journal January 2013
Revealing the Relationship between Semiconductor Electronic Structure and Electron Transfer Dynamics at Metal Oxide–Chromophore Interfaces journal November 2013
Improved Photon-to-Current Conversion Efficiency with a Nanoporous p-Type NiO Electrode by the Use of a Sensitizer-Acceptor Dyad journal February 2008
Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation journal July 2009
Biomolecule immobilization on electrode surfaces by entrapment or attachment to electrochemically polymerized films. A review journal May 1999
Nanostructured electrocatalysts immobilised on electrode surfaces and organic film templates journal January 2012
Making Oxygen with Ruthenium Complexes journal December 2009
Interfacial Energy Conversion in Ru II Polypyridyl-Derivatized Oligoproline Assemblies on TiO 2 journal March 2013
Cobalt Polypyridyl-Based Electrolytes for p-Type Dye-Sensitized Solar Cells journal April 2011
Selective CO 2 Conversion to Formate Conjugated with H 2 O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts journal October 2011
A Monolithic Photovoltaic-Photoelectrochemical Device for Hydrogen Production via Water Splitting journal April 1998
Spectroscopy and Dynamics of Phosphonate-Derivatized Ruthenium Complexes on TiO 2 journal January 2013
Photochemical Conversion of Solar Energy journal February 2008
Transient Absorption Studies of the Primary Charge Separation in Photosystem II journal January 1996
Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II journal March 2008
Excited-State Electron Transfer from Ruthenium-Polypyridyl Compounds to Anatase TiO 2 Nanocrystallites: Evidence for a Stark Effect journal November 2010
Water Splitting on Composite Plasmonic-Metal/Semiconductor Photoelectrodes: Evidence for Selective Plasmon-Induced Formation of Charge Carriers near the Semiconductor Surface journal April 2011
Accumulation of Multiple Oxidative Equivalents at a Single Site by Cross-Surface Electron Transfer on TiO 2 journal July 2013
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting journal January 2013
Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst journal March 2010
ZnO-Based Dye-Sensitized Solar Cells journal April 2012
Homogeneous water oxidation catalysts containing a single metal site journal January 2013
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation journal October 2014
Nonaqueous Catalytic Water Oxidation journal December 2010
Recent developments in solar water-splitting photocatalysis journal January 2011
Charge Transport versus Recombination in Dye-Sensitized Solar Cells Employing Nanocrystalline TiO 2 and SnO 2 Films journal June 2005
Engine of Life and Big Bang of Evolution: A Personal Perspective journal January 2004
Improved Utilization of Photogenerated Charge Using Fluorine-Doped TiO 2 Hollow Spheres Scattering Layer in Dye-Sensitized Solar Cells journal June 2012
Z-scheme photocatalyst systems for water splitting under visible light irradiation journal January 2011
Mechanism of Charge Recombination in Dye-Sensitized Nanocrystalline Semiconductors:  Random Flight Model April 2002
Molecular water oxidation catalysts based on transition metals and their decomposition pathways journal August 2012
Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO 2 and TiO 2 Nanoparticles journal October 2013
Chemical and Spectroscopic Evidence for an FeV-Oxo Complex journal February 2007
Efficient Electro-Oxidation of Water near Its Reversible Potential by a Mesoporous IrO x Nanoparticle Film journal July 2009
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å journal April 2011
The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay journal January 2012
Using Surface-Attached Organosilanes to Control and Understand Hydrophobicity and Superhydrophobicity book January 2012
Molecular Catalytic Assemblies for Electrodriven Water Splitting journal December 2012
Reduction of Charge Recombination by an Amorphous Titanium Oxide Interlayer in Layered Graphene/Quantum Dots Photochemical Cells journal May 2011
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis journal June 2010
Ultrafast Electron Transfer Dynamics from Molecular Adsorbates to Semiconductor Nanocrystalline Thin Films journal May 2001
Catalytic water oxidation at single metal sites journal January 2012
Particle size dependence of oxygen evolution reaction on nanocrystalline RuO2 and Ru0.8Co0.2O2−x journal September 2006
High-Throughput Bubble Screening Method for Combinatorial Discovery of Electrocatalysts for Water Splitting journal January 2014
Interfacial Electron Transfer Dynamics Following Laser Flash Photolysis of [Ru(bpy)2((4,4′-PO3H2)2bpy)]2+ in TiO2 Nanoparticle Films in Aqueous Environments journal February 2011
Photophysical Characterization of a Chromophore/Water Oxidation Catalyst Containing a Layer-by-Layer Assembly on Nanocrystalline TiO 2 Using Ultrafast Spectroscopy journal May 2014
Solar Fuels via Artificial Photosynthesis journal December 2009
Electrochemical Instability of Phosphonate-Derivatized, Ruthenium(III) Polypyridyl Complexes on Metal Oxide Surfaces journal May 2015
Watching Photoactivation in a Ru(II) Chromophore–Catalyst Assembly on TiO 2 by Ultrafast Spectroscopy journal November 2013
Synchronously Reduced Surface States, Charge Recombination, and Light Absorption Length for High-Performance Organic Dye-Sensitized Solar Cells journal April 2010
Molecular water-oxidation catalysts for photoelectrochemical cells journal January 2009
Oxygen evolution at RuO2(x)+Co3O4(1−x) electrodes from acid solution journal February 2001
Bound exciton and donor–acceptor pair recombinations in ZnO journal February 2004
All-solid-state Z-scheme in CdS–Au–TiO2 three-component nanojunction system journal September 2006
Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function journal January 1970
Stable Carbon Cycle-Climate Relationship During the Late Pleistocene journal November 2005
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries journal January 2013
Climate and atmospheric history of the past 420,000 years from the Vostok ice core, Antarctica journal June 1999
Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective journal April 2012
Catalytic water oxidation on derivatized nanoITO journal January 2010
Molecular Control of Recombination Dynamics in Dye-Sensitized Nanocrystalline TiO 2 Films:  Free Energy vs Distance Dependence journal April 2004
Impact of Ligand Exchange in Hydrogen Production from Cobaloxime-Containing Photocatalytic Systems journal November 2011
Economic and environmental choices in the stabilization of atmospheric CO2 concentrations journal January 1996
The role of proton coupled electron transfer in water oxidation journal January 2012
Estimation of excited-state redox potentials by electron-transfer quenching. Application of electron-transfer theory to excited-state redox processes journal August 1979
A photoelectrochemical device for visible light driven water splitting by a molecular ruthenium catalyst assembled on dye-sensitized nanostructured TiO2 journal January 2010
Electron Transfer Dynamics in Semiconductor–Chromophore–Polyoxometalate Catalyst Photoanodes journal January 2013
A soluble copper–bipyridine water-oxidation electrocatalyst journal May 2012
Molecular Catalysts for Water Oxidation journal January 2001
Visible Light Driven Water Splitting in a Molecular Device with Unprecedentedly High Photocurrent Density journal March 2013
Proton-Coupled Electron Transfer journal October 1998
Compositional engineering of perovskite materials for high-performance solar cells journal January 2015
One-Electron Activation of Water Oxidation Catalysis journal May 2014
Light-driven water oxidation for solar fuels journal November 2012
Lighting porphyrins and phthalocyanines for molecular photovoltaics journal January 2010
Low-Overpotential Water Oxidation by a Surface-Bound Ruthenium-Chromophore-Ruthenium-Catalyst Assembly journal November 2013
Photodriven heterogeneous charge transfer with transition-metal compounds anchored to TiO 2 semiconductor surfaces journal January 2009
Identification of the Different Mechanisms of Activation of a [Ru II (tpy)(bpy)(OH 2 )] 2+ Catalyst by Modified Ruthenium Sensitizers in Supramolecular Complexes journal May 2013
Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation journal December 2008
Varying the Electronic Structure of Surface-Bound Ruthenium(II) Polypyridyl Complexes journal December 2014
Stabilization of a Ruthenium(II) Polypyridyl Dye on Nanocrystalline TiO 2 by an Electropolymerized Overlayer journal October 2013
Inorganic Materials as Catalysts for Photochemical Splitting of Water journal January 2008
Surface Modification of SnO 2 Photoelectrodes in Dye-Sensitized Solar Cells: Significant Improvements in Photovoltage via Al 2 O 3 Atomic Layer Deposition journal April 2010
Effect of Anchoring Group on Electron Injection and Recombination Dynamics in Organic Dye-Sensitized Solar Cells journal February 2009
Water-Splitting Catalysis and Solar Fuel Devices: Artificial Leaves on the Move journal August 2013
Synthesis, Photophysics, and Electrochemistry of Ruthenium(II) Polypyridine Complexes with Crown Ether Pendants journal May 1997
Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts journal January 2012
A New Family of Ru Complexes for Water Oxidation journal September 2005
Oil's tipping point has passed journal January 2012
High-Temperature Anodized WO 3 Nanoplatelet Films for Photosensitive Devices journal July 2009
Driving Force Dependent, Photoinduced Electron Transfer at Degenerately Doped, Optically Transparent Semiconductor Nanoparticle Interfaces journal November 2014
Concerted O atom-proton transfer in the O--O bond forming step in water oxidation journal April 2010
An adaptive junction journal December 2013
Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications journal February 2010
Heterojunction BiVO4/WO3 electrodes for enhanced photoactivity of water oxidation journal January 2011
Dynamics of Electron Injection and Recombination of Dye-Sensitized TiO 2 Particles journal December 1998
Evidence Against the Hopping Mechanism as an Important Electron Transfer Pathway for Conformationally Constrained Oligopeptides journal January 2005
Spectral Characteristics of Light Harvesting, Electron Injection, and Steady-State Charge Collection in Pressed TiO 2 Dye Solar Cells journal March 2008
Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex journal January 2011
Tris (2,2'-bipyridine)ruthenium(II) sensitized reactions of some oxalato complexes journal August 1973
Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes journal January 2013
Activation Energy of Electron Transport in Dye-Sensitized TiO 2 Solar Cells journal June 2005
The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II journal July 2007
Transparent conducting materials: overview and recent results conference October 2012
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement journal May 2011
Electron transfer dynamics of peptide-derivatized Ru II -polypyridyl complexes on nanocrystalline metal oxide films journal January 2013
A Sensitized Nb 2 O 5 Photoanode for Hydrogen Production in a Dye-Sensitized Photoelectrosynthesis Cell journal December 2012
Photostability of Phosphonate-Derivatized, Ru II Polypyridyl Complexes on Metal Oxide Surfaces journal February 2012
Injection and Ultrafast Regeneration in Dye-Sensitized Solar Cells journal April 2014
Artificial Photosynthesis: From Nanosecond Electron Transfer to Catalytic Water Oxidation journal August 2013
Photoassisted Overall Water Splitting in a Visible Light-Absorbing Dye-Sensitized Photoelectrochemical Cell
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Insights into Ru-Based Molecular Water Oxidation Catalysts: Electronic and Noncovalent-Interaction Effects on Their Catalytic Activities journal June 2013
Artificial photosynthesis. 1. Photosensitization of titania solar cells with chlorophyll derivatives and related natural porphyrins journal June 1993
Slow Electron Injection on Ru−Phthalocyanine Sensitized TiO 2
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Tuning of spacer groups in organic dyes for efficient inhibition of charge recombination in dye-sensitized solar cells journal October 2012
Crossing the divide between homogeneous and heterogeneous catalysis in water oxidation journal November 2013
Hopping Transport of Electrons in Dye-Sensitized Solar Cells journal October 2007
Combinatorial Search for Improved Metal Oxide Oxygen Evolution Electrocatalysts in Acidic Electrolytes journal January 2013
Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues journal October 1982
Exited state electron and energy transfer in molecular assemblies journal February 2005
Injection Limitations in a Series of Porphyrin Dye-Sensitized Solar Cells journal January 2010
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II journal March 2012
Synthesis and Electrocatalytic Water Oxidation by Electrode-Bound Helical Peptide Chromophore–Catalyst Assemblies journal July 2014
Subpicosecond Interfacial Charge Separation in Dye-Sensitized Nanocrystalline Titanium Dioxide Films journal January 1996
Mimicking Photosynthetic Solar Energy Transduction journal January 2001
Theoretical Insights into Photoinduced Charge Transfer and Catalysis at Oxide Interfaces journal December 2012
Femtosecond Transient Absorption of Zinc Porphyrins with Oligo(phenylethylnyl) Linkers in Solution and on TiO 2 Films journal March 2009
Insight into Water Oxidation by Mononuclear Polypyridyl Ru Catalysts journal March 2010
Design, Synthesis, and Application of Amphiphilic Ruthenium Polypyridyl Photosensitizers in Solar Cells Based on Nanocrystalline TiO 2 Films journal February 2002

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