Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation

Zhu, Jing; Zheng, Xin; Wang, Jie; Wu, Zexing; Han, Lili; Lin, Ruoqian; Xin, Huolin L.; Wang, Deli

doi:10.1039/C5TA05699C

Title: Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation

Journal Article · Tue Sep 15 00:00:00 EDT 2015 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C5TA05699C· OSTI ID:1222622

Zhu, Jing ^[1]; Zheng, Xin ^[1]; Wang, Jie ^[1]; Wu, Zexing ^[1]; Han, Lili ^[2]; Lin, Ruoqian ^[2]; Xin, Huolin L. ^[3]; Wang, Deli ^[1]

Huazhong Univ. of Science and Technology, Wuhan (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)

Controlling the size, composition, and structure of bimetallic nanoparticles is of particular interest in the field of electrocatalysts for fuel cells. In the present work, structurally ordered nanoparticles with intermetallic phases of Pt₃Zn and PtZn have been successfully synthesized via an impregnation reduction method, followed by post heat-treatment. The Pt₃Zn and PtZn ordered intermetallic nanoparticles are well dispersed on a carbon support with ultrasmall mean particle sizes of ~5 nm and ~3 nm in diameter, respectively, which are credited to the evaporation of the zinc element at high temperature. These catalysts are less susceptible to CO poisoning relative to Pt/C and exhibited enhanced catalytic activity and stability toward formic acid electrooxidation. The mass activities of the as-prepared catalysts were approximately 2 to 3 times that of commercial Pt at 0.5 V (vs. RHE). As a result, this facile synthetic strategy is scalable for mass production of catalytic materials.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: 21306060

OSTI ID:: 1222622

Report Number(s):: BNL-108453-2015-JA; JMCAET; KC0403020

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 47 works

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Title: Structurally ordered Pt–Zn/C series nanoparticles as efficient anode catalysts for formic acid electrooxidation

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