skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Colloidal nanocrystals and method of making

Patent ·
OSTI ID:1222597

A tight confinement nanocrystal comprises a homogeneous center region having a first composition and a smoothly varying region having a second composition wherein a confining potential barrier monotonically increases and then monotonically decreases as the smoothly varying region extends from the surface of the homogeneous center region to an outer surface of the nanocrystal. A method of producing the nanocrystal comprises forming a first solution by combining a solvent and at most two nanocrystal precursors; heating the first solution to a nucleation temperature; adding to the first solution, a second solution having a solvent, at least one additional and different precursor to form the homogeneous center region and at most an initial portion of the smoothly varying region; and lowering the solution temperature to a growth temperature to complete growth of the smoothly varying region.

Research Organization:
The Research Foundation for the State University of New York, Amherst, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0000979
Assignee:
The Research Foundation for the State University of New York (Amherst, NY)
Patent Number(s):
9,153,731
Application Number:
14/454,293
OSTI ID:
1222597
Resource Relation:
Patent File Date: 2014 Aug 07
Country of Publication:
United States
Language:
English

References (22)

Highly luminescent color-selective nano-crystalline materials patent November 2001
Alloyed semiconductor quantum dots and concentration-gradient alloyed quantum dots, series comprising the same and methods related thereto patent April 2013
Method of making highly-confined semiconductor nanocrystals patent July 2014
Quantum Dots Having Composition Gradient Shell Structure and Manufacturing Method Thereof patent-application June 2010
Electron–vibration coupling in semiconductor clusters studied by resonance Raman spectroscopy journal April 1989
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies journal August 2000
Electrophilicity Index journal March 1999
Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals journal January 1996
Formation of High Quality InP and InAs Nanocrystals in a Noncoordinating Solvent journal September 2002
Accurate ab initio predictions of III–V direct-indirect band gap crossovers journal August 2010
Synthesis Routes for Large Volumes of Nanoparticles journal August 2004
Step-Wise Synthesis of InP/ZnS Core−Shell Quantum Dots and the Role of Zinc Acetate journal February 2009
Efficient and Color-Tunable Mn-Doped ZnSe Nanocrystal Emitters:  Control of Optical Performance via Greener Synthetic Chemistry journal March 2007
Improved Precursor Chemistry for the Synthesis of III–V Quantum Dots journal December 2012
Highly Luminescent CdTe/CdSe Colloidal Heteronanocrystals with Temperature-Dependent Emission Color
  • Chin, Patrick T. K.; de Mello Donegá, Celso; van Bavel, Svetlana S.
  • Journal of the American Chemical Society, Vol. 129, Issue 48 https://doi.org/10.1021/ja0738071
journal December 2007
Temperature Dependence of the Photoluminescence of InP/ZnS Quantum Dots journal May 2008
Ligand exchange reactions in InGaAs metalorganic vapor-phase epitaxy journal July 1998
State-Resolved Exciton−Phonon Couplings in CdSe Semiconductor Quantum Dots journal May 2008
Effects of Ligand Exchange Reactions on the Composition of Cd 1 - y Zn y Te Grown by Metalorganic Vapor-Phase Epitaxy journal June 1997
High-Temperature Luminescence Quenching of Colloidal Quantum Dots journal September 2012
Theory of the linear and nonlinear optical properties of semiconductor microcrystallites journal May 1987
Optical Gain and Stimulated Emission in Nanocrystal Quantum Dots journal October 2000

Similar Records

Related Subjects