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Title: Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode

Abstract

A molecular-level understanding of the reactions that occur at the lithium-metal anode/electrolyte interphase is essential to improve the performance of Li–O2 batteries. Experimental and computational techniques are applied to explore the reactivity of tri(ethylene glycol)-substituted trimethylsilane (1NM3), a siloxane-based ether electrolyte, at the lithium-metal anode. In situ/ex situ X-ray diffraction and Fourier-transform infrared spectroscopy studies provide evidence of the formation of lithium hydroxide and lithium carbonates at the anode upon gradual degradation of the metallic lithium anode and the solvent molecules in the presence of oxygen. Density functional calculations performed to obtain a mechanistic understanding of the reductive decomposition of 1NM3 indicate that the decomposition does not require any apparent barrier to produce lithium hydroxide and lithium carbonates when the reduced 1NM3 solvent molecules interact with the oxygen crossing over from the cathode. This study indicates that degradation may be more significant in the case of the 1NM3 solvent, compared to linear ethers such as tetraglyme or dioxalone, because of its relatively high electron affinity. Also, both protection of the lithium metal and prevention of oxygen crossover to the anode are essential for minimizing electrolyte and anode decomposition.

Authors:
; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1222110
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemphyschem, 15(10):2077–2083
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Assary, Rajeev S., Lu, Jun, Luo, Xiangyi, Zhang, Xiaoyi, Ren, Yang, Wu, Huiming, Albishri, Hassan M., El-Hady, D. A., Al-Bogami, A. S., Curtiss, Larry A., and Amine, Khalil. Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode. United States: N. p., 2014. Web. doi:10.1002/cphc.201402130.
Assary, Rajeev S., Lu, Jun, Luo, Xiangyi, Zhang, Xiaoyi, Ren, Yang, Wu, Huiming, Albishri, Hassan M., El-Hady, D. A., Al-Bogami, A. S., Curtiss, Larry A., & Amine, Khalil. Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode. United States. doi:10.1002/cphc.201402130.
Assary, Rajeev S., Lu, Jun, Luo, Xiangyi, Zhang, Xiaoyi, Ren, Yang, Wu, Huiming, Albishri, Hassan M., El-Hady, D. A., Al-Bogami, A. S., Curtiss, Larry A., and Amine, Khalil. Mon . "Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode". United States. doi:10.1002/cphc.201402130.
@article{osti_1222110,
title = {Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode},
author = {Assary, Rajeev S. and Lu, Jun and Luo, Xiangyi and Zhang, Xiaoyi and Ren, Yang and Wu, Huiming and Albishri, Hassan M. and El-Hady, D. A. and Al-Bogami, A. S. and Curtiss, Larry A. and Amine, Khalil},
abstractNote = {A molecular-level understanding of the reactions that occur at the lithium-metal anode/electrolyte interphase is essential to improve the performance of Li–O2 batteries. Experimental and computational techniques are applied to explore the reactivity of tri(ethylene glycol)-substituted trimethylsilane (1NM3), a siloxane-based ether electrolyte, at the lithium-metal anode. In situ/ex situ X-ray diffraction and Fourier-transform infrared spectroscopy studies provide evidence of the formation of lithium hydroxide and lithium carbonates at the anode upon gradual degradation of the metallic lithium anode and the solvent molecules in the presence of oxygen. Density functional calculations performed to obtain a mechanistic understanding of the reductive decomposition of 1NM3 indicate that the decomposition does not require any apparent barrier to produce lithium hydroxide and lithium carbonates when the reduced 1NM3 solvent molecules interact with the oxygen crossing over from the cathode. This study indicates that degradation may be more significant in the case of the 1NM3 solvent, compared to linear ethers such as tetraglyme or dioxalone, because of its relatively high electron affinity. Also, both protection of the lithium metal and prevention of oxygen crossover to the anode are essential for minimizing electrolyte and anode decomposition.},
doi = {10.1002/cphc.201402130},
journal = {Chemphyschem, 15(10):2077–2083},
number = ,
volume = ,
place = {United States},
year = {Mon Jul 21 00:00:00 EDT 2014},
month = {Mon Jul 21 00:00:00 EDT 2014}
}