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Title: Nanocellular thermoplastic foam and process for making the same

Patent ·
OSTI ID:1221982

Prepare a thermoplastic polymer foam having a porosity of 70% or more and at least one of: (i) an average cell size of 200 nanometers or less; and (ii) a nucleation density of at least 1.times.1015 effective nucleation sites per cubic centimeter of foamable polymer composition not including blowing agent using a foamable polymer composition containing a thermoplastic polymer selected from styrenic polymer and (meth)acrylic polymers, a blowing agent comprising at least 20 mole-percent carbon dioxide based on moles of blowing agent and an additive having a Total Hansen Solubility Parameter that differs from that of carbon dioxide by less than 2 and that is present at a concentration of 0.01 to 1.5 weight parts per hundred weight parts thermoplastic polymer.

Research Organization:
Dow Global Technologies LLC, Midland, MI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0003916
Assignee:
Dow Global Technologies LLC (Midland, MI)
Patent Number(s):
9,145,477
Application Number:
14/421,851
OSTI ID:
1221982
Resource Relation:
Patent File Date: 2013 Sep 13
Country of Publication:
United States
Language:
English

References (6)

Transparent supermicrocellular polymer foams and method for their manufacture patent April 2003
Transparent supermicrocellular polymer foams from high Tg polymers and method for manufacture patent April 2003
Determination of mesopore size of aerogels from thermal conductivity measurements journal March 2002
A process for making microcellular thermoplastic parts journal October 1990
Two-step micro cellular foaming of amorphous polymers in supercritical CO2 journal May 2011
The nucleation of microcellular thermoplastic foam with additives: Part II: Experimental results and discussion journal April 1987

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