PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization

Perras, Frederic A.; Kobayashi, Takeshi; Pruski, Marek

doi:10.1039/c5cp04145g

Title: PRESTO polarization transfer to quadrupolar nuclei: Implications for dynamic nuclear polarization

Journal Article · Tue Aug 04 00:00:00 EDT 2015 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/c5cp04145g· OSTI ID:1221933

Perras, Frederic A. ^[1]; Kobayashi, Takeshi ^[1]; Pruski, Marek ^[2]

Ames Lab., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

In this study, we show both experimentally and numerically on a series of model systems that in experiments involving transfer of magnetization from ¹H to the quadrupolar nuclei under magic-angle-spinning (MAS), the PRESTO technique consistently outperforms traditionally used cross polarization (CP), affording more quantitative intensities, improved lineshapes, better overall sensitivity, and straightforward optimization. This advantage derives from the fact that PRESTO circumvents the convoluted and uncooperative spin dynamics during the CP transfer under MAS, by replacing the spin-locking of quadrupolar nuclei with a single central transition selective 90° pulse and using a symmetry-based recoupling sequence in the ¹H channel. This is important in the context of dynamic nuclear polarization (DNP) NMR of quadrupolar nuclei, where the efficient transfer of enhanced ¹H polarization is desired to obtain the highest sensitivity.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1221933

Report Number(s):: IS-J-8778; PPCPFQ; PII: S0965977399002603

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 17, Issue 35; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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