A single crystalline porphyrinic titanium metal–organic framework

Yuan, Shuai; Liu, Tian-Fu; Feng, Dawei; Tian, Jian; Wang, Kecheng; Qin, Junsheng; Zhang, Qiang; Chen, Ying-Pin; Bosch, Mathieu; Zou, Lanfang; Teat, Simon J.; Dalgarno, Scott J.; Zhou, Hong-Cai

doi:10.1039/C5SC00916B

Title: A single crystalline porphyrinic titanium metal–organic framework

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · Chemical Science

DOI:https://doi.org/10.1039/C5SC00916B· OSTI ID:1490498

Yuan, Shuai ^[1]; Liu, Tian-Fu ^[1]; Feng, Dawei ^[1]; Tian, Jian ^[1]; Wang, Kecheng ^[1]; Qin, Junsheng ^[1]; Zhang, Qiang ^[1]; Chen, Ying-Pin ^[1]; Bosch, Mathieu ^[1]; Zou, Lanfang ^[1]; Teat, Simon J. ^[2]; Dalgarno, Scott J. ^[3]; Zhou, Hong-Cai ^[1]

Department of Chemistry, Texas A&M University, College Station, USA
Advanced Light Source, Lawrence Berkeley National Laboratory Berkeley, USA
Institute of Chemical Sciences, Heriot-Watt University Riccarton, Edinburgh EH14 4AS, UK

We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AR0000249; AC02-05CH11231.; SC0001015; AC02-05CH11231; N000141310753; A-1725

OSTI ID:: 1490498

Alternate ID(s):: OSTI ID: 1214548

Journal Information:: Chemical Science, Journal Name: Chemical Science Vol. 6 Journal Issue: 7; ISSN 2041-6520

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 196 works

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