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Title: Facile one-pot synthesis of porphyrin based porous polymer networks (PPNs) as biomimetic catalysts

Abstract

Stable porphyrin based porous polymer networks, PPN-23 and PPN-24, have been synthesized through a facile one-pot approach by the aromatic substitution reactions of pyrrole and aldehydes. PPN-24(Fe) shows high catalytic efficiency as a biomimetic catalyst in the oxidation reaction of 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) in the presence of H2O2.

Authors:
; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1211270
DOE Contract Number:  
DE-AR0000249
Resource Type:
Journal Article
Resource Relation:
Journal Name: ChemComm; Journal Volume: 51; Journal Issue: 19
Country of Publication:
United States
Language:
English

Citation Formats

Zou, LF, Feng, DW, Liu, TF, Chen, YP, Fordham, S, Yuan, S, Tian, J, and Zhou, HC. Facile one-pot synthesis of porphyrin based porous polymer networks (PPNs) as biomimetic catalysts. United States: N. p., 2015. Web. doi:10.1039/c4cc09479d.
Zou, LF, Feng, DW, Liu, TF, Chen, YP, Fordham, S, Yuan, S, Tian, J, & Zhou, HC. Facile one-pot synthesis of porphyrin based porous polymer networks (PPNs) as biomimetic catalysts. United States. doi:10.1039/c4cc09479d.
Zou, LF, Feng, DW, Liu, TF, Chen, YP, Fordham, S, Yuan, S, Tian, J, and Zhou, HC. Thu . "Facile one-pot synthesis of porphyrin based porous polymer networks (PPNs) as biomimetic catalysts". United States. doi:10.1039/c4cc09479d.
@article{osti_1211270,
title = {Facile one-pot synthesis of porphyrin based porous polymer networks (PPNs) as biomimetic catalysts},
author = {Zou, LF and Feng, DW and Liu, TF and Chen, YP and Fordham, S and Yuan, S and Tian, J and Zhou, HC},
abstractNote = {Stable porphyrin based porous polymer networks, PPN-23 and PPN-24, have been synthesized through a facile one-pot approach by the aromatic substitution reactions of pyrrole and aldehydes. PPN-24(Fe) shows high catalytic efficiency as a biomimetic catalyst in the oxidation reaction of 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) in the presence of H2O2.},
doi = {10.1039/c4cc09479d},
journal = {ChemComm},
number = 19,
volume = 51,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}