A cobalt(II) bis(salicylate)-based ionic liquid that shows thermoresponsive and selective water coordination
A metal-containing ionic liquid (MCIL) has been prepared in which the [CoII(salicylate)(2)](2-) anion is able to selectively coordinate two water molecules with a visible colour change, even in the presence of alcohols. Upon moderate heating or placement in vacuo, the hydrated MCIL undergoes reversible thermochromism by releasing the bound water molecules.
- Sponsoring Organization:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- DOE Contract Number:
- DE-AR0000098
- OSTI ID:
- 1211265
- Journal Information:
- ChemComm, Vol. 50, Issue 50; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
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