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Title: Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores

Abstract

A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.

Authors:
 [1];  [1];  [1]
  1. Texas A & M Univ., College Station, TX (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) and Center for Gas Separations Relevant to Clean Energy Technologies (CGS), Washington, DC (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1210607
DOE Contract Number:
SC0001015
Resource Type:
Journal Article
Resource Relation:
Journal Name: J. Am. Chem Soc.; Journal Volume: 137; Journal Issue: 4; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University
Country of Publication:
United States
Language:
English
Subject:
membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. United States: N. p., 2015. Web. doi:10.1021/ja5123528.
Park, Jihye, Feng, Dawei, & Zhou, Hong-Cai. Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores. United States. doi:10.1021/ja5123528.
Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. Wed . "Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores". United States. doi:10.1021/ja5123528.
@article{osti_1210607,
title = {Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores},
author = {Park, Jihye and Feng, Dawei and Zhou, Hong-Cai},
abstractNote = {A facile functionalization assisted by the structural attributes of PCN-333 has been studied while maintaining the integrity of the parent MOF including ultralarge pores, chemical robustness, and crystallinity. Herein we thoroughly analyzed ligand exchange phenomena in PCN-333 and demonstrate that the extent of exchange can be tailored by varying the exchange conditions as potential applications may require. Through this method a variety of functional groups are incorporated into PCN-333. To further show the capabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was performed to the functionalized framework via a click reaction. We anticipate the PCN-333 with functional anchor can serve as a stable platform for further chemistry to be explored in future applications.},
doi = {10.1021/ja5123528},
journal = {J. Am. Chem Soc.},
number = 4,
volume = 137,
place = {United States},
year = {Wed Feb 04 00:00:00 EST 2015},
month = {Wed Feb 04 00:00:00 EST 2015}
}