Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; Velizhanin, Kirill A.; Cirloganu, Claudiu M.; Luo, Hongmei; Klimov, Victor I.; Pietryga, Jeffrey M.

doi:10.1021/nn505793y

Title: Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared

Journal Article · Tue Jan 27 00:00:00 EST 2015 · ACS Nano

DOI:https://doi.org/10.1021/nn505793y· OSTI ID:1210560

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; Velizhanin, Kirill A.; Cirloganu, Claudiu M.; Luo, Hongmei; Klimov, Victor I.; Pietryga, Jeffrey M.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Advanced Solar Photophysics (CASP)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC52-06NA25396

OSTI ID:: 1210560

Journal Information:: ACS Nano, Vol. 9; Related Information: CASP partners with Los Alamos National Laboratory (lead); University of California, Irvine; University of Colorado; Colorado School of Mines; George Mason University; Los Alamos National Laboratory; University of Minnesota; National Renewable Energy Laboratory

Country of Publication:: United States

Language:: English

References (49)

Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals Hines, Margaret A.; Guyot-Sionnest, Philippe The Journal of Physical Chemistry, Vol. 100, Issue 2, p. 468-471 https://doi.org/10.1021/jp9530562	journal	January 1996
Type-II Quantum Dots: CdTe/CdSe(Core/Shell) and CdSe/ZnTe(Core/Shell) Heterostructures Kim, Sungjee; Fisher, Brent; Eisler, Hans-Jürgen Journal of the American Chemical Society, Vol. 125, Issue 38, p. 11466-11467 https://doi.org/10.1021/ja0361749	journal	September 2003
Inverted Core/Shell Nanocrystals Continuously Tunable between Type-I and Type-II Localization Regimes Balet, L. P.; Ivanov, S. A.; Piryatinski, A. Nano Letters, Vol. 4, Issue 8 https://doi.org/10.1021/nl049146c	journal	August 2004
Light Amplification Using Inverted Core/Shell Nanocrystals: Towards Lasing in the Single-Exciton Regime Ivanov, Sergei A.; Nanda, Jagjit; Piryatinski, Andrei The Journal of Physical Chemistry B, Vol. 108, Issue 30 https://doi.org/10.1021/jp0483371	journal	July 2004
Single-exciton optical gain in semiconductor nanocrystals Klimov, Victor I.; Ivanov, Sergei A.; Nanda, Jagjit Nature, Vol. 447, Issue 7143 https://doi.org/10.1038/nature05839	journal	May 2007
“Giant” Multishell CdSe Nanocrystal Quantum Dots with Suppressed Blinking Chen, Yongfen; Vela, Javier; Htoon, Han Journal of the American Chemical Society, Vol. 130, Issue 15 https://doi.org/10.1021/ja711379k	journal	April 2008
Suppressed Auger Recombination in “Giant” Nanocrystals Boosts Optical Gain Performance García-Santamaría, Florencio; Chen, Yongfen; Vela, Javier Nano Letters, Vol. 9, Issue 10 https://doi.org/10.1021/nl901681d	journal	October 2009
Subdiffraction, Luminescence-Depletion Imaging of Isolated, Giant, CdSe/CdS Nanocrystal Quantum Dots Lesoine, Michael D.; Bhattacharjee, Ujjal; Guo, Yijun The Journal of Physical Chemistry C, Vol. 117, Issue 7 https://doi.org/10.1021/jp312231k	journal	February 2013
High-Precision Tracking with Non-blinking Quantum Dots Resolves Nanoscale Vertical Displacement Marchuk, Kyle; Guo, Yijun; Sun, Wei Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja301332t	journal	April 2012
Large-area luminescent solar concentrators based on ‘Stokes-shift-engineered’ nanocrystals in a mass-polymerized PMMA matrix Meinardi, Francesco; Colombo, Annalisa; Velizhanin, Kirill A. Nature Photonics, Vol. 8, Issue 5, p. 392-399 https://doi.org/10.1038/nphoton.2014.54	journal	April 2014
Synthesis and Micrometer-Scale Assembly of Colloidal CdSe/CdS Nanorods Prepared by a Seeded Growth Approach Carbone, Luigi; Nobile, Concetta; De Giorgi, Milena Nano Letters, Vol. 7, Issue 10 https://doi.org/10.1021/nl0717661	journal	October 2007
Ultrafast Electron−Hole Dynamics in Core/Shell CdSe/CdS Dot/Rod Nanocrystals Lupo, Maria Grazia; Della Sala, Fabio; Carbone, Luigi Nano Letters, Vol. 8, Issue 12 https://doi.org/10.1021/nl8028366	journal	December 2008
Suppression of Biexciton Auger Recombination in CdSe/CdS Dot/Rods: Role of the Electronic Structure in the Carrier Dynamics Zavelani-Rossi, Margherita; Lupo, Maria Grazia; Tassone, Francesco Nano Letters, Vol. 10, Issue 8 https://doi.org/10.1021/nl101930z	journal	August 2010
Controlled Alloying of the Core–Shell Interface in CdSe/CdS Quantum Dots for Suppression of Auger Recombination Bae, Wan Ki; Padilha, Lazaro A.; Park, Young-Shin ACS Nano, Vol. 7, Issue 4 https://doi.org/10.1021/nn4002825	journal	April 2013
Dynamic Hole Blockade Yields Two-Color Quantum and Classical Light from Dot-in-Bulk Nanocrystals Galland, Christophe; Brovelli, Sergio; Bae, Wan Ki Nano Letters, Vol. 13, Issue 1 https://doi.org/10.1021/nl3045316	journal	December 2012
Dual-Color Electroluminescence from Dot-in-Bulk Nanocrystals Brovelli, Sergio; Bae, Wan Ki; Galland, Christophe Nano Letters, Vol. 14, Issue 2 https://doi.org/10.1021/nl403478s	journal	December 2013
1.3μm to 1.55μm Tunable Electroluminescence from PbSe Quantum Dots Embedded within an Organic Device Steckel, J. S.; Coe-Sullivan, S.; Bulović, V. Advanced Materials, Vol. 15, Issue 21 https://doi.org/10.1002/adma.200305449	journal	November 2003
Efficient Infrared Electroluminescent Devices Using Solution-Processed Colloidal Quantum Dots Konstantatos, G.; Huang, C.; Levina, L. Advanced Functional Materials, Vol. 15, Issue 11 https://doi.org/10.1002/adfm.200500379	journal	November 2005
Peak External Photocurrent Quantum Efficiency Exceeding 100% via MEG in a Quantum Dot Solar Cell Semonin, O. E.; Luther, J. M.; Choi, S. Science, Vol. 334, Issue 6062 https://doi.org/10.1126/science.1209845	journal	December 2011
Core/Shell PbSe/PbS QDs TiO ₂ Heterojunction Solar Cell Etgar, Lioz; Yanover, Diana; Čapek, Richard Karel Advanced Functional Materials, Vol. 23, Issue 21 https://doi.org/10.1002/adfm.201202322	journal	December 2012
PbS Quantum Dot Solar Cells Integrated with Sol–Gel-Derived ZnO as an n-Type Charge-Selective Layer Park, Hye-Yun; Ryu, Ilhwan; Kim, Jinhyun The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp504156c	journal	July 2014
Improved performance and stability in quantum dot solar cells through band alignment engineering Chuang, Chia-Hao M.; Brown, Patrick R.; Bulović, Vladimir Nature Materials, Vol. 13, Issue 8, p. 796-801 https://doi.org/10.1038/nmat3984	journal	May 2014
Effect of Solar Concentration on the Thermodynamic Power Conversion Efficiency of Quantum-Dot Solar Cells Exhibiting Multiple Exciton Generation Hanna, Mark C.; Beard, Matthew C.; Nozik, Arthur J. The Journal of Physical Chemistry Letters, Vol. 3, Issue 19 https://doi.org/10.1021/jz301077e	journal	September 2012
Carrier Multiplication in Quantum Dots within the Framework of Two Competing Energy Relaxation Mechanisms Stewart, John T.; Padilha, Lazaro A.; Bae, Wan Ki The Journal of Physical Chemistry Letters, Vol. 4, Issue 12 https://doi.org/10.1021/jz4004334	journal	June 2013
Detailed-balance power conversion limits of nanocrystal-quantum-dot solar cells in the presence of carrier multiplication Klimov, Victor I. Applied Physics Letters, Vol. 89, Issue 12 https://doi.org/10.1063/1.2356314	journal	September 2006
Pushing the Band Gap Envelope: Mid-Infrared Emitting Colloidal PbSe Quantum Dots Pietryga, Jeffrey M.; Schaller, Richard D.; Werder, Donald Journal of the American Chemical Society, Vol. 126, Issue 38 https://doi.org/10.1021/ja047659f	journal	September 2004
Colloidal synthesis of nanocrystals and nanocrystal superlattices Murray, C. B.; Sun, Shouheng; Gaschler, W. IBM Journal of Research and Development, Vol. 45, Issue 1 https://doi.org/10.1147/rd.451.0047	journal	January 2001
Ultrabright PbSe Magic-sized Clusters Evans, Christopher M.; Guo, Li; Peterson, Jeffrey J. Nano Letters, Vol. 8, Issue 9 https://doi.org/10.1021/nl801685a	journal	September 2008
Utilizing the Lability of Lead Selenide to Produce Heterostructured Nanocrystals with Bright, Stable Infrared Emission Pietryga, Jeffrey M.; Werder, Donald J.; Williams, Darrick J. Journal of the American Chemical Society, Vol. 130, Issue 14 https://doi.org/10.1021/ja710437r	journal	April 2008
The Different Nature of Band Edge Absorption and Emission in Colloidal PbSe/CdSe Core/Shell Quantum Dots De Geyter, Bram; Justo, Yolanda; Moreels, Iwan ACS Nano, Vol. 5, Issue 1 https://doi.org/10.1021/nn102980e	journal	December 2010
Anisotropic Cation Exchange in PbSe/CdSe Core/Shell Nanocrystals of Different Geometry Casavola, Marianna; van Huis, Marijn A.; Bals, Sara Chemistry of Materials, Vol. 24, Issue 2 https://doi.org/10.1021/cm202796s	journal	December 2011
Probing the Structure of Colloidal Core/Shell Quantum Dots Formed by Cation Exchange Abel, Keith A.; FitzGerald, Paul A.; Wang, Ting-Yu The Journal of Physical Chemistry C, Vol. 116, Issue 6 https://doi.org/10.1021/jp2112928	journal	February 2012
Three-Dimensional Atomic Imaging of Colloidal Core–Shell Nanocrystals Bals, Sara; Casavola, Marianna; van Huis, Marijn A. Nano Letters, Vol. 11, Issue 8 https://doi.org/10.1021/nl201826e	journal	August 2011
Towards controlled synthesis and better understanding of highly luminescent PbS/CdS core/shell quantum dots Zhao, Haiguang; Chaker, Mohamed; Wu, Nianqiang Journal of Materials Chemistry, Vol. 21, Issue 24 https://doi.org/10.1039/c1jm11205h	journal	January 2011
Some physical properties of the systems Pb1?xMgxSe and Pb1?xCdxSe Sealy, B. J.; Crocker, A. J. Journal of Materials Science, Vol. 8, Issue 9 https://doi.org/10.1007/BF00549339	journal	September 1973
Uncovering Hot Hole Dynamics in CdSe Nanocrystals Liu, Cunming; Peterson, Jeffrey J.; Krauss, Todd D. The Journal of Physical Chemistry Letters, Vol. 5, Issue 17 https://doi.org/10.1021/jz5015554	journal	August 2014
Breaking the Phonon Bottleneck in Semiconductor Nanocrystals via Multiphonon Emission Induced by Intrinsic Nonadiabatic Interactions Schaller, Richard D.; Pietryga, Jeffrey M.; Goupalov, Serguei V. Physical Review Letters, Vol. 95, Issue 19 https://doi.org/10.1103/PhysRevLett.95.196401	journal	October 2005
Thermally induced atomic reconstruction of PbSe/CdSe core/shell quantum dots into PbSe/CdSe bi-hemisphere hetero-nanocrystals Grodzińska, Dominika; Pietra, Francesca; van Huis, Marijn A. Journal of Materials Chemistry, Vol. 21, Issue 31 https://doi.org/10.1039/c0jm04458j	journal	January 2011
Simple Theoretical Estimates of the Schottky Constants and Virtual‐Enthalpies of Single Vacancy Formation in Zinc‐Blende and Wurtzite Type Semiconductors Van Vechten, J. A. Journal of The Electrochemical Society, Vol. 122, Issue 3 https://doi.org/10.1149/1.2134226	journal	March 1975
The mean square atomic displacements and enthalpies of vacancy formation in some semiconductors Bublik, V. T. Physica Status Solidi (a), Vol. 45, Issue 2 https://doi.org/10.1002/pssa.2210450223	journal	February 1978
Relations between vacancy migration and formation energies, debye temperature and melting point Ben-Abraham, S. I.; Rabinovitch, A.; Pelleg, J. Physica Status Solidi (b), Vol. 84, Issue 2 https://doi.org/10.1002/pssb.2220840205	journal	December 1977
Melting in Semiconductor Nanocrystals Goldstein, A. N.; Echer, C. M.; Alivisatos, A. P. Science, Vol. 256, Issue 5062, p. 1425-1427 https://doi.org/10.1126/science.256.5062.1425	journal	June 1992
Density Functional Theory Study of Ligand Binding on CdSe (0001), (0001̄), and (112̄0) Single Crystal Relaxed and Reconstructed Surfaces: Implications for Nanocrystalline Growth Rempel, Jane Y.; Trout, Bernhardt L.; Bawendi, Moungi G. The Journal of Physical Chemistry B, Vol. 110, Issue 36 https://doi.org/10.1021/jp064051f	journal	September 2006
Zinc-blende–wurtzite polytypism in semiconductors Yeh, Chin-Yu; Lu, Z. W.; Froyen, S. Physical Review B, Vol. 46, Issue 16 https://doi.org/10.1103/PhysRevB.46.10086	journal	October 1992
Self-diffusion and the defect structure of cadmium sulfide Kumar, V.; Kröger, F. A. Journal of Solid State Chemistry, Vol. 3, Issue 3 https://doi.org/10.1016/0022-4596(71)90075-2	journal	August 1971
Interfacial Alloying in CdSe/CdS Heteronanocrystals: A Raman Spectroscopy Analysis Tschirner, Norman; Lange, Holger; Schliwa, Andrei Chemistry of Materials, Vol. 24, Issue 2 https://doi.org/10.1021/cm202947n	journal	December 2011
Infrared-Active Heterostructured Nanocrystals with Ultralong Carrier Lifetimes Lee, Doh C.; Robel, István; Pietryga, Jeffrey M. Journal of the American Chemical Society, Vol. 132, Issue 29 https://doi.org/10.1021/ja102716p	journal	July 2010
Blue Luminescence from (CdS)ZnS Core–Shell Nanocrystals Steckel, Jonathan S.; Zimmer, John P.; Coe-Sullivan, Seth Angewandte Chemie International Edition, Vol. 43, Issue 16 https://doi.org/10.1002/anie.200453728	journal	April 2004
Measurement of Electronic States of PbS Nanocrystal Quantum Dots Using Scanning Tunneling Spectroscopy: The Role of Parity Selection Rules in Optical Absorption Diaconescu, Bogdan; Padilha, Lazaro A.; Nagpal, Prashant Physical Review Letters, Vol. 110, Issue 12 https://doi.org/10.1103/PhysRevLett.110.127406	journal	March 2013

Cited By (10)

Role of Interface Chemistry in Opening New Radiative Pathways in InP/CdSe Giant Quantum Dots with Blinking‐Suppressed Two‐Color Emission Dennis, Allison M.; Buck, Matthew R.; Wang, Feng Advanced Functional Materials, Vol. 29, Issue 37 https://doi.org/10.1002/adfm.201809111	journal	June 2019
Light‐Emitting Diodes with Cu‐Doped Colloidal Quantum Wells: From Ultrapure Green, Tunable Dual‐Emission to White Light Liu, Baiquan; Sharma, Manoj; Yu, Junhong Small, Vol. 15, Issue 38 https://doi.org/10.1002/smll.201901983	journal	August 2019
Sub–single-exciton lasing using charged quantum dots coupled to a distributed feedback cavity Kozlov, Oleg V.; Park, Young-Shin; Roh, Jeongkyun Science, Vol. 365, Issue 6454 https://doi.org/10.1126/science.aax3489	journal	August 2019
Biomineralization of PbS and PbS–CdS core–shell nanocrystals and their application in quantum dot sensitized solar cells Spangler, Leah C.; Lu, Li; Kiely, Christopher J. Journal of Materials Chemistry A, Vol. 4, Issue 16 https://doi.org/10.1039/c5ta10534j	journal	January 2016
Band Gap Engineering Improves the Efficiency of Double Quantum Dot Upconversion Nanocrystals Yang, Gaoling; Meir, Noga; Raanan, Dekel Advanced Functional Materials, Vol. 29, Issue 23 https://doi.org/10.1002/adfm.201900755	journal	April 2019
Ultrasensitive, Biocompatible, Self-Calibrating, Multiparametric Temperature Sensors Zhao, Haiguang; Vomiero, Alberto; Rosei, Federico Small, Vol. 11, Issue 43 https://doi.org/10.1002/smll.201502249	journal	October 2015
Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots Meinardi, Francesco; McDaniel, Hunter; Carulli, Francesco Nature Nanotechnology, Vol. 10, Issue 10 https://doi.org/10.1038/nnano.2015.178	journal	August 2015
Photoinduced electron transfer in novel CdSe–Cu ₂ Se type II core–shell quantum dots Simi, N. J.; Vinayakan, R.; Ison, V. V. RSC Advances, Vol. 9, Issue 26 https://doi.org/10.1039/c9ra02027f	journal	January 2019
Influence of the Ion Coordination Number on Cation Exchange Reactions with Copper Telluride Nanocrystals Tu, Renyong; Xie, Yi; Bertoni, Giovanni Journal of the American Chemical Society, Vol. 138, Issue 22 https://doi.org/10.1021/jacs.6b02830	journal	May 2016
Carrier Multiplication Mechanisms and Competing Processes in Colloidal Semiconductor Nanostructures Kershaw, Stephen; Rogach, Andrey Materials, Vol. 10, Issue 9 https://doi.org/10.3390/ma10091095	journal	September 2017

Similar Records

Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared

Journal Article · Thu Dec 18 00:00:00 EST 2014 · ACS Nano · OSTI ID:1210560

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; +5 more

Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared

Journal Article · Thu Dec 18 00:00:00 EST 2014 · ACS Nano · OSTI ID:1210560

Lin, Qianglu; Makarov, Nikolay S.; Koh, Weon-kyu; +5 more

Synthesis of Type I PbSe/CdSe Dot-on-Plate Heterostructures with Near-Infrared Emission

Journal Article · Mon Mar 18 00:00:00 EDT 2019 · Journal of the American Chemical Society · OSTI ID:1210560

Williams, Kali R.; Diroll, Benjamin T.; Watkins, Nicolas E.; +4 more

Related Subjects

solar (photovoltaic)
solar (fuels)
solid state lighting
bio-inspired
electrodes - solar
defects
charge transport
materials and chemistry by design
optics
synthesis (novel materials)
synthesis (scalable processing)

Title: Design and Synthesis of Heterostructured Quantum Dots with Dual Emission in the Visible and Infrared

Citation Formats

References (49)

Cited By (10)

Similar Records

Related Subjects