Efficient Conversion of CO2 to CO using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

Medina-Ramos, J.; Pupillo, R.C.; Keane, T.P.; DiMeglio, J.L.; Rosenthal, J.

doi:10.1021/ja5121088

Title: Efficient Conversion of CO2 to CO using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

Journal Article · Wed Apr 22 00:00:00 EDT 2015 · J Am Chem Soc

DOI:https://doi.org/10.1021/ja5121088· OSTI ID:1210503

Medina-Ramos, J.; Pupillo, R.C.; Keane, T.P.; DiMeglio, J.L.; Rosenthal, J.

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: ERKCC61

OSTI ID:: 1210503

Journal Information:: J Am Chem Soc, Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia

Country of Publication:: United States

Language:: English

References (37)

Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
The role of copper and zinc oxide in methanol synthesis catalysts Burch, Robert; Golunski, Stanislaw E.; Spencer, Michael S. Journal of the Chemical Society, Faraday Transactions, Vol. 86, Issue 15 https://doi.org/10.1039/ft9908602683	journal	January 1990
Synthesis of Acetic Acid from Methanol and Carbon Monoxide Singh, Alamjit D.; Krase, Norman W. Industrial & Engineering Chemistry, Vol. 27, Issue 8 https://doi.org/10.1021/ie50308a015	journal	August 1935
A comprehensive mechanism for the Fischer-Tropsch synthesis Rofer-DePoorter, Cheryl K. Chemical Reviews, Vol. 81, Issue 5 https://doi.org/10.1021/cr00045a002	journal	October 1981
Beyond Petrochemicals: The Renewable Chemicals Industry Vennestrøm, P. N. R.; Osmundsen, C. M.; Christensen, C. H. Angewandte Chemie International Edition, Vol. 50, Issue 45 https://doi.org/10.1002/anie.201102117	journal	October 2011
Important roles of Fischer–Tropsch synfuels in the global energy future Takeshita, Takayuki; Yamaji, Kenji Energy Policy, Vol. 36, Issue 8 https://doi.org/10.1016/j.enpol.2008.02.044	journal	August 2008
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper Li, Christina W.; Ciston, Jim; Kanan, Matthew W. Nature, Vol. 508, Issue 7497 https://doi.org/10.1038/nature13249	journal	April 2014
A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper Gattrell, M.; Gupta, N.; Co, A. Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19 https://doi.org/10.1016/j.jelechem.2006.05.013	journal	August 2006
Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low-Temperature Aqueous KHCO₃ Media Azuma, Masashi; Hashimoto, Kazuhito; Hiramoto, Masahiro Journal of The Electrochemical Society, Vol. 137, Issue 6, p. 1772-1778 https://doi.org/10.1149/1.2086796	journal	January 1990
PRODUCTION OF CO AND CH ₄ IN ELECTROCHEMICAL REDUCTION OF CO ₂ AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin Chemistry Letters, Vol. 14, Issue 11 https://doi.org/10.1246/cl.1985.1695	journal	November 1985
Electrochemical reduction of CO₂ on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110) Hoshi, Nagahiro; Kato, Makiko; Hori, Yoshio Journal of Electroanalytical Chemistry, Vol. 440, Issue 1-2, p. 283-286 https://doi.org/10.1016/S0022-0728(97)00447-6	journal	December 1997
Nanoparticle Silver Catalysts That Show Enhanced Activity for Carbon Dioxide Electrolysis Salehi-Khojin, Amin; Jhong, Huei-Ru Molly; Rosen, Brian A. The Journal of Physical Chemistry C, Vol. 117, Issue 4 https://doi.org/10.1021/jp310509z	journal	January 2013
Nitrogen-Based Catalysts for the Electrochemical Reduction of CO ₂ to CO Tornow, Claire E.; Thorson, Michael R.; Ma, Sichao Journal of the American Chemical Society, Vol. 134, Issue 48 https://doi.org/10.1021/ja308217w	journal	November 2012
Electrochemical reduction of carbon dioxides to carbon monoxide at a gold electrode in aqueous potassium hydrogen carbonate Hori, Yoshio; Murata, Akira; Kikuchi, Katsuhei Journal of the Chemical Society, Chemical Communications, Issue 10 https://doi.org/10.1039/c39870000728	journal	January 1987
Aqueous CO ₂ Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles Chen, Yihong; Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 49 https://doi.org/10.1021/ja309317u	journal	November 2012
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO Zhu, Wenlei; Michalsky, Ronald; Metin, Önder Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409445p	journal	October 2013
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
Electrochemical CO₂ Reduction on Metal Electrodes Hori, Y.; Vayenas, Constantinos G.; White, Ralph E. Modern Aspects of Electrochemistry, p. 89-189 https://doi.org/10.1007/978-0-387-49489-0_3	book	January 2008
Selective Conversion of CO ₂ to CO with High Efficiency Using an Inexpensive Bismuth-Based Electrocatalyst DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4033549	journal	June 2013
Ionic Liquid-Mediated Selective Conversion of CO₂ to CO at Low Overpotentials Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R. Science, Vol. 334, Issue 6056, p. 643-644 https://doi.org/10.1126/science.1209786	journal	September 2011
In Situ Spectroscopic Examination of a Low Overpotential Pathway for Carbon Dioxide Conversion to Carbon Monoxide Rosen, Brian A.; Haan, John L.; Mukherjee, Prabuddha The Journal of Physical Chemistry C, Vol. 116, Issue 29, p. 15307-15312 https://doi.org/10.1021/jp210542v	journal	July 2012
Water Enhancement of CO₂ Conversion on Silver in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate Rosen, B. A.; Zhu, W.; Kaul, G. Journal of the Electrochemical Society, Vol. 160, Issue 2, p. H138-H141 https://doi.org/10.1149/2.004303jes	journal	November 2012
Electrocatalytic CO ₂ Reduction with a Homogeneous Catalyst in Ionic Liquid: High Catalytic Activity at Low Overpotential Grills, David C.; Matsubara, Yasuo; Kuwahara, Yutaka The Journal of Physical Chemistry Letters, Vol. 5, Issue 11 https://doi.org/10.1021/jz500759x	journal	May 2014
Efficient Reduction of CO ₂ to CO with High Current Density Using in Situ or ex Situ Prepared Bi-Based Materials Medina-Ramos, Jonnathan; DiMeglio, John L.; Rosenthal, Joel Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja501923g	journal	May 2014
Tin Oxide Dependence of the CO ₂ Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts Chen, Yihong; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja2108799	journal	January 2012
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide Ikeda, Shoichiro; Takagi, Takehiko; Ito, Kaname Bulletin of the Chemical Society of Japan, Vol. 60, Issue 7, p. 2517-2522 https://doi.org/10.1246/bcsj.60.2517	journal	July 1987
Mechanism and kinetic characteristics of the electrochemical reduction of carbon dioxide in media of low proton availability Amatore, Christian; Saveant, Jean Michel Journal of the American Chemical Society, Vol. 103, Issue 17 https://doi.org/10.1021/ja00407a008	journal	August 1981
Electrochemical Reduction of CO₂ at Sb and Bi Electrodes in KHCO₃ Solution Komatsu, Seiji; Yanagihara, Tetsu; Hiraga, Yuki Denki Kagaku oyobi Kogyo Butsuri Kagaku, Vol. 63, Issue 3 https://doi.org/10.5796/kogyobutsurikagaku.63.217	journal	January 1995
Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH Whipple, Devin T.; Finke, Eryn C.; Kenis, Paul J. A. Electrochemical and Solid-State Letters, Vol. 13, Issue 9 https://doi.org/10.1149/1.3456590	journal	January 2010
The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility Agarwal, Arun S.; Zhai, Yumei; Hill, Davion ChemSusChem, Vol. 4, Issue 9 https://doi.org/10.1002/cssc.201100220	journal	September 2011
Electrochemical Processing of Carbon Dioxide Oloman, Colin; Li, Hui ChemSusChem, Vol. 1, Issue 5, p. 385-391 https://doi.org/10.1002/cssc.200800015	journal	May 2008
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate Zhang, Sheng; Kang, Peng; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja4113885	journal	January 2014
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Switching the Reaction Course of Electrochemical CO ₂ Reduction with Ionic Liquids Sun, Liyuan; Ramesha, Ganganahalli K.; Kamat, Prashant V. Langmuir, Vol. 30, Issue 21 https://doi.org/10.1021/la5009076	journal	May 2014
Electrosynthesis of Imidazolium Carboxylates de Robillard, Guillaume; Devillers, Charles H.; Kunz, Doris Organic Letters, Vol. 15, Issue 17 https://doi.org/10.1021/ol401949f	journal	August 2013

Cited By (56)

Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron- and Nitrogen-Co-doped Nanodiamond Liu, Yanming; Zhang, Yujing; Cheng, Kai Angewandte Chemie International Edition, Vol. 56, Issue 49 https://doi.org/10.1002/anie.201706311	journal	October 2017
Nanostructured Copper-Based Electrocatalysts for CO ₂ Reduction Gu, Zhengxiang; Shen, Hao; Shang, Longmei Small Methods, Vol. 2, Issue 11 https://doi.org/10.1002/smtd.201800121	journal	July 2018
Antimonene: From Experimental Preparation to Practical Application Wang, Xin; Song, Jun; Qu, Junle Angewandte Chemie International Edition, Vol. 58, Issue 6 https://doi.org/10.1002/anie.201808302	journal	November 2018
Dielectric barrier discharge plasma assisted CO ₂ conversion: understanding the effects of reactor design and operating parameters Lu, Na; Zhang, Chuke; Shang, Kefeng Journal of Physics D: Applied Physics, Vol. 52, Issue 22 https://doi.org/10.1088/1361-6463/ab0ebb	journal	March 2019
Electrosynthesis of a Defective Indium Selenide with 3D Structure on a Substrate for Tunable CO ₂ Electroreduction to Syngas Yang, Dexin; Zhu, Qinggong; Sun, Xiaofu Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201914831	journal	February 2020
Electrochemical Reduction of CO2 to Formate on Easily Prepared Carbon-Supported Bi Nanoparticles Ávila-Bolívar, Beatriz; García-Cruz, Leticia; Montiel, Vicente Molecules, Vol. 24, Issue 11 https://doi.org/10.3390/molecules24112032	journal	May 2019
Zn-Doped Cu(100) facet with efficient catalytic ability for the CO ₂ electroreduction to ethylene Zhang, Yuefeng; Zhao, Yong; Wang, Caiyun Physical Chemistry Chemical Physics, Vol. 21, Issue 38 https://doi.org/10.1039/c9cp03692j	journal	January 2019
Metal-based heterogeneous electrocatalysts for reduction of carbon dioxide and nitrogen: mechanisms, recent advances and perspective Zhou, Jun-Hao; Zhang, Ya-Wen Reaction Chemistry & Engineering, Vol. 3, Issue 5 https://doi.org/10.1039/c8re00111a	journal	January 2018
Electrocatalytic Alloys for CO ₂ Reduction He, Jingfu; Johnson, Noah J. J.; Huang, Aoxue ChemSusChem, Vol. 11, Issue 1 https://doi.org/10.1002/cssc.201701825	journal	December 2017
Achieving the Widest Range of Syngas Proportions at High Current Density over Cadmium Sulfoselenide Nanorods in CO ₂ Electroreduction He, Rong; Zhang, An; Ding, Yilun Advanced Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adma.201705872	journal	January 2018
Nickel Doping in Atomically Thin Tin Disulfide Nanosheets Enables Highly Efficient CO ₂ Reduction Zhang, An; He, Rong; Li, Huiping Angewandte Chemie International Edition, Vol. 57, Issue 34 https://doi.org/10.1002/anie.201806043	journal	August 2018
Copper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2 Jiao, Jiqing; Lin, Rui; Liu, Shoujie Nature Chemistry, Vol. 11, Issue 3 https://doi.org/10.1038/s41557-018-0201-x	journal	January 2019
Hydride Pinning Pathway in the Hydrogenation of CO ₂ to Formic Acid on Dimeric Tin Dioxide Sarma, Plaban Jyoti; Baruah, Satyajit Dey; Logsdail, Andrew ChemPhysChem, Vol. 20, Issue 5 https://doi.org/10.1002/cphc.201801194	journal	February 2019
Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts Yang, Dexin; Zhu, Qinggong; Chen, Chunjun Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08653-9	journal	February 2019
Alkalinity Initiated Decomposition of Mediating Imidazolium Ions in High Current Density CO ₂ Electrolysis Neubauer, Sebastian S.; Schmid, Bernhard; Reller, Christian ChemElectroChem, Vol. 4, Issue 1 https://doi.org/10.1002/celc.201600461	journal	October 2016
Highly selective and efficient reduction of CO ₂ to CO on cadmium electrodes derived from cadmium hydroxide Shi, Jinbiao; Shao, Dan; Zhang, Jianling Chemical Communications, Vol. 54, Issue 43 https://doi.org/10.1039/c8cc02055h	journal	January 2018
Electrochemical Reduction of Carbon Dioxide in a Monoethanolamine Capture Medium Chen, Lu; Li, Fengwang; Zhang, Ying ChemSusChem, Vol. 10, Issue 20 https://doi.org/10.1002/cssc.201701075	journal	September 2017
Progress in development of electrocatalyst for CO ₂ conversion to selective CO production Nguyen, Dang Le Tri; Kim, Younghye; Hwang, Yun Jeong Carbon Energy, Vol. 2, Issue 1 https://doi.org/10.1002/cey2.27	journal	March 2020
CO ₂ reduction: the quest for electrocatalytic materials Khezri, Bahareh; Fisher, Adrian C.; Pumera, Martin Journal of Materials Chemistry A, Vol. 5, Issue 18 https://doi.org/10.1039/c6ta09875d	journal	January 2017
Copper-Tin Alloys for the Electrocatalytic Reduction of CO2 in an Imidazolium-Based Non-Aqueous Electrolyte Sacci, Robert; Velardo, Stephanie; Xiong, Lu Energies, Vol. 12, Issue 16 https://doi.org/10.3390/en12163132	journal	August 2019
Selective CO ₂ Reduction on 2D Mesoporous Bi Nanosheets Yang, Hui; Han, Na; Deng, Jun Advanced Energy Materials, Vol. 8, Issue 35 https://doi.org/10.1002/aenm.201801536	journal	October 2018
Nanostructured Materials for Heterogeneous Electrocatalytic CO ₂ Reduction and their Related Reaction Mechanisms Zhang, Lei; Zhao, Zhi-Jian; Gong, Jinlong Angewandte Chemie International Edition, Vol. 56, Issue 38 https://doi.org/10.1002/anie.201612214	journal	July 2017
CO ₂ Electrolysis to CO and O ₂ at High Selectivity, Stability and Efficiency Using Sustainion Membranes Liu, Zengcai; Yang, Hongzhou; Kutz, Robert Journal of The Electrochemical Society, Vol. 165, Issue 15 https://doi.org/10.1149/2.0501815jes	journal	January 2018
Towards sustainable fuels and chemicals through the electrochemical reduction of CO ₂ : lessons from water electrolysis Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/c5gc01893e	journal	January 2015
Selective electroreduction of CO ₂ to formate on 3D [100] Pb dendrites with nanometer-sized needle-like tips Fan, Mengyang; Garbarino, Sébastien; Botton, Gianluigi A. J. Mater. Chem. A, Vol. 5, Issue 39 https://doi.org/10.1039/c7ta06528k	journal	January 2017
Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction Lei, Fengcai; Liu, Wei; Sun, Yongfu Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12697	journal	September 2016
Water Splitting-Biosynthetic Hybrid System for CO ₂ Conversion using Nickel Nanoparticles Embedded in N-Doped Carbon Nanotubes Li, Zhongjian; Li, Gang; Chen, Xinlu ChemSusChem, Vol. 11, Issue 14 https://doi.org/10.1002/cssc.201800878	journal	June 2018
Unlocking the Electrocatalytic Activity of Antimony for CO ₂ Reduction by Two-Dimensional Engineering of the Bulk Material Li, Fengwang; Xue, Mianqi; Li, Jiezhen Angewandte Chemie International Edition, Vol. 56, Issue 46 https://doi.org/10.1002/anie.201710038	journal	October 2017
Theoretical insight into the electrocatalytic reduction of CO ₂ with different metal ratios and reaction mechanisms on palladium–copper alloys Xing, Minmin; Guo, Ling; Hao, Zijun Dalton Transactions, Vol. 48, Issue 4 https://doi.org/10.1039/c8dt03571g	journal	January 2019
CO ₂ reduction to acetate in mixtures of ultrasmall (Cu) _n ,(Ag) _m bimetallic nanoparticles Wang, Ying; Wang, Degao; Dares, Christopher J. Proceedings of the National Academy of Sciences, Vol. 115, Issue 2 https://doi.org/10.1073/pnas.1713962115	journal	December 2017
Theoretical design and mechanistic study of the metal-free reduction of CO ₂ to CO Ma, Gongli; Song, Guoliang; Li, Zhen Hua Phys. Chem. Chem. Phys., Vol. 19, Issue 41 https://doi.org/10.1039/c7cp05538b	journal	January 2017
Oxygenates from the Electrochemical Reduction of Carbon Dioxide Feng, Guanghui; Chen, Wei; Wang, Baiyin Chemistry - An Asian Journal, Vol. 13, Issue 16 https://doi.org/10.1002/asia.201800637	journal	July 2018
Ionic-caged heterometallic bismuth–platinum complex exhibiting electrocatalytic CO ₂ reduction Yoshida, Takefumi; Ahsan, Habib Md.; Zhang, Hai-Tao Dalton Transactions, Vol. 49, Issue 8 https://doi.org/10.1039/c9dt04817k	journal	January 2020
High efficiency electrochemical reduction of CO ₂ beyond the two-electron transfer pathway on grain boundary rich ultra-small SnO ₂ nanoparticles Liang, Chenglu; Kim, Byoungsu; Yang, Shize Journal of Materials Chemistry A, Vol. 6, Issue 22 https://doi.org/10.1039/c8ta01367e	journal	January 2018
Hybrid bioinorganic approach to solar-to-chemical conversion Nichols, Eva M.; Gallagher, Joseph J.; Liu, Chong Proceedings of the National Academy of Sciences, Vol. 112, Issue 37 https://doi.org/10.1073/pnas.1508075112	journal	August 2015
Introduction of carbon–boron atomic groups as an efficient strategy to boost formic acid production toward CO ₂ electrochemical reduction Cao, Yun; Geng, Zhigang; Chen, Weiwei Chemical Communications, Vol. 54, Issue 27 https://doi.org/10.1039/c8cc00644j	journal	January 2018
Bipyridine‐Assisted Assembly of Au Nanoparticles on Cu Nanowires To Enhance the Electrochemical Reduction of CO ₂ Fu, Jiaju; Zhu, Wenlei; Chen, Ying Angewandte Chemie, Vol. 131, Issue 40 https://doi.org/10.1002/ange.201905318	journal	August 2019
Selective CO ₂ reduction to C ₃ and C ₄ oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV Calvinho, Karin U. D.; Laursen, Anders B.; Yap, Kyra M. K. Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee00936h	journal	January 2018
Recent Advances in Electrochemical CO ₂ -to-CO Conversion on Heterogeneous Catalysts Zheng, Tingting; Jiang, Kun; Wang, Haotian Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802066	journal	August 2018
Recent progress on advanced design for photoelectrochemical reduction of CO2 to fuels Zhang, Ning; Long, Ran; Gao, Chao Science China Materials, Vol. 61, Issue 6 https://doi.org/10.1007/s40843-017-9151-y	journal	January 2018
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide Zhu, Dong Dong; Liu, Jin Long; Qiao, Shi Zhang Advanced Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adma.201504766	journal	March 2016
Metal–organic framework-derived indium–copper bimetallic oxide catalysts for selective aqueous electroreduction of CO ₂ Guo, Weiwei; Sun, Xiaofu; Chen, Chunjun Green Chemistry, Vol. 21, Issue 3 https://doi.org/10.1039/c8gc03261k	journal	January 2019
Electrosynthesis of a Defective Indium Selenide with 3D Structure on a Substrate for Tunable CO ₂ Electroreduction to Syngas Yang, Dexin; Zhu, Qinggong; Sun, Xiaofu Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201914831	journal	December 2019
[ ¹¹ C]CO ₂ to [ ¹¹ C]CO conversion mediated by [ ¹¹ C]silanes: a novel route for [ ¹¹ C]carbonylation reactions Taddei, Carlotta; Bongarzone, Salvatore; Haji Dheere, Abdul Karim Chemical Communications, Vol. 51, Issue 59 https://doi.org/10.1039/c5cc02095f	journal	January 2015
Low-energy formate production from CO ₂ electroreduction using electrodeposited tin on GDE Irtem, E.; Andreu, T.; Parra, A. Journal of Materials Chemistry A, Vol. 4, Issue 35 https://doi.org/10.1039/c6ta04432h	journal	January 2016
Electrochemical [ ¹¹ C]CO ₂ to [ ¹¹ C]CO conversion for PET imaging Anders, David A.; Bongarzone, Salvatore; Fortt, Robin Chemical Communications, Vol. 53, Issue 20 https://doi.org/10.1039/c7cc00319f	journal	January 2017
Antimonen: von der experimentellen Herstellung zur praktischen Anwendung Wang, Xin; Song, Jun; Qu, Junle Angewandte Chemie, Vol. 131, Issue 6 https://doi.org/10.1002/ange.201808302	journal	November 2018
Pristine Transition‐Metal‐Based Metal‐Organic Frameworks for Electrocatalysis Sun, Fancheng; Li, Qing; Xue, Huaiguo ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801520	journal	January 2019
Progress in catalyst exploration for heterogeneous CO ₂ reduction and utilization: a critical review Zhao, Guixia; Huang, Xiubing; Wang, Xiangxue J. Mater. Chem. A, Vol. 5, Issue 41 https://doi.org/10.1039/c7ta07290b	journal	January 2017
Facile Synthesis of Nanostructural High-Performance Cu-Pb Electrocatalysts for CO ₂ Reduction Wang, Yutian; Hu, Hanjun; Sun, Yufan Advanced Materials Interfaces, Vol. 6, Issue 2 https://doi.org/10.1002/admi.201801200	journal	November 2018
Bipyridine-Assisted Assembly of Au Nanoparticles on Cu Nanowires To Enhance the Electrochemical Reduction of CO ₂ Fu, Jiaju; Zhu, Wenlei; Chen, Ying Angewandte Chemie International Edition, Vol. 58, Issue 40 https://doi.org/10.1002/anie.201905318	journal	August 2019
Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO ₂ Reduction to Formate Han, Na; Ding, Pan; He, Le Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902338	journal	November 2019
Solar-powered synthesis of hydrocarbons from carbon dioxide and water Kunene, Thabiso; Xiong, Lu; Rosenthal, Joel Proceedings of the National Academy of Sciences https://doi.org/10.1073/pnas.1904856116	journal	May 2019
Tuning of CO ₂ Reduction Selectivity on Metal Electrocatalysts Wang, Yuhang; Liu, Junlang; Wang, Yifei Small, Vol. 13, Issue 43 https://doi.org/10.1002/smll.201701809	journal	September 2017
Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron- and Nitrogen-Co-doped Nanodiamond Liu, Yanming; Zhang, Yujing; Cheng, Kai Angewandte Chemie, Vol. 129, Issue 49 https://doi.org/10.1002/ange.201706311	journal	October 2017
Adsorption of CO₂ on Heterostructures of Bi₂O₃ Nanocluster-Modified TiO₂ and the Role of Reduction in Promoting CO₂ Activation Nolan, Michael ACS Omega, Vol. 3, Issue 10 https://doi.org/10.1021/acsomega.8b01957	journal	October 2018

Similar Records

Efficient Conversion of CO ₂ to CO Using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

Journal Article · Wed Apr 08 00:00:00 EDT 2015 · Journal of the American Chemical Society · OSTI ID:1210503

Medina-Ramos, Jonnathan; Pupillo, Rachel C.; Keane, Thomas P.; +2 more

Efficient Conversion of CO₂ to CO Using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

Journal Article · Thu Feb 19 00:00:00 EST 2015 · Journal of the American Chemical Society · OSTI ID:1210503

Medina-Ramos, Jonnathan; Pupillo, Rachel C.; Keane, Thomas P.; +2 more

Efficient electrochemical CO2 reduction to CO by metal and nitrogen co-doped carbon catalysts derived from pharmaceutical wastes adsorbed on commercial carbon nanotubes

Journal Article · Wed Feb 01 00:00:00 EST 2023 · Chemical Engineering Journal · OSTI ID:1210503

Gang, Yang; Li, Boyang; Fang, Siyuan; +8 more

Related Subjects

catalysis (heterogeneous)
solar (fuels)
energy storage (including batteries and capacitors)
hydrogen and fuel cells
electrodes - solar
mechanical behavior
charge transport
materials and chemistry by design
synthesis (novel materials)

Title: Efficient Conversion of CO2 to CO using Tin and Other Inexpensive and Easily Prepared Post-Transition Metal Catalysts

Citation Formats

References (37)

Cited By (56)

Similar Records

Related Subjects