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Title: Metal-silicate catalysts: Single site, mesoporous systems without templates

Abstract

The textural properties of a family of silicate and mixed metal-silicate materials prepared by a nonaqueous sol-gel reaction involving the cubic silicate Si 8O 20(SnMe 3) 8 and metal chlorides MCl 4 (M = Si, Ti, Zr) cross-linking reagents are described. Nitrogen adsorption isotherm data is presented and surface area and pore size distribution analyses for several examples of these materials are developed and correlated with the ratio of cross-linking reagent and the cubic silicate building block at the time of synthesis. Significant surface area and pore size distributions that shift to higher pore diameters are observed as the ratio of cross-linking reagent-to-cubic building block increases. A simple strategy for simultaneously controlling the porosity of these matrices while homogeneously dispersing identical metal centers on their surfaces for next generation catalysts is described.

Authors:
; ; ; ; ; ; ;
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1210419
DOE Contract Number:
SC000997
Resource Type:
Journal Article
Resource Relation:
Journal Name: Science Letters Journal; Journal Volume: 4; Related Information: C3Bio partners with Purdue University (lead); Argonne National Laboratory; National Renewable Energy Laboratory; Northeastern University; University of Tennessee
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; catalysis (homogeneous), catalysis (heterogeneous), biofuels (including algae and biomass), bio-inspired, materials and chemistry by design, synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Barnes, Craig E., Sharp, Katherine, Albert, Austin A, Abbott, Joshua, Peretich, Michael E, Fulvio, Pasquale, Ciesielski, Peter N., and Donohoe, Bryon S. Metal-silicate catalysts: Single site, mesoporous systems without templates. United States: N. p., 2015. Web.
Barnes, Craig E., Sharp, Katherine, Albert, Austin A, Abbott, Joshua, Peretich, Michael E, Fulvio, Pasquale, Ciesielski, Peter N., & Donohoe, Bryon S. Metal-silicate catalysts: Single site, mesoporous systems without templates. United States.
Barnes, Craig E., Sharp, Katherine, Albert, Austin A, Abbott, Joshua, Peretich, Michael E, Fulvio, Pasquale, Ciesielski, Peter N., and Donohoe, Bryon S. 2015. "Metal-silicate catalysts: Single site, mesoporous systems without templates". United States. doi:.
@article{osti_1210419,
title = {Metal-silicate catalysts: Single site, mesoporous systems without templates},
author = {Barnes, Craig E. and Sharp, Katherine and Albert, Austin A and Abbott, Joshua and Peretich, Michael E and Fulvio, Pasquale and Ciesielski, Peter N. and Donohoe, Bryon S.},
abstractNote = {The textural properties of a family of silicate and mixed metal-silicate materials prepared by a nonaqueous sol-gel reaction involving the cubic silicate Si8O20(SnMe3)8 and metal chlorides MCl4 (M = Si, Ti, Zr) cross-linking reagents are described. Nitrogen adsorption isotherm data is presented and surface area and pore size distribution analyses for several examples of these materials are developed and correlated with the ratio of cross-linking reagent and the cubic silicate building block at the time of synthesis. Significant surface area and pore size distributions that shift to higher pore diameters are observed as the ratio of cross-linking reagent-to-cubic building block increases. A simple strategy for simultaneously controlling the porosity of these matrices while homogeneously dispersing identical metal centers on their surfaces for next generation catalysts is described.},
doi = {},
journal = {Science Letters Journal},
number = ,
volume = 4,
place = {United States},
year = 2015,
month = 1
}
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