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Title: Bimetallic catalysts for CO.sub.2 hydrogenation and H.sub.2 generation from formic acid and/or salts thereof

Abstract

The invention relates to a ligand that may be used to create a catalyst including a coordination complex is formed by the addition of two metals; Cp, Cp* or an unsubstituted or substituted .pi.-arene; and two coordinating solvent species or solvent molecules. The bimetallic catalyst may be used in the hydrogenation of CO.sub.2 to form formic acid and/or salts thereof, and in the dehydrogenation of formic acid and/or salts thereof to form H.sub.2 and CO.sub.2.

Inventors:
; ; ;
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1207345
Patent Number(s):
9,095,846
Application Number:
14/240,587
Assignee:
Brookhaven Science Associates, LLC (Upton, NY)
DOE Contract Number:  
AC02-98CH10886
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Sep 12
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES

Citation Formats

Hull, Jonathan F., Himeda, Yuichiro, Fujita, Etsuko, and Muckeman, James T. Bimetallic catalysts for CO.sub.2 hydrogenation and H.sub.2 generation from formic acid and/or salts thereof. United States: N. p., 2015. Web.
Hull, Jonathan F., Himeda, Yuichiro, Fujita, Etsuko, & Muckeman, James T. Bimetallic catalysts for CO.sub.2 hydrogenation and H.sub.2 generation from formic acid and/or salts thereof. United States.
Hull, Jonathan F., Himeda, Yuichiro, Fujita, Etsuko, and Muckeman, James T. Tue . "Bimetallic catalysts for CO.sub.2 hydrogenation and H.sub.2 generation from formic acid and/or salts thereof". United States. https://www.osti.gov/servlets/purl/1207345.
@article{osti_1207345,
title = {Bimetallic catalysts for CO.sub.2 hydrogenation and H.sub.2 generation from formic acid and/or salts thereof},
author = {Hull, Jonathan F. and Himeda, Yuichiro and Fujita, Etsuko and Muckeman, James T.},
abstractNote = {The invention relates to a ligand that may be used to create a catalyst including a coordination complex is formed by the addition of two metals; Cp, Cp* or an unsubstituted or substituted .pi.-arene; and two coordinating solvent species or solvent molecules. The bimetallic catalyst may be used in the hydrogenation of CO.sub.2 to form formic acid and/or salts thereof, and in the dehydrogenation of formic acid and/or salts thereof to form H.sub.2 and CO.sub.2.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {8}
}

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Works referenced in this record:

Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials
journal, May 2010