Materials Data on CsReF8 by Materials Project

Dataset · Tue Jul 14 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1204290· OSTI ID:1204290

The Materials Project

CsReF8 crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Cs1+ is bonded to twelve F1- atoms to form distorted edge-sharing CsF12 cuboctahedra. There are four shorter (3.24 Å) and eight longer (3.25 Å) Cs–F bond lengths. Re7+ is bonded in a 8-coordinate geometry to eight F1- atoms. There is four shorter (1.92 Å) and four longer (1.94 Å) Re–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to two equivalent Cs1+ and one Re7+ atom. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Cs1+ and one Re7+ atom.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1204290
• Report Number(s): mp-29842
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
CsReF8
Cs-F-Re