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Title: Emergence of reconfigurable wires and spinners via dynamic self-assembly

Abstract

Dissipative colloidal materials use energy to generate and maintain structural complexity. The energy injection rate, and properties of the environment are important control parameters that influence the outcome of dynamic self-assembly. Here we demonstrate that dispersions of magnetic microparticles confined at the air-liquid interface, and energized by a uniaxial in-plane alternating magnetic field, self-assemble into a variety of structures that range from pulsating clusters and single-particle-thick wires to dynamic arrays of spinners (self-assembled short chains) rotating in either direction. The spinners emerge via spontaneous breaking of the uniaxial symmetry of the energizing magnetic field. Demonstration of the formation and disaggregation of particle assemblies suggests strategies to form new meso-scale structures with the potential to perform functions such as mixing and sensing.

Authors:
 [1];  [2];  [3];  [2];  [4]
  1. Jozef Stefan Institute, Ljubliana (Slovenia). Complex Matter Dept.
  2. Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States). Dept. of Engineering Science and Applied Mathematics.
  3. Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry and Chemical Biology.
  4. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division
OSTI Identifier:
1200895
Alternate Identifier(s):
OSTI ID: 1392516
Grant/Contract Number:  
AC02-06CH11357; FG02-00ER45852
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Kokot, Gasper, Piet, David, Whitesides, George M., Aranson, Igor S., and Snezhko, Alexey. Emergence of reconfigurable wires and spinners via dynamic self-assembly. United States: N. p., 2015. Web. doi:10.1038/srep09528.
Kokot, Gasper, Piet, David, Whitesides, George M., Aranson, Igor S., & Snezhko, Alexey. Emergence of reconfigurable wires and spinners via dynamic self-assembly. United States. doi:10.1038/srep09528.
Kokot, Gasper, Piet, David, Whitesides, George M., Aranson, Igor S., and Snezhko, Alexey. Thu . "Emergence of reconfigurable wires and spinners via dynamic self-assembly". United States. doi:10.1038/srep09528. https://www.osti.gov/servlets/purl/1200895.
@article{osti_1200895,
title = {Emergence of reconfigurable wires and spinners via dynamic self-assembly},
author = {Kokot, Gasper and Piet, David and Whitesides, George M. and Aranson, Igor S. and Snezhko, Alexey},
abstractNote = {Dissipative colloidal materials use energy to generate and maintain structural complexity. The energy injection rate, and properties of the environment are important control parameters that influence the outcome of dynamic self-assembly. Here we demonstrate that dispersions of magnetic microparticles confined at the air-liquid interface, and energized by a uniaxial in-plane alternating magnetic field, self-assemble into a variety of structures that range from pulsating clusters and single-particle-thick wires to dynamic arrays of spinners (self-assembled short chains) rotating in either direction. The spinners emerge via spontaneous breaking of the uniaxial symmetry of the energizing magnetic field. Demonstration of the formation and disaggregation of particle assemblies suggests strategies to form new meso-scale structures with the potential to perform functions such as mixing and sensing.},
doi = {10.1038/srep09528},
journal = {Scientific Reports},
number = ,
volume = 5,
place = {United States},
year = {Thu Mar 26 00:00:00 EDT 2015},
month = {Thu Mar 26 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 17 works
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