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Title: Diameter Control and Photoluminescence of ZnO Nanorods from Trialkylamines

Abstract

A novel solution method to control the diameter of ZnO nanorods is reported. Small diameter (2-3 nm) nanorods were synthesized from trihexylamine, and large diameter (50–80 nm) nanorods were synthesized by increasing the alkyl chain length to tridodecylamine. The defect (green) emission of the photoluminescence (PL) spectra of the nanorods varies with diameter, and can thus be controlled by the diameter control. The small ZnO nanorods have strong green emission, while the large diameter nanorods exhibit a remarkably suppressed green band. We show that this observation supports surface oxygen vacancies as the defect that gives rise to the green emission.

Authors:
; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1198457
Grant/Contract Number:
FG02-03ER15463
Resource Type:
Journal Article: Published Article
Journal Name:
Journal of Nanomaterials
Additional Journal Information:
Journal Volume: 2007; Related Information: CHORUS Timestamp: 2016-08-11 13:05:11; Journal ID: ISSN 1687-4110
Publisher:
Hindawi Publishing Corporation
Country of Publication:
Egypt
Language:
English

Citation Formats

Andelman, Tamar, Gong, Yinyan, Neumark, Gertrude, and O'Brien, Stephen. Diameter Control and Photoluminescence of ZnO Nanorods from Trialkylamines. Egypt: N. p., 2007. Web. doi:10.1155/2007/73824.
Andelman, Tamar, Gong, Yinyan, Neumark, Gertrude, & O'Brien, Stephen. Diameter Control and Photoluminescence of ZnO Nanorods from Trialkylamines. Egypt. doi:10.1155/2007/73824.
Andelman, Tamar, Gong, Yinyan, Neumark, Gertrude, and O'Brien, Stephen. Mon . "Diameter Control and Photoluminescence of ZnO Nanorods from Trialkylamines". Egypt. doi:10.1155/2007/73824.
@article{osti_1198457,
title = {Diameter Control and Photoluminescence of ZnO Nanorods from Trialkylamines},
author = {Andelman, Tamar and Gong, Yinyan and Neumark, Gertrude and O'Brien, Stephen},
abstractNote = {A novel solution method to control the diameter of ZnO nanorods is reported. Small diameter (2-3 nm) nanorods were synthesized from trihexylamine, and large diameter (50–80 nm) nanorods were synthesized by increasing the alkyl chain length to tridodecylamine. The defect (green) emission of the photoluminescence (PL) spectra of the nanorods varies with diameter, and can thus be controlled by the diameter control. The small ZnO nanorods have strong green emission, while the large diameter nanorods exhibit a remarkably suppressed green band. We show that this observation supports surface oxygen vacancies as the defect that gives rise to the green emission.},
doi = {10.1155/2007/73824},
journal = {Journal of Nanomaterials},
number = ,
volume = 2007,
place = {Egypt},
year = {Mon Jan 01 00:00:00 EST 2007},
month = {Mon Jan 01 00:00:00 EST 2007}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1155/2007/73824

Citation Metrics:
Cited by: 2works
Citation information provided by
Web of Science

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