Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

Brauer, C. S.; Blake, T. A.; Guenther, A. B.; Sharpe, S. W.; Sams, R. L.; Johnson, T. J.

doi:10.5194/amt-7-3839-2014

Title: Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

Journal Article · Wed Nov 19 00:00:00 EST 2014 · Atmospheric Measurement Techniques (Online)

DOI:https://doi.org/10.5194/amt-7-3839-2014· OSTI ID:1197861

Brauer, C. S. ^[1]; Blake, T. A. ^[1]; Guenther, A. B. ^[1]; Sharpe, S. W. ^[1]; Sams, R. L. ^[1]; Johnson, T. J. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Isoprene (C₅H₈, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) and is one of the primary contributors to annual global VOC emissions. Isoprene is produced primarily by vegetation as well as anthropogenic sources, and its OH- and O₃-initiated oxidations are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, limiting the ability to quantify isoprene emissions via remote or in situ infrared detection. We thus report absorption cross sections and integrated band intensities for isoprene in the 600–6500 cm^-1 region. The pressure-broadened (1 atmosphere N₂) spectra were recorded at 278, 298, and 323 K in a 19.94 cm path-length cell at 0.112 cm^-1 resolution, using a Bruker IFS 66v/S Fourier transform infrared (FTIR) spectrometer. Composite spectra are derived from a minimum of seven isoprene sample pressures, each at one of three temperatures, and the number densities are normalized to 296 K and 1 atm.

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Sponsoring Organization:: USDOE Office of Defense Programs (DP)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1197861

Journal Information:: Atmospheric Measurement Techniques (Online), Journal Name: Atmospheric Measurement Techniques (Online) Vol. 7 Journal Issue: 11; ISSN 1867-8548

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 26 works

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