Synergistic stabilization of metastable Fe23B6 and γ-Fe in undercooled Fe83B17

Quirinale, D. G.; Rustan, G. E.; Kreyssig, A.; Goldman, A. I.

doi:10.1063/1.4922802

Title: Synergistic stabilization of metastable Fe₂₃B₆ and γ-Fe in undercooled Fe₈₃B₁₇

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4922802· OSTI ID:1186931

Quirinale, D. G. ^[1]; Rustan, G. E. ^[1]; Kreyssig, A. ^[2]; Goldman, A. I. ^[2]

Iowa State Univ., Ames, IA (United States)
Ames Lab., and Iowa State Univ., Ames, IA (United States)

Previous investigations of undercooled liquid Fe₈₃B₁₇ near the eutectic composition have found that metastable crystalline phases, such as Fe₂₃B₆, can be formed and persist down to ambient temperature even for rather modest cooling rates. Using time-resolved high-energy x-ray diffraction on electrostatically levitated samples of Fe₈₃B₁₇, we demonstrate that the Fe₂₃B₆ metastable phase and fcc γ-Fe grow coherently from the undercooled Fe₈₃B₁₇ liquid and effectively suppress the formation of the equilibrium Fe₂B + bcc α-Fe phases. Here, the stabilization of γ-Fe offers another opportunity for experimental investigations of magnetism in metastable fcc iron.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF)

Grant/Contract Number:: DMR-1308099

OSTI ID:: 1186931

Journal Information:: Applied Physics Letters, Vol. 106, Issue 24; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 20 works

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