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Title: Recent progress in enhancing solar-to-hydrogen efficiency

Abstract

Solar water splitting is a promising and ideal route for renewable production of hydrogen by using the most abundant resources of solar light and water. Focusing on the working principal of solar water splitting, including photon absorption and exciton generation in semiconductor, exciton separation and transfer to the surface of semiconductor, and respective electron and hole reactions with absorbed surface species to generate hydrogen and oxygen, this review covers the comprehensive efforts and findings made in recent years on the improvement for the solar-to-hydrogen efficiency (STH) determined by a combination of light absorption process, charge separation and migration, and catalytic reduction and oxidation reactions. Critical evaluation is attempted on the strategies for improving solar light harvesting efficiency, enhancing charge separation and migration, and improving surface reactions. Towards the end, new and emerging technologies for boosting the STH efficiency are discussed on multiple exciton generation, up-conversion, multi-strategy modifications and the potentials of organometal hybrid perovskite materials.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [3]
  1. Hohai University, China
  2. ORNL
  3. University of Delaware
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Laboratory Directed Research and Development (LDRD) Program
OSTI Identifier:
1185452
DOE Contract Number:
DE-AC05-00OR22725
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Power Sources; Journal Volume: 280
Country of Publication:
United States
Language:
English

Citation Formats

Chen, Jianqing, Yang, Donghui, Song, Dan, Jiang, Jinghua, Ma, Aibin, Hu, Michael Z., and Ni, Chaoying. Recent progress in enhancing solar-to-hydrogen efficiency. United States: N. p., 2015. Web. doi:10.1016/j.jpowsour.2015.01.073.
Chen, Jianqing, Yang, Donghui, Song, Dan, Jiang, Jinghua, Ma, Aibin, Hu, Michael Z., & Ni, Chaoying. Recent progress in enhancing solar-to-hydrogen efficiency. United States. doi:10.1016/j.jpowsour.2015.01.073.
Chen, Jianqing, Yang, Donghui, Song, Dan, Jiang, Jinghua, Ma, Aibin, Hu, Michael Z., and Ni, Chaoying. Thu . "Recent progress in enhancing solar-to-hydrogen efficiency". United States. doi:10.1016/j.jpowsour.2015.01.073.
@article{osti_1185452,
title = {Recent progress in enhancing solar-to-hydrogen efficiency},
author = {Chen, Jianqing and Yang, Donghui and Song, Dan and Jiang, Jinghua and Ma, Aibin and Hu, Michael Z. and Ni, Chaoying},
abstractNote = {Solar water splitting is a promising and ideal route for renewable production of hydrogen by using the most abundant resources of solar light and water. Focusing on the working principal of solar water splitting, including photon absorption and exciton generation in semiconductor, exciton separation and transfer to the surface of semiconductor, and respective electron and hole reactions with absorbed surface species to generate hydrogen and oxygen, this review covers the comprehensive efforts and findings made in recent years on the improvement for the solar-to-hydrogen efficiency (STH) determined by a combination of light absorption process, charge separation and migration, and catalytic reduction and oxidation reactions. Critical evaluation is attempted on the strategies for improving solar light harvesting efficiency, enhancing charge separation and migration, and improving surface reactions. Towards the end, new and emerging technologies for boosting the STH efficiency are discussed on multiple exciton generation, up-conversion, multi-strategy modifications and the potentials of organometal hybrid perovskite materials.},
doi = {10.1016/j.jpowsour.2015.01.073},
journal = {Journal of Power Sources},
number = ,
volume = 280,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}