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Title: Impact of the oxygen defects and the hydrogen concentration on the surface of tetragonal and monoclinic ZrO2 on the reduction rates of stearic acid on Ni/ZrO2

Abstract

The effect of the physicochemical properties of ZrO2 phases on the activity of Ni/ZrO2 catalysts for hydrodeoxygenation of stearic acid are described. A synergistic interaction between Ni and ZrO2 support was found. The effect is greatest for the monoclinic phase of ZrO2.

Authors:
; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1184913
Report Number(s):
PNNL-SA-105470
3158a; 3158; KC0302010
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemistry - A European Journal, 21(6):2423-2434
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Foraita, Sebastian D., Fulton, John L., Chase, Zizwe A., Vjunov, Aleksei, Xu, Pinghong, Barath, Eszter, Camaioni, Donald M., Zhao, Chen, and Lercher, Johannes A.. Impact of the oxygen defects and the hydrogen concentration on the surface of tetragonal and monoclinic ZrO2 on the reduction rates of stearic acid on Ni/ZrO2. United States: N. p., 2015. Web. doi:10.1002/chem.201405312.
Foraita, Sebastian D., Fulton, John L., Chase, Zizwe A., Vjunov, Aleksei, Xu, Pinghong, Barath, Eszter, Camaioni, Donald M., Zhao, Chen, & Lercher, Johannes A.. Impact of the oxygen defects and the hydrogen concentration on the surface of tetragonal and monoclinic ZrO2 on the reduction rates of stearic acid on Ni/ZrO2. United States. doi:10.1002/chem.201405312.
Foraita, Sebastian D., Fulton, John L., Chase, Zizwe A., Vjunov, Aleksei, Xu, Pinghong, Barath, Eszter, Camaioni, Donald M., Zhao, Chen, and Lercher, Johannes A.. Mon . "Impact of the oxygen defects and the hydrogen concentration on the surface of tetragonal and monoclinic ZrO2 on the reduction rates of stearic acid on Ni/ZrO2". United States. doi:10.1002/chem.201405312.
@article{osti_1184913,
title = {Impact of the oxygen defects and the hydrogen concentration on the surface of tetragonal and monoclinic ZrO2 on the reduction rates of stearic acid on Ni/ZrO2},
author = {Foraita, Sebastian D. and Fulton, John L. and Chase, Zizwe A. and Vjunov, Aleksei and Xu, Pinghong and Barath, Eszter and Camaioni, Donald M. and Zhao, Chen and Lercher, Johannes A.},
abstractNote = {The effect of the physicochemical properties of ZrO2 phases on the activity of Ni/ZrO2 catalysts for hydrodeoxygenation of stearic acid are described. A synergistic interaction between Ni and ZrO2 support was found. The effect is greatest for the monoclinic phase of ZrO2.},
doi = {10.1002/chem.201405312},
journal = {Chemistry - A European Journal, 21(6):2423-2434},
number = ,
volume = ,
place = {United States},
year = {Mon Feb 02 00:00:00 EST 2015},
month = {Mon Feb 02 00:00:00 EST 2015}
}