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Title: Hydrogen storage compositions

Patent ·
OSTI ID:1176425

Compositions for hydrogen storage and methods of making such compositions employ an alloy that exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The composition includes a ternary alloy including magnesium, boron and a metal and a metal hydride. The ternary alloy and the metal hydride are present in an amount sufficient to render the composition capable of hydrogen storage. The molar ratio of the metal to magnesium and boron in the alloy is such that the alloy exhibits reversible formation/deformation of BH.sub.4.sup.- anions. The hydrogen storage composition is prepared by combining magnesium, boron and a metal to prepare a ternary alloy and combining the ternary alloy with a metal hydride to form the hydrogen storage composition.

Research Organization:
HRL Laboratories, LLC, Malibu, CA (United States)
Sponsoring Organization:
USDOE
Assignee:
HRL Laboratories, LLC (Malibu, CA)
Patent Number(s):
7,927,507
Application Number:
12/404,201
OSTI ID:
1176425
Resource Relation:
Patent File Date: 2009 Mar 13
Country of Publication:
United States
Language:
English

References (9)

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Reversible Storage of Hydrogen in Destabilized LiBH 4 journal March 2005
Stability and Reversibility of LiBH 4 journal January 2008
Fabrication and hydrogen storage property study of nanostructured Mg–Ni–B ternary alloys journal June 2009
Reversible hydrogen storage in metal-doped Mg–LiBH4 composites journal April 2009
Structure, transport and magnetic properties of MgNi3B2 journal January 2007
NMR Confirmation for Formation of [B 12 H 12 ] 2- Complexes during Hydrogen Desorption from Metal Borohydrides journal March 2008
On the possibility of metal hydride formation journal June 1998
Tetrahydroborates as new hydrogen storage materials journal May 2007