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Title: Hydrogenolysis of 6-carbon sugars and other organic compounds

Abstract

Methods for hydrogenolysis are described which use a Re-containing multimetallic catalyst for hydrogenolysis of both C--O and C--C bonds. Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 6-carbon sugar, sugar alcohol, or glycerol are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol.

Inventors:
; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1175197
Patent Number(s):
6,841,085
Application Number:
10/000,836
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC06-76RL01830
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Werpy, Todd A., Frye, Jr., John G., Zacher, Alan H., and Miller, Dennis J. Hydrogenolysis of 6-carbon sugars and other organic compounds. United States: N. p., 2005. Web.
Werpy, Todd A., Frye, Jr., John G., Zacher, Alan H., & Miller, Dennis J. Hydrogenolysis of 6-carbon sugars and other organic compounds. United States.
Werpy, Todd A., Frye, Jr., John G., Zacher, Alan H., and Miller, Dennis J. Tue . "Hydrogenolysis of 6-carbon sugars and other organic compounds". United States. https://www.osti.gov/servlets/purl/1175197.
@article{osti_1175197,
title = {Hydrogenolysis of 6-carbon sugars and other organic compounds},
author = {Werpy, Todd A. and Frye, Jr., John G. and Zacher, Alan H. and Miller, Dennis J.},
abstractNote = {Methods for hydrogenolysis are described which use a Re-containing multimetallic catalyst for hydrogenolysis of both C--O and C--C bonds. Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 6-carbon sugar, sugar alcohol, or glycerol are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol.},
doi = {},
url = {https://www.osti.gov/biblio/1175197}, journal = {},
number = ,
volume = ,
place = {United States},
year = {2005},
month = {1}
}

Patent:

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