High Methane Storage Capacity in Aluminum Metal–Organic Frameworks
Abstract
The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal–organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm3 cm–3 at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm3 cm–33 under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm3 cm–3, and between 5 and 80 bar, 230 cm3 cm–3.
- Authors:
-
- Department of Chemistry, University of California−Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, and Kavli Energy NanoSciences Institute at Berkeley, University of California−Berkeley, Berkeley, California 94720, United States
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1174086
- Alternate Identifier(s):
- OSTI ID: 1383987
- Grant/Contract Number:
- SC0001015; AC02-05CH11231; HDTRA 1-12-1-0053
- Resource Type:
- Journal Article: Published Article
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Name: Journal of the American Chemical Society Journal Volume: 136 Journal Issue: 14; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing); hydrocarbons; ligands; aluminum; metal organic framework materials
Citation Formats
Gándara, Felipe, Furukawa, Hiroyasu, Lee, Seungkyu, and Yaghi, Omar M. High Methane Storage Capacity in Aluminum Metal–Organic Frameworks. United States: N. p., 2014.
Web. doi:10.1021/ja501606h.
Gándara, Felipe, Furukawa, Hiroyasu, Lee, Seungkyu, & Yaghi, Omar M. High Methane Storage Capacity in Aluminum Metal–Organic Frameworks. United States. https://doi.org/10.1021/ja501606h
Gándara, Felipe, Furukawa, Hiroyasu, Lee, Seungkyu, and Yaghi, Omar M. 2014.
"High Methane Storage Capacity in Aluminum Metal–Organic Frameworks". United States. https://doi.org/10.1021/ja501606h.
@article{osti_1174086,
title = {High Methane Storage Capacity in Aluminum Metal–Organic Frameworks},
author = {Gándara, Felipe and Furukawa, Hiroyasu and Lee, Seungkyu and Yaghi, Omar M.},
abstractNote = {The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal–organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm3 cm–3 at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm3 cm–33 under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm3 cm–3, and between 5 and 80 bar, 230 cm3 cm–3.},
doi = {10.1021/ja501606h},
url = {https://www.osti.gov/biblio/1174086},
journal = {Journal of the American Chemical Society},
issn = {0002-7863},
number = 14,
volume = 136,
place = {United States},
year = {Wed Feb 26 00:00:00 EST 2014},
month = {Wed Feb 26 00:00:00 EST 2014}
}
Web of Science
Works referenced in this record:
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999
- Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H.
- Science, Vol. 283, Issue 5405, p. 1148-1150
A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
- Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
- Nature, Vol. 427, Issue 6974, p. 523-527
Hydrogen Storage in Metal–Organic Frameworks
journal, September 2011
- Suh, Myunghyun Paik; Park, Hye Jeong; Prasad, Thazhe Kootteri
- Chemical Reviews, Vol. 112, Issue 2, p. 782-835
Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
journal, October 2010
- Meek, Scott T.; Greathouse, Jeffery A.; Allendorf, Mark D.
- Advanced Materials, Vol. 23, Issue 2
Evaluating metal–organic frameworks for natural gas storage
journal, January 2014
- Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.
- Chemical Science, Vol. 5, Issue 1, p. 32-51
Methane storage in advanced porous materials
journal, January 2012
- Makal, Trevor A.; Li, Jian-Rong; Lu, Weigang
- Chemical Society Reviews, Vol. 41, Issue 23
Magnetic Anisotropy of the Antiferromagnetic Ring [Cr8F8Piv16]
journal, January 2002
- van Slageren, Joris; Sessoli, Roberta; Gatteschi, Dante
- Chemistry - A European Journal, Vol. 8, Issue 1
Switching of myosin-V motion between the lever-arm swing and Brownian search-and-catch
journal, January 2012
- Fujita, Keisuke; Iwaki, Mitsuhiro; Iwane, Atsuko H.
- Nature Communications, Vol. 3, Issue 1
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010
- Bloch, Eric D.; Britt, David; Lee, Chain
- Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010
- Furukawa, H.; Ko, N.; Go, Y. B.
- Science, Vol. 329, Issue 5990, p. 424-428
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Metal–organic frameworks—prospective industrial applications
journal, January 2006
- Mueller, U.; Schubert, M.; Teich, F.
- J. Mater. Chem., Vol. 16, Issue 7
Synthesis and Hydrogen Storage Properties of Be 12 (OH) 12 (1,3,5-benzenetribenzoate) 4
journal, October 2009
- Sumida, Kenji; Hill, Matthew R.; Horike, Satoshi
- Journal of the American Chemical Society, Vol. 131, Issue 42
A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n]
journal, June 2000
- Noro, Shin-ichiro; Kitagawa, Susumu; Kondo, Mitsuru
- Angewandte Chemie International Edition, Vol. 39, Issue 12, p. 2081-2084
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units
journal, February 2005
- Rosi, Nathaniel L.; Kim, Jaheon; Eddaoudi, Mohamed
- Journal of the American Chemical Society, Vol. 127, Issue 5, p. 1504-1518
Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework
journal, January 2006
- Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael
- Chemical Communications, Issue 9
A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration
journal, March 2004
- Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse
- Chemistry - A European Journal, Vol. 10, Issue 6
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
journal, November 2012
- Cook, Timothy R.; Zheng, Yao-Rong; Stang, Peter J.
- Chemical Reviews, Vol. 113, Issue 1
A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake
journal, January 2012
- Stoeck, Ulrich; Krause, Simon; Bon, Volodymyr
- Chemical Communications, Vol. 48, Issue 88
The Magnetic Möbius Strip: Synthesis, Structure, and Magnetic Studies of Odd-Numbered Antiferromagnetically Coupled Wheels
journal, October 2004
- Cador, Olivier; Gatteschi, Dante; Sessoli, Roberta
- Angewandte Chemie International Edition, Vol. 43, Issue 39
Systematic modulation and enhancement of CO2 : N2 selectivity and water stability in an isoreticular series of bio-MOF-11 analogues
journal, January 2013
- Li, Tao; Chen, De-Li; Sullivan, Jeanne E.
- Chemical Science, Vol. 4, Issue 4
Hydrogen storage in metal–organic frameworks
journal, January 2009
- Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314
A partially interpenetrated metal–organic framework for selective hysteretic sorption of carbon dioxide
journal, June 2012
- Yang, Sihai; Lin, Xiang; Lewis, William
- Nature Materials, Vol. 11, Issue 8
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
journal, August 2010
- Corma, A.; García, H.; Llabrés i Xamena, F. X.
- Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655
High H2 Adsorption by Coordination-Framework Materials
journal, November 2006
- Lin, Xiang; Jia, Junhua; Zhao, Xuebo
- Angewandte Chemie International Edition, Vol. 45, Issue 44
[Al 4 (OH) 2 (OCH 3 ) 4 (H 2 N-bdc) 3 ]⋅ x H 2 O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick
journal, June 2009
- Ahnfeldt, Tim; Guillou, Nathalie; Gunzelmann, Daniel
- Angewandte Chemie International Edition, Vol. 48, Issue 28
The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
- Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
- Science, Vol. 341, Issue 6149, p. 1230444-1230444
Functional Porous Coordination Polymers
journal, April 2004
- Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
- Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
- Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
- Nature, Vol. 402, Issue 6759, p. 276-279
Methane storage in metal organic frameworks
journal, January 2012
- Konstas, Kristina; Osl, Theresa; Yang, Yunxia
- Journal of Materials Chemistry, Vol. 22, Issue 33
Phosphonate and sulfonate metal organic frameworks
journal, January 2009
- Shimizu, George K. H.; Vaidhyanathan, Ramanathan; Taylor, Jared M.
- Chemical Society Reviews, Vol. 38, Issue 5
Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake
journal, January 2008
- Ma, Shengqian; Sun, Daofeng; Simmons, Jason M.
- Journal of the American Chemical Society, Vol. 130, Issue 3
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008
- Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
journal, July 2013
- Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894
BioMOFs: Metal-Organic Frameworks for Biological and Medical Applications
journal, July 2010
- McKinlay, Alistair C.; Morris, Russell E.; Horcajada, Patricia
- Angewandte Chemie International Edition, Vol. 49, Issue 36, p. 6260-6266
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011
- O’Keeffe, Michael; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 675-702