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Title: Studies on the Mechanisms of Methyl Iodide Adsorption and Iodine Retention on Silver-Mordenite

Abstract

Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I 2) to form AgI. However the mechanisms for organoiodine capture are not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent.

Authors:
 [1];  [2]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  2. Idaho National Lab. (INL), Idaho Falls, ID (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
OSTI Identifier:
1171585
Report Number(s):
SAND2014-17740R
537547
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Nenoff, Tina Maria, and Soelberg, Nick. Studies on the Mechanisms of Methyl Iodide Adsorption and Iodine Retention on Silver-Mordenite. United States: N. p., 2014. Web. doi:10.2172/1171585.
Nenoff, Tina Maria, & Soelberg, Nick. Studies on the Mechanisms of Methyl Iodide Adsorption and Iodine Retention on Silver-Mordenite. United States. doi:10.2172/1171585.
Nenoff, Tina Maria, and Soelberg, Nick. Mon . "Studies on the Mechanisms of Methyl Iodide Adsorption and Iodine Retention on Silver-Mordenite". United States. doi:10.2172/1171585. https://www.osti.gov/servlets/purl/1171585.
@article{osti_1171585,
title = {Studies on the Mechanisms of Methyl Iodide Adsorption and Iodine Retention on Silver-Mordenite},
author = {Nenoff, Tina Maria and Soelberg, Nick},
abstractNote = {Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I2) to form AgI. However the mechanisms for organoiodine capture are not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent.},
doi = {10.2172/1171585},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Sep 01 00:00:00 EDT 2014},
month = {Mon Sep 01 00:00:00 EDT 2014}
}

Technical Report:

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