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Title: Physical properties of V 1-xTi xO₂ (0 < x < 0.187) single crystals

Abstract

Free standing, low strain, single crystals of pure and titanium doped VO₂ were grown out of an excess of V ₂O₅ using high temperature solution growth techniques. At T MI ~ 340 K, pure VO₂ exhibits a clear first-order phase transition from a high-temperature paramagnetic tetragonal phase (R) to a low-temperature non-magnetic monoclinic phase (M1). With Ti doping, another monoclinic phase (M2) emerges between the R and M1 phases. The phase transition temperature between R and M2 increases with increasing Ti doping while the transition temperature between M2 and M1 decreases.

Authors:
 [1];  [2];  [1];  [1]
  1. Ames Laboratory, Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
  2. Iowa State University, Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1170237
Alternate Identifier(s):
OSTI ID: 1201665; OSTI ID: 1421205
Grant/Contract Number:
AC02-07CH11358
Resource Type:
Journal Article: Published Article
Journal Name:
APL Materials
Additional Journal Information:
Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2166-532X
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., and Canfield, Paul C. Physical properties of V 1-xTixO₂ (0 < x < 0.187) single crystals. United States: N. p., 2015. Web. doi:10.1063/1.4908245.
Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., & Canfield, Paul C. Physical properties of V 1-xTixO₂ (0 < x < 0.187) single crystals. United States. doi:10.1063/1.4908245.
Kong, Tai, Masters, Morgan W., Bud’ko, Sergey L., and Canfield, Paul C. Fri . "Physical properties of V 1-xTixO₂ (0 < x < 0.187) single crystals". United States. doi:10.1063/1.4908245.
@article{osti_1170237,
title = {Physical properties of V 1-xTixO₂ (0 < x < 0.187) single crystals},
author = {Kong, Tai and Masters, Morgan W. and Bud’ko, Sergey L. and Canfield, Paul C.},
abstractNote = {Free standing, low strain, single crystals of pure and titanium doped VO₂ were grown out of an excess of V ₂O₅ using high temperature solution growth techniques. At TMI ~ 340 K, pure VO₂ exhibits a clear first-order phase transition from a high-temperature paramagnetic tetragonal phase (R) to a low-temperature non-magnetic monoclinic phase (M1). With Ti doping, another monoclinic phase (M2) emerges between the R and M1 phases. The phase transition temperature between R and M2 increases with increasing Ti doping while the transition temperature between M2 and M1 decreases.},
doi = {10.1063/1.4908245},
journal = {APL Materials},
number = 4,
volume = 3,
place = {United States},
year = {Fri Feb 13 00:00:00 EST 2015},
month = {Fri Feb 13 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1063/1.4908245

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

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