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Title: A Three-Dimensional Microporous Metal-Metalloporphyrin Framework

Abstract

A new porphyrin-based microporous MOF, {Mn(II) 0.5[Mn(II) 4Cl(Mn(III)Cl-ttzpp) 2(H 2O) 4]}·(DEF) 20·(CH 3OH) 18·(H 2O) 12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C 2H 2/CH 4 separation at room temperature.

Authors:
; ; ; ; ; ; ;  [1];  [2];  [2];  [2]
  1. Ames
  2. (
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
OTHER
OSTI Identifier:
1168522
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorg. Chem.; Journal Volume: 54; Journal Issue: (1) ; 01, 2015
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Guo, Zhiyong, Yan, Dan, Wang, Hailong, Tesfagaber, Daniel, Li, Xinle, Chen, Yusheng, Huang, Wenyu, Chen, Banglin, Texas-SA), UC), and Iowa State). A Three-Dimensional Microporous Metal-Metalloporphyrin Framework. United States: N. p., 2015. Web. doi:10.1021/ic502116k.
Guo, Zhiyong, Yan, Dan, Wang, Hailong, Tesfagaber, Daniel, Li, Xinle, Chen, Yusheng, Huang, Wenyu, Chen, Banglin, Texas-SA), UC), & Iowa State). A Three-Dimensional Microporous Metal-Metalloporphyrin Framework. United States. doi:10.1021/ic502116k.
Guo, Zhiyong, Yan, Dan, Wang, Hailong, Tesfagaber, Daniel, Li, Xinle, Chen, Yusheng, Huang, Wenyu, Chen, Banglin, Texas-SA), UC), and Iowa State). Wed . "A Three-Dimensional Microporous Metal-Metalloporphyrin Framework". United States. doi:10.1021/ic502116k.
@article{osti_1168522,
title = {A Three-Dimensional Microporous Metal-Metalloporphyrin Framework},
author = {Guo, Zhiyong and Yan, Dan and Wang, Hailong and Tesfagaber, Daniel and Li, Xinle and Chen, Yusheng and Huang, Wenyu and Chen, Banglin and Texas-SA) and UC) and Iowa State)},
abstractNote = {A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.},
doi = {10.1021/ic502116k},
journal = {Inorg. Chem.},
number = (1) ; 01, 2015,
volume = 54,
place = {United States},
year = {Wed Jan 14 00:00:00 EST 2015},
month = {Wed Jan 14 00:00:00 EST 2015}
}