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Title: Methods and systems for the formation of cyclic carbonates

Abstract

Described herein are inventive methods for synthesis of cyclic carbonates from CO.sub.2 and epoxide. In some embodiments, the methods are carried out in the presence of a catalyst comprising an electrophilic halogen. In some embodiments, the methods are carried out in a flow reactor.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
Massachusetts Institute of Technology, Cambridge, MA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1166758
Patent Number(s):
8,921,580
Application Number:
13/826,539
Assignee:
Massachusetts Institute of Technology (Cambridge, MA) NETL
DOE Contract Number:  
FE0004271
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Mar 14
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hatton, Trevor Alan, Jamison, Timothy F, Kozak, Jennifer Aiden, Simeon, Fritz, and Wu, Jie. Methods and systems for the formation of cyclic carbonates. United States: N. p., 2014. Web.
Hatton, Trevor Alan, Jamison, Timothy F, Kozak, Jennifer Aiden, Simeon, Fritz, & Wu, Jie. Methods and systems for the formation of cyclic carbonates. United States.
Hatton, Trevor Alan, Jamison, Timothy F, Kozak, Jennifer Aiden, Simeon, Fritz, and Wu, Jie. Tue . "Methods and systems for the formation of cyclic carbonates". United States. doi:. https://www.osti.gov/servlets/purl/1166758.
@article{osti_1166758,
title = {Methods and systems for the formation of cyclic carbonates},
author = {Hatton, Trevor Alan and Jamison, Timothy F and Kozak, Jennifer Aiden and Simeon, Fritz and Wu, Jie},
abstractNote = {Described herein are inventive methods for synthesis of cyclic carbonates from CO.sub.2 and epoxide. In some embodiments, the methods are carried out in the presence of a catalyst comprising an electrophilic halogen. In some embodiments, the methods are carried out in a flow reactor.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 30 00:00:00 EST 2014},
month = {Tue Dec 30 00:00:00 EST 2014}
}

Patent:

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Works referenced in this record:

Et2SBr⋅SbCl5 Br: An Effective Reagent for Direct Bromonium-Induced Polyene Cyclizations
journal, October 2009

  • Snyder, Scott A.; Treitler, Daniel S.
  • Angewandte Chemie International Edition, Vol. 48, Issue 42, p. 7899-7903
  • DOI: 10.1002/anie.200903834

Intramolecularly two-centered cooperation catalysis for the synthesis of cyclic carbonates from CO2 and epoxides
journal, November 2008