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Title: Silver-catalyzed synthesis of amides from amines and aldehydes

Patent ·
OSTI ID:1163991
; ; ; ;

The invention provides a method for producing amides via the reaction of aldehydes and amines with oxygen adsorbed on a metallic silver or silver alloy catalyst. An exemplary reaction is shown in Scheme 1: (I), (II), (III). ##STR00001##

Research Organization:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-84ER13289
Assignee:
President and Fellows of Harvard College (Cambridge, MA)
Patent Number(s):
8,889,908
Application Number:
13/575,150
OSTI ID:
1163991
Resource Relation:
Patent File Date: 2011 Jan 25
Country of Publication:
United States
Language:
English

References (30)

Efficient CO Oxidation at Low Temperature on Au(111) † journal October 2006
Highly Efficient Oxidative Amidation of Aldehydes with Amine Hydrochloride Salts journal October 2006
Surface-Mediated Self-Coupling of Ethanol on Gold journal April 2009
Selective oxidation of propylamine to propionitrile and propionaldehyde on oxygen-covered gold journal January 2009
Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen journal December 2008
Mercury-Catalyzed Rearrangement of Ketoximes into Amides and Lactams in Acetonitrile journal June 2007
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2 journal August 2007
The oxidation of methanol on a silver (110) catalyst journal September 1978
Ruthenium-Catalyzed Oxidation of Alcohols into Amides journal June 2009
Direct Amide Synthesis from Alcohols and Amines by Phosphine-Free Ruthenium Catalyst Systems journal November 2009
Alcohol selective oxidation over modified foam-silver catalysts journal July 2004
Cell Surface Engineering by a Modified Staudinger Reaction journal March 2000
Process for the preparation of carboxamides by oxidation of aldehydes in the presence of amines patent-application May 2002
Cleavage of NH bonds by active oxygen on Ag(110): II. Selective oxidation of ethylamine to acetonitrile journal February 1990
Cleavage of N-H bonds by active oxygen on Ag(110): I. Ammonia journal October 1989
Process for Preparing Amides from Alcohols and Amines patent-application April 2009
Highly Selective Acylation of Dimethylamine Mediated by Oxygen Atoms on Metallic Gold Surfaces journal December 2009
Chemical Synthesis of Natural Product Peptides:  Coupling Methods for the Incorporation of Noncoded Amino Acids into Peptides journal October 1997
Generation of atomic oxygen on Ag(111) and Ag(110) using NO2: a TPD, LEED, HREELS, XPS and NRA study journal November 1995
Progress in hydroformylation and carbonylation journal December 1995
A study of the adsorption of oxygen on silver at high pressure by electron spectroscopy journal January 1979
Mild Amidation of Aldehydes with Amines Mediated by Lanthanide Catalysts journal January 2008
Synthesis of carboxamides from the catalyzed reaction of aldehydes and amines patent January 2002
Methanol oxidation/dehydrogenation over silver-gold alloy patent August 1980
Alkyne Carbonylation by Radicals: Tin-Radical-Catalyzed Synthesis of α-Methylene Amides from 1-Alkynes, Carbon Monoxide, and Amines journal February 2005
Selective production of hydrogen from partial oxidation of methanol over silver catalysts at low temperatures journal January 2004
Anticipating catalytic oxidation reactions on gold at high pressure (including liquid phase) from ultrahigh vacuum studies journal September 2008
N -Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles journal June 2009
Direct Dehydrogenative Amide Synthesis from Alcohols and Amines Catalyzed by γ-Alumina Supported Silver Cluster journal October 2009
Selectivity Control in Gold-Mediated Esterification of Methanol journal May 2009

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