Magnetoelectric coupling tuned by competing anisotropies in Mn1-xNixTiO3

Chi, Songxue; Ye, Feng; Zhou, H. D.; Choi, E. S.; Hwang, J.; Cao, Huibo; Fernandez-Baca, Jaime A.

doi:10.1103/PhysRevB.90.144429

Title: Magnetoelectric coupling tuned by competing anisotropies in ${Mn}_{1 - x} {Ni}_{x} {TiO}_{3}$

Journal Article · Fri Oct 24 00:00:00 EDT 2014 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.90.144429· OSTI ID:1163155

Chi, Songxue ^[1]; Ye, Feng ^[2]; Zhou, H. D. ^[3]; Choi, E. S. ^[4]; Hwang, J. ^[4]; Cao, Huibo ^[1]; Fernandez-Baca, Jaime A. ^[5]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Kentucky, Lexington, KY (United States). Dept. of Physics and Astronomy
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy; Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy

A flop of electric polarization from P$$\|$$c (P_c) to P$$\|$$ a (P_a) is observed in MnTiO₃ as a spin flop transtion is triggered by a c-axis magnetic field, H_$$\|$$c=7 T. The critical magnetic field for P_a is significantly reduced in Mn_1-xNi_xTiO₃ (x=0.33). Neutron diffraction measurements revealed similar magnetic arrangements for the two compositions where the ordered spins couple antiferromagnetically with their nearest intra- and inter-planar neighbors. In the x=0.33 system, the single ion anisotropies of Mn²⁺ and Ni²⁺ compete and give rise to an additional spin reorientation transition at TR. A magnetic field, H_c, aligns the spins along c for T_R_N. The rotation of the collinear spins away from the c-axis for T_R alters the magnetic point symmetry and gives rise to new ME susceptibility tensor form. Such linear ME response provides satisfactory explanation for behavior of field-induced electric polarization in both compositions. As the Ni content increases to x=0.5 and 0.68, the ME effect disappears as a new magnetic phase emerges.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; DMR-0654118

OSTI ID:: 1163155

Alternate ID(s):: OSTI ID: 1181043

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 90, Issue 14; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Title: Magnetoelectric coupling tuned by competing anisotropies in ${Mn}_{1 - x} {Ni}_{x} {TiO}_{3}$