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Title: Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine)

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Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
OSTI Identifier:
Report Number(s):
DOE Contract Number:  
Resource Type:
Journal Article
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 4
Country of Publication:
United States

Citation Formats

ONeal, K., Brinzari, T., Wright, J., Ma, C., Giri, S., Schlueter, J., Wang, Q., Jena, P., Liu, Z., and Musfeldt, J. Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine). United States: N. p., 2014. Web. doi:10.1038/srep06054.
ONeal, K., Brinzari, T., Wright, J., Ma, C., Giri, S., Schlueter, J., Wang, Q., Jena, P., Liu, Z., & Musfeldt, J. Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine). United States. doi:10.1038/srep06054.
ONeal, K., Brinzari, T., Wright, J., Ma, C., Giri, S., Schlueter, J., Wang, Q., Jena, P., Liu, Z., and Musfeldt, J. Wed . "Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine)". United States. doi:10.1038/srep06054.
title = {Pressure-Induced Magnetic Crossover Driven by Hydrogen Bonding in CuF2(H2O)2(3-chloropyridine)},
author = {ONeal, K. and Brinzari, T. and Wright, J. and Ma, C. and Giri, S. and Schlueter, J. and Wang, Q. and Jena, P. and Liu, Z. and Musfeldt, J.},
abstractNote = {},
doi = {10.1038/srep06054},
journal = {Scientific Reports},
number = ,
volume = 4,
place = {United States},
year = {2014},
month = {8}

Works referenced in this record:

Complexity in Strongly Correlated Electronic Systems
journal, July 2005

Magnetoelectric phase diagrams of orthorhombic R MnO 3 ( R = Gd , Tb, and Dy)
journal, June 2005

Molecules to build solids: high TC molecule-based magnets by design and recent revival of cyano complexes chemistry
journal, September 1999

Magnetic field effects on the far-infrared absorption in Mn 12 -acetate
journal, May 2001

Preparation, crystal structure and magnetic properties of Ni2(dpa)2(pyz)(H2O)4
journal, May 2011

Magnetoelectric effects in an organometallic quantum magnet
journal, April 2011

Recent Developments in Low-Dimensional Copper(II) Molecular Magnets
journal, March 2013

  • Landee, Christopher P.; Turnbull, Mark M.
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 13
  • DOI: 10.1002/ejic.201300133

Thermal-, Pressure- and Light-Induced Spin-Crossover Behaviour in the Two-Dimensional Hofmann-Like Coordination Polymer [Fe(3-Clpy) 2 Pd(CN) 4 ]
journal, January 2013

  • Martínez, Víctor; Arcís Castillo, Zulema; Muñoz, M. Carmen
  • European Journal of Inorganic Chemistry, Vol. 2013, Issue 5-6
  • DOI: 10.1002/ejic.201201097

Evolution of magnetic interactions in a pressure-induced Jahn-Teller driven magnetic dimensionality switch
journal, June 2013

[Co(NCS)2(1,2-bis(2-pyridyl)ethylene)]n: A new 1D coordination polymer that shows a metamagnetic transition
journal, October 2013

Quantum Critical Transition Amplifies Magnetoelastic Coupling in Mn [ N ( CN ) 2 ] 2
journal, June 2013

Hydrogen Bonding and Multiphonon Structure in Copper Pyrazine Coordination Polymers
journal, October 2007

  • Brown, S.; Cao, J.; Musfeldt, J. L.
  • Inorganic Chemistry, Vol. 46, Issue 21
  • DOI: 10.1021/ic070122t

Pressure-Induced Sequential Orbital Reorientation in a Magnetic Framework Material
journal, September 2010

  • Halder, Gregory J.; Chapman, Karena W.; Schlueter, John A.
  • Angewandte Chemie International Edition, Vol. 50, Issue 2
  • DOI: 10.1002/anie.201003380

Pressure Effects on the Quasi-1-D Molecular Ferromagnet 2-(4,5,6,7-Tetrafluorobenzimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro- 1H -imidazole-3-oxide-1-oxyl
journal, October 2011

  • Seber, Gonca; Halder, Gregory J.; Schlueter, John A.
  • Crystal Growth & Design, Vol. 11, Issue 10
  • DOI: 10.1021/cg200802c

Pressure-Driven Orbital Reorientations and Coordination-Sphere Reconstructions in [CuF2(H2O)2(pyz)]
journal, May 2012

  • Prescimone, Alessandro; Morien, Chelsey; Allan, David
  • Angewandte Chemie International Edition, Vol. 51, Issue 30
  • DOI: 10.1002/anie.201202367

Importance of Halogen···Halogen Contacts for the Structural and Magnetic Properties of CuX 2 (pyrazine- N , N ′-dioxide)(H 2 O) 2 (X = Cl and Br)
journal, January 2012

  • Schlueter, John A.; Park, Hyunsoo; Halder, Gregory J.
  • Inorganic Chemistry, Vol. 51, Issue 4
  • DOI: 10.1021/ic201924q

Pressure-Induced Phase Transitions in Ammonium Squarate: A Supramolecular Structure Based on Hydrogen-Bonding and π-Stacking Interactions
journal, July 2011

  • Li, Shourui; Wang, Kai; Zhou, Mi
  • The Journal of Physical Chemistry B, Vol. 115, Issue 29
  • DOI: 10.1021/jp202975q

The magnetic exchange interaction via N–H⋯O-bonding in copper(II) complex with 1-phenyl-3-methyl-4-formylpyrazol-5-one 2-quinolylhydrazone
journal, August 2013

  • Levchenkov, Sergey I.; Shcherbakov, Igor N.; Popov, Leonid D.
  • Inorganica Chimica Acta, Vol. 405
  • DOI: 10.1016/j.ica.2013.05.032

High-Temperature and Pressure-Induced Ferroelectricity in Hydrogen-Bonded Supramolecular Crystals of Anilic Acids and 2,3-Di(2-pyridinyl)pyrazine
journal, March 2013

  • Horiuchi, Sachio; Kumai, Reiji; Tokura, Yoshinori
  • Journal of the American Chemical Society, Vol. 135, Issue 11
  • DOI: 10.1021/ja400318v

ESR of coupled spin-1/2 chains in copper pyrazine dinitrate: unveiling geometrical frustration
journal, December 2013

Review: A gentle introduction to magnetism: units, fields, theory, and experiment
journal, February 2014

Magnetic Interactions in Molecules and Highly Correlated Materials: Physical Content, Analytical Derivation, and Rigorous Extraction of Magnetic Hamiltonians
journal, September 2013

  • Malrieu, Jean Paul; Caballol, Rosa; Calzado, Carmen J.
  • Chemical Reviews, Vol. 114, Issue 1
  • DOI: 10.1021/cr300500z

Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF 2 (H 2 O) 2 (3-chloropyridine)
journal, January 2013

  • Lapidus, Saul H.; Manson, Jamie L.; Park, Hyunsoo
  • Chem. Commun., Vol. 49, Issue 5
  • DOI: 10.1039/C2CC37444G

Magnetoelastic coupling in [Ru 2 (O 2 CMe) 4 ] 3 [Cr(CN) 6 ] molecule-based magnet
journal, December 2012

Magnetoelastic interactions in Raman spectra of Ho1−xNdxFe3(BO3)4 crystals
journal, November 2013

  • Krylov, Alexander S.; Sofronova, Svetlana N.; Gudim, Irina A.
  • Solid State Communications, Vol. 174
  • DOI: 10.1016/j.ssc.2013.09.011

An infrared and Raman spectroscopic study of gypsum at high pressures
journal, October 2001

  • Knittle, E.; Phillips, W.; Williams, Q.
  • Physics and Chemistry of Minerals, Vol. 28, Issue 9
  • DOI: 10.1007/s002690100187

Determination of molybdenum-oxygen bond distances and bond orders by Raman spectroscopy
journal, October 1990

  • Hardcastle, Franklin D.; Wachs, Israel E.
  • Journal of Raman Spectroscopy, Vol. 21, Issue 10
  • DOI: 10.1002/jrs.1250211009

Some Thoughts about Bond Energies, Bond Lengths, and Force Constants
journal, April 2000

  • Cremer, Dieter; Wu, Anan; Larsson, Andreas
  • Journal of Molecular Modeling, Vol. 6, Issue 4
  • DOI: 10.1007/PL00010739

Magnetoelastic phase transitions in the LuFe4Ge2 and YFe4Si2 compounds: A neutron diffraction study
journal, November 2012

  • Schobinger-Papamantellos, P.; Buschow, K. H. J.; Rodríguez-Carvajal, J.
  • Journal of Magnetism and Magnetic Materials, Vol. 324, Issue 22
  • DOI: 10.1016/j.jmmm.2012.05.058

Driving Magnetostructural Transitions in Layered Intermetallic Compounds
journal, May 2013

Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices: Switching of Molecular Spin States in Inorganic Complexes
journal, November 2004

  • Bousseksou, Azzedine; Molnár, Gábor; Matouzenko, Galina
  • European Journal of Inorganic Chemistry, Vol. 2004, Issue 22
  • DOI: 10.1002/ejic.200400571

A Room-Temperature Molecular/Organic-Based Magnet
journal, June 1991

Specific volume measurements of Cu, Mo, Pd, and Ag and calibration of the ruby R 1 fluorescence pressure gauge from 0.06 to 1 Mbar
journal, June 1978

  • Mao, H. K.; Bell, P. M.; Shaner, J. W.
  • Journal of Applied Physics, Vol. 49, Issue 6
  • DOI: 10.1063/1.325277

High-power terahertz radiation from relativistic electrons
journal, November 2002

  • Carr, G. L.; Martin, Michael C.; McKinney, Wayne R.
  • Nature, Vol. 420, Issue 6912
  • DOI: 10.1038/nature01175

    Works referencing / citing this record:

    Dinuclear Complexes Formed by Hydrogen Bonds: Synthesis, Structure and Magnetic and Electrochemical Properties
    journal, May 2017

    • Granelli, Matteo; Downward, Alan M.; Huber, Robin
    • Chemistry - A European Journal, Vol. 23, Issue 29
    • DOI: 10.1002/chem.201700591

    Ternary and binary copper(II) complexes: synthesis, characterization, ROS-inductive, proteasome inhibitory, and anticancer properties
    journal, October 2016

    HCl chemisorption-induced drastic magneto-structural transformation in a layered cobalt–phosphonotriazolate coordination polymer
    journal, January 2016

    • Zhang, Weiquan; Wang, Dianpeng; Zhu, Lin
    • Dalton Transactions, Vol. 45, Issue 26
    • DOI: 10.1039/c6dt01363e