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Title: Milestone Report - Complete New Adsorbent Materials for Marine Testing to Demonstrate 4.5 g-U/kg Adsorbent

Abstract

This report describes work on the successful completion of Milestone M2FT-14OR03100115 (8/20/2014) entitled, “Complete new adsorbent materials for marine testing to demonstrate 4.5 g-U/kg adsorbent”. This effort is part of the Seawater Uranium Recovery Program, sponsored by the U.S. Department of Energy, Office of Nuclear Energy, and involved the development of new adsorbent materials at the Oak Ridge National Laboratory (ORNL) and marine testing at the Pacific Northwest National Laboratory (PNNL). ORNL has recently developed two new families of fiber adsorbents that have demonstrated uranium adsorption capacities greater than 4.5 g-U/kg adsorbent after marine testing at PNNL. One adsorbent was synthesized by radiation-induced graft polymerization of itaconic acid and acrylonitrile onto high surface area polyethylene fibers followed by amidoximation and base conditioning. This fiber showed a capacity of 4.6 g-U/kg adsorbent in marine testing at PNNL. The second adsorbent was prepared by atom-transfer radical polymerization of t-butyl acrylate and acrylonitrile onto halide-functionalized round fibers followed by amidoximation and base hydrolysis. This fiber demonstrated uranium adsorption capacity of 5.4 g-U/kg adsorbent in marine testing at PNNL.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [2];  [2];  [2]
+ Show Author Affiliations
  1. ORNL
  2. PNNL
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
Contributing Org.:
PNNL
OSTI Identifier:
1162052
Report Number(s):
ORNL/LTR-2014/318
R&D Project: AF5855000; M2FT-14OR03100115
DOE Contract Number:
DE-AC05-00OR22725
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; 36 MATERIALS SCIENCE; Seawater Uranium Recovery

Citation Formats

Janke, Christopher James, Das, Sadananda, Oyola, Yatsandra, Mayes, Richard T., Saito, Tomonori, Brown, Suree, Gill, Gary, Kuo, Li-Jung, and Wood, Jordana. Milestone Report - Complete New Adsorbent Materials for Marine Testing to Demonstrate 4.5 g-U/kg Adsorbent. United States: N. p., 2014. Web. doi:10.2172/1162052.
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Janke, Christopher James, Das, Sadananda, Oyola, Yatsandra, Mayes, Richard T., Saito, Tomonori, Brown, Suree, Gill, Gary, Kuo, Li-Jung, & Wood, Jordana. Milestone Report - Complete New Adsorbent Materials for Marine Testing to Demonstrate 4.5 g-U/kg Adsorbent. United States. doi:10.2172/1162052.
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Janke, Christopher James, Das, Sadananda, Oyola, Yatsandra, Mayes, Richard T., Saito, Tomonori, Brown, Suree, Gill, Gary, Kuo, Li-Jung, and Wood, Jordana. Fri . "Milestone Report - Complete New Adsorbent Materials for Marine Testing to Demonstrate 4.5 g-U/kg Adsorbent". United States. doi:10.2172/1162052. https://www.osti.gov/servlets/purl/1162052.
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@article{osti_1162052,
title = {Milestone Report - Complete New Adsorbent Materials for Marine Testing to Demonstrate 4.5 g-U/kg Adsorbent},
author = {Janke, Christopher James and Das, Sadananda and Oyola, Yatsandra and Mayes, Richard T. and Saito, Tomonori and Brown, Suree and Gill, Gary and Kuo, Li-Jung and Wood, Jordana},
abstractNote = {This report describes work on the successful completion of Milestone M2FT-14OR03100115 (8/20/2014) entitled, “Complete new adsorbent materials for marine testing to demonstrate 4.5 g-U/kg adsorbent”. This effort is part of the Seawater Uranium Recovery Program, sponsored by the U.S. Department of Energy, Office of Nuclear Energy, and involved the development of new adsorbent materials at the Oak Ridge National Laboratory (ORNL) and marine testing at the Pacific Northwest National Laboratory (PNNL). ORNL has recently developed two new families of fiber adsorbents that have demonstrated uranium adsorption capacities greater than 4.5 g-U/kg adsorbent after marine testing at PNNL. One adsorbent was synthesized by radiation-induced graft polymerization of itaconic acid and acrylonitrile onto high surface area polyethylene fibers followed by amidoximation and base conditioning. This fiber showed a capacity of 4.6 g-U/kg adsorbent in marine testing at PNNL. The second adsorbent was prepared by atom-transfer radical polymerization of t-butyl acrylate and acrylonitrile onto halide-functionalized round fibers followed by amidoximation and base hydrolysis. This fiber demonstrated uranium adsorption capacity of 5.4 g-U/kg adsorbent in marine testing at PNNL.},
doi = {10.2172/1162052},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Aug 01 00:00:00 EDT 2014},
month = {Fri Aug 01 00:00:00 EDT 2014}
}
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Technical Report:
View Technical Report (1.61 MB)
DOI:  10.2172/1162052
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