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Title: NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels

Abstract

Off-gas treatment systems in used fuel reprocessing which use fixed-bed adsorbers are typically designed to operate for an extended period of time before replacement or regeneration of the adsorbent. During this time, the sorbent material will be exposed to the off-gas stream. Exposure could last for months, depending on the replacement cycle time. The gas stream will be at elevated temperature and will possibly contain a mixture of water vapor, NOx, nitric acid vapors, and a variety of other constituents in addition to the radionuclides of capture interest. A series of studies were undertaken to evaluate the effects of long-term exposure, or aging, on proposed iodine sorbent materials under increasingly harsh off-gas conditions. Previous studies have evaluated the effects of up to 6 months of aging under dry air and under humid air conditions on the iodine loading behavior of Ag0-functionalized aerogels. This study examines the effects of extended exposure (up to 6 months) to NO2 on the iodine loading capacity of Ag0- functionalized aerogels. Material aged for 1 and 2 months appeared to have a similar total loading capacity to fresh material. Over an aging period of 4 months, a loss of approximately 15% of the total iodine capacitymore » was seen. The iodine capacity loss on silver-functionalized aerogels due to NO2 was smaller than the iodine capacity loss due to humid or dry air aging.« less

Authors:
 [1];  [1];  [1];  [1]
  1. ORNL
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
OSTI Identifier:
1157588
Report Number(s):
ORNL/LTR-2014/271
M3FT-14OR03120210 ; FCRD-SWF-2014-000274
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Technical Report
Resource Relation:
Related Information: SEPARATIONS AND WASTE FORMS CAMPAIGN/FUEL CYCLE RESEARCH AND DEVELOPMENT: NO2 AGING AND IODINE LOADING OF SILVERFUNCTIONALIZED AEROGELS
Country of Publication:
United States
Language:
English

Citation Formats

Patton, K K, Bruffey, S H, Walker, J F, and Jubin, R T. NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels. United States: N. p., 2014. Web. doi:10.2172/1157588.
Patton, K K, Bruffey, S H, Walker, J F, & Jubin, R T. NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels. United States. doi:10.2172/1157588.
Patton, K K, Bruffey, S H, Walker, J F, and Jubin, R T. Thu . "NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels". United States. doi:10.2172/1157588. https://www.osti.gov/servlets/purl/1157588.
@article{osti_1157588,
title = {NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels},
author = {Patton, K K and Bruffey, S H and Walker, J F and Jubin, R T},
abstractNote = {Off-gas treatment systems in used fuel reprocessing which use fixed-bed adsorbers are typically designed to operate for an extended period of time before replacement or regeneration of the adsorbent. During this time, the sorbent material will be exposed to the off-gas stream. Exposure could last for months, depending on the replacement cycle time. The gas stream will be at elevated temperature and will possibly contain a mixture of water vapor, NOx, nitric acid vapors, and a variety of other constituents in addition to the radionuclides of capture interest. A series of studies were undertaken to evaluate the effects of long-term exposure, or aging, on proposed iodine sorbent materials under increasingly harsh off-gas conditions. Previous studies have evaluated the effects of up to 6 months of aging under dry air and under humid air conditions on the iodine loading behavior of Ag0-functionalized aerogels. This study examines the effects of extended exposure (up to 6 months) to NO2 on the iodine loading capacity of Ag0- functionalized aerogels. Material aged for 1 and 2 months appeared to have a similar total loading capacity to fresh material. Over an aging period of 4 months, a loss of approximately 15% of the total iodine capacity was seen. The iodine capacity loss on silver-functionalized aerogels due to NO2 was smaller than the iodine capacity loss due to humid or dry air aging.},
doi = {10.2172/1157588},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 31 00:00:00 EDT 2014},
month = {Thu Jul 31 00:00:00 EDT 2014}
}

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