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Title: Functionalization of poly(phenylene) by the attachment of sidechains

Abstract

A composition and an anion exchange membranes including a composition and a method of forming a composition including a compound including a poly(phenylene) backbone represented by the following formula: ##STR00001## wherein each of R.sub.1, R.sub.2 and R.sub.3 may be the same or different and is H or an unsubstituted or inertly-substituted aromatic moiety; wherein each of Ar.sub.1 and Ar.sub.2 may be the same or different and is an unsubstituted or inertly-substituted aromatic moiety; wherein each of R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 is H or a monovalent hydrocarbon group including two to 18 carbon atoms, with the proviso that each R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 cannot be H; and wherein each of Y.sub.6, Y.sub.7, Y.sub.8, Y.sub.9, Y.sub.10 and Y.sub.11 may be the same or different and is H or a functional group.

Inventors:
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1150641
Patent Number(s):
8,809,483
Application Number:
13/627,098
Assignee:
Sandia Corporation (Albuquerque, NM)
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hibbs, Michael R. Functionalization of poly(phenylene) by the attachment of sidechains. United States: N. p., 2014. Web.
Hibbs, Michael R. Functionalization of poly(phenylene) by the attachment of sidechains. United States.
Hibbs, Michael R. Tue . "Functionalization of poly(phenylene) by the attachment of sidechains". United States. https://www.osti.gov/servlets/purl/1150641.
@article{osti_1150641,
title = {Functionalization of poly(phenylene) by the attachment of sidechains},
author = {Hibbs, Michael R.},
abstractNote = {A composition and an anion exchange membranes including a composition and a method of forming a composition including a compound including a poly(phenylene) backbone represented by the following formula: ##STR00001## wherein each of R.sub.1, R.sub.2 and R.sub.3 may be the same or different and is H or an unsubstituted or inertly-substituted aromatic moiety; wherein each of Ar.sub.1 and Ar.sub.2 may be the same or different and is an unsubstituted or inertly-substituted aromatic moiety; wherein each of R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 is H or a monovalent hydrocarbon group including two to 18 carbon atoms, with the proviso that each R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10 and R.sub.11 cannot be H; and wherein each of Y.sub.6, Y.sub.7, Y.sub.8, Y.sub.9, Y.sub.10 and Y.sub.11 may be the same or different and is H or a functional group.},
doi = {},
url = {https://www.osti.gov/biblio/1150641}, journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {8}
}

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Works referenced in this record:

Anion-exchange membranes with improved alkaline stability
journal, December 1990


Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization:  Synthesis and Physical Properties of a Novel Polyelectrolyte
journal, June 2005


Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells
journal, November 2009


Anion Conductive Block Poly(arylene ether)s: Synthesis, Properties, and Application in Alkaline Fuel Cells
journal, July 2011


Prospects for Alkaline Anion-Exchange Membranes in Low Temperature Fuel Cells
journal, October 2004