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Title: Preparation of functionalized zeolitic frameworks

Abstract

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Inventors:
; ; ; ; ;
Publication Date:
Research Org.:
University of California, Oakland, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1150640
Patent Number(s):
8,809,546
Application Number:
13/630,554
Assignee:
The Regents of the University of California (Oakland, CA); The Regents of the University of Michigan (Ann Arbor, MI) CHO
DOE Contract Number:
FG02-06ER15813
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Yaghi, Omar M., Hayashi, Hideki, Banerjee, Rahul, Park, Kyo Sung, Wang, Bo, and Cote, Adrien P. Preparation of functionalized zeolitic frameworks. United States: N. p., 2014. Web.
Yaghi, Omar M., Hayashi, Hideki, Banerjee, Rahul, Park, Kyo Sung, Wang, Bo, & Cote, Adrien P. Preparation of functionalized zeolitic frameworks. United States.
Yaghi, Omar M., Hayashi, Hideki, Banerjee, Rahul, Park, Kyo Sung, Wang, Bo, and Cote, Adrien P. Tue . "Preparation of functionalized zeolitic frameworks". United States. doi:. https://www.osti.gov/servlets/purl/1150640.
@article{osti_1150640,
title = {Preparation of functionalized zeolitic frameworks},
author = {Yaghi, Omar M. and Hayashi, Hideki and Banerjee, Rahul and Park, Kyo Sung and Wang, Bo and Cote, Adrien P.},
abstractNote = {The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 19 00:00:00 EDT 2014},
month = {Tue Aug 19 00:00:00 EDT 2014}
}

Patent:

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  • The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.
  • The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.
  • Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.
  • Functionalized metal-organic framework adsorbents with ligands containing basic nitrogen groups such as alkylamines and alkyldiamines appended to the metal centers and method of isolating carbon dioxide from a stream of combined gases and carbon dioxide partial pressures below approximately 1 and 1000 mbar. The adsorption material has an isosteric heat of carbon dioxide adsorption of greater than -60 kJ/mol at zero coverage using a dual-site Langmuir model.
  • The disclosure provides for metal catecholate frameworks, and methods of use thereof, including gas separation, gas storage, catalysis, tunable conductors, supercapacitors, and sensors.