Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils
Patent
·
OSTI ID:1133664
Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.
- Research Organization:
- University of Massachusetts, Boston, MA (USA)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-07ER86324
- Assignee:
- University of Massachusetts (Boston, MA)
- Patent Number(s):
- 8,741,258
- Application Number:
- 13/119,750
- OSTI ID:
- 1133664
- Country of Publication:
- United States
- Language:
- English
Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review
|
journal | May 2006 |
Historical Developments in Hydroprocessing Bio-oils
|
journal | May 2007 |
Overview of Applications of Biomass Fast Pyrolysis Oil
|
journal | March 2004 |
Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water
|
journal | August 2002 |
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