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Title: Enhanced Noble Gas Adsorption in Ag@MOF-74Ni

Abstract

Various amounts of Ag nanoparticles were successfully deposited in porous MOF-74Ni (or Ni/DOBDC) with an auto-reduction method. An optimized silver-loaded MOF-74Ni was shown to have an improved Xe adsorption capacity (15% more) at STP compared to the MOF without silver nanoparticles. The silver-loaded sample also has a higher Xe/Kr selectivity. These results are explained by the stronger interactions between polarizable Xe molecules and the well-dispersed Ag nanoparticles.

Authors:
; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1130648
Report Number(s):
PNNL-SA-99495
AF5805010
DOE Contract Number:
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Chemical Communications, 50(4):466-468
Country of Publication:
United States
Language:
English

Citation Formats

Liu, Jian, Strachan, Denis M., and Thallapally, Praveen K. Enhanced Noble Gas Adsorption in Ag@MOF-74Ni. United States: N. p., 2014. Web. doi:10.1039/C3CC47777K.
Liu, Jian, Strachan, Denis M., & Thallapally, Praveen K. Enhanced Noble Gas Adsorption in Ag@MOF-74Ni. United States. doi:10.1039/C3CC47777K.
Liu, Jian, Strachan, Denis M., and Thallapally, Praveen K. 2014. "Enhanced Noble Gas Adsorption in Ag@MOF-74Ni". United States. doi:10.1039/C3CC47777K.
@article{osti_1130648,
title = {Enhanced Noble Gas Adsorption in Ag@MOF-74Ni},
author = {Liu, Jian and Strachan, Denis M. and Thallapally, Praveen K.},
abstractNote = {Various amounts of Ag nanoparticles were successfully deposited in porous MOF-74Ni (or Ni/DOBDC) with an auto-reduction method. An optimized silver-loaded MOF-74Ni was shown to have an improved Xe adsorption capacity (15% more) at STP compared to the MOF without silver nanoparticles. The silver-loaded sample also has a higher Xe/Kr selectivity. These results are explained by the stronger interactions between polarizable Xe molecules and the well-dispersed Ag nanoparticles.},
doi = {10.1039/C3CC47777K},
journal = {Chemical Communications, 50(4):466-468},
number = ,
volume = ,
place = {United States},
year = 2014,
month = 1
}