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Title: Pressure-induced isostructural phase transition of a metal-organic framework Co 2(4,4'-bpy) 3(NO 3) 4·xH 2O

Abstract

Based on the 4,4'-bipyridine organic linker, metal–organic frameworks of Co 2(4,4'-bpy) 3(NO 3) 4·xH 2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.

Authors:
; ; ; ; ; ; ;  [1]
  1. Jilin
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
FOREIGNNSFDOE - BASIC ENERGY SCIENCESDOE-NNSA
OSTI Identifier:
1130105
Resource Type:
Journal Article
Resource Relation:
Journal Name: Cryst. Eng. Comm.; Journal Volume: 16; Journal Issue: 05, 2014
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Zhou, Mi, Wang, Kai, Men, Zhiwei, Sun, Chenglin, Li, Zhanlong, Liu, Bingbing, Zou, Guangtian, and Zou, Bo. Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O. United States: N. p., 2014. Web. doi:10.1039/c3ce42607f.
Zhou, Mi, Wang, Kai, Men, Zhiwei, Sun, Chenglin, Li, Zhanlong, Liu, Bingbing, Zou, Guangtian, & Zou, Bo. Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O. United States. doi:10.1039/c3ce42607f.
Zhou, Mi, Wang, Kai, Men, Zhiwei, Sun, Chenglin, Li, Zhanlong, Liu, Bingbing, Zou, Guangtian, and Zou, Bo. Thu . "Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O". United States. doi:10.1039/c3ce42607f.
@article{osti_1130105,
title = {Pressure-induced isostructural phase transition of a metal-organic framework Co2(4,4'-bpy)3(NO3)4·xH2O},
author = {Zhou, Mi and Wang, Kai and Men, Zhiwei and Sun, Chenglin and Li, Zhanlong and Liu, Bingbing and Zou, Guangtian and Zou, Bo},
abstractNote = {Based on the 4,4'-bipyridine organic linker, metal–organic frameworks of Co2(4,4'-bpy)3(NO3)4·xH2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.},
doi = {10.1039/c3ce42607f},
journal = {Cryst. Eng. Comm.},
number = 05, 2014,
volume = 16,
place = {United States},
year = {Thu Jul 17 00:00:00 EDT 2014},
month = {Thu Jul 17 00:00:00 EDT 2014}
}