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Title: A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

Abstract

Two new silver containing materials with TCNQ derivatives were prepared by electrocrystallization. Synchrotron radiation diffraction studies were conducted to determine the structures of the new phases which exhibit unprecedented high room temperature conductivity. The I–V characteristics reveal a room-temperature switching behaviour and memory effect based on intrinsic negative differential resistance (NDR). EPR spectroscopic measurements performed under an applied electric field indicate a g-tensor shift that is correlated to the amplitude of current.

Authors:
; ; ; ;  [1];  [2]
  1. TAM
  2. (
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1123940
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Materials Chemistry. C; Journal Volume: 2; Journal Issue: (2) ; 2014
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Zhang, Zhongyue, Zhao, Hanhua, Matsushita, Michio M., Awaga, Kunio, Dunbar, Kim R., and Nagoya). A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior. United States: N. p., 2014. Web. doi:10.1039/C3TC31577K.
Zhang, Zhongyue, Zhao, Hanhua, Matsushita, Michio M., Awaga, Kunio, Dunbar, Kim R., & Nagoya). A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior. United States. doi:10.1039/C3TC31577K.
Zhang, Zhongyue, Zhao, Hanhua, Matsushita, Michio M., Awaga, Kunio, Dunbar, Kim R., and Nagoya). Wed . "A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior". United States. doi:10.1039/C3TC31577K.
@article{osti_1123940,
title = {A new metal-organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior},
author = {Zhang, Zhongyue and Zhao, Hanhua and Matsushita, Michio M. and Awaga, Kunio and Dunbar, Kim R. and Nagoya)},
abstractNote = {Two new silver containing materials with TCNQ derivatives were prepared by electrocrystallization. Synchrotron radiation diffraction studies were conducted to determine the structures of the new phases which exhibit unprecedented high room temperature conductivity. The I–V characteristics reveal a room-temperature switching behaviour and memory effect based on intrinsic negative differential resistance (NDR). EPR spectroscopic measurements performed under an applied electric field indicate a g-tensor shift that is correlated to the amplitude of current.},
doi = {10.1039/C3TC31577K},
journal = {Journal of Materials Chemistry. C},
number = (2) ; 2014,
volume = 2,
place = {United States},
year = {Wed Aug 06 00:00:00 EDT 2014},
month = {Wed Aug 06 00:00:00 EDT 2014}
}