Symmetries and multiferroic properties of novel room-temperature magnetoelectrics: Lead iron tantalate – lead zirconate titanate (PFT/PZT)

Sanchez, Dilsom A.; Ortega, N.; Kumar, Ashok; Roque-Malherbe, R.; Polanco, R.; Scott, J. F.; Katiyar, Ram S.

doi:10.1063/1.3670361

Title: Symmetries and multiferroic properties of novel room-temperature magnetoelectrics: Lead iron tantalate – lead zirconate titanate (PFT/PZT)

Journal Article · Thu Dec 01 00:00:00 EST 2011 · AIP Advances

DOI:https://doi.org/10.1063/1.3670361· OSTI ID:1114948

Sanchez, Dilsom A.; Ortega, N.; Kumar, Ashok; Roque-Malherbe, R.; Polanco, R.; Scott, J. F.; Katiyar, Ram S.

Mixing 60-70% lead zirconate titanate with 40-30% lead iron tantalate produces a single-phase, low-loss, room-temperature multiferroic with magnetoelectric coupling: (PbZr_0.53Ti_0.47O₃) _(1-x)- (PbFe_0.5Ta_0.5O₃)_x. Our study combines x-ray scattering, magnetic and polarization hysteresis in both phases, plus a second-order dielectric divergence (to epsilon = 6000 at 475 K for 0.4 PFT; to 4000 at 520 K for 0.3 PFT) for an unambiguous assignment as a C_2v-C_4v (Pmm2-P4mm) transition. Furthermore, the material exhibits square saturated magnetic hysteresis loops with 0.1 emu/g at 295 K and saturation polarization P_r = 25 μC/cm², which actually increases (to 40 μC/cm²) in the high-T tetragonal phase, representing an exciting new room temperature oxide multiferroic to compete with BiFeO₃. Additional transitions at high temperatures (cubic at T>1300 K) and low temperatures (rhombohedral or monoclinic at T<250 K) are found. Finally, these are the lowest-loss room-temperature multiferroics known, which is a great advantage for magnetoelectric devices.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Turabo, Gurabo (Puerto Rico)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: FG 02-08ER46526; NA0000672; FG02-08Er46526

OSTI ID:: 1114948

Alternate ID(s):: OSTI ID: 1336262

Journal Information:: AIP Advances, Journal Name: AIP Advances Vol. 1 Journal Issue: 4; ISSN 2158-3226

Publisher:: American Institute of PhysicsCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 98 works

Citation information provided by
Web of Science

References (41)

Relaxor characteristics of Pb(Fe2∕3W1∕3)O3–BiFeO3 solid solution prepared by mechanosynthesis route Choudhary, R. N. P.; Pradhan, Dillip K.; Tirado, C. M. Journal of Applied Physics, Vol. 100, Issue 8 https://doi.org/10.1063/1.2359624	journal	October 2006
Coexistence of Antiferromagnetic and Spin Cluster Glass Order in the Magnetoelectric Relaxor Multiferroic ${PbFe}_{0.5} {Nb}_{0.5} O_{3}$ Kleemann, W.; Shvartsman, V. V.; Borisov, P. Physical Review Letters, Vol. 105, Issue 25 https://doi.org/10.1103/PhysRevLett.105.257202	journal	December 2010
Piezoelectric Properties of Lead Zirconate‐Lead Titanate Solid‐Solution Ceramics Jaffe, B.; Roth, R. S.; Marzullo, S. Journal of Applied Physics, Vol. 25, Issue 6 https://doi.org/10.1063/1.1721741	journal	June 1954
Lead-free piezoceramics Saito, Yasuyoshi; Takao, Hisaaki; Tani, Toshihiko Nature, Vol. 432, Issue 7013 https://doi.org/10.1038/nature03028	journal	October 2004
Anisotropy of the Magnetoelectric Effect in ${Cr}_{2}$ $O_{3}$ Folen, V. J.; Rado, G. T.; Stalder, E. W. Physical Review Letters, Vol. 6, Issue 11 https://doi.org/10.1103/PhysRevLett.6.607	journal	June 1961
Fabrication and characterization of the multiferroic birelaxor lead–iron–tungstate/lead–zirconate–titanate Kumar, Ashok; Katiyar, R. S.; Scott, J. F. Journal of Applied Physics, Vol. 108, Issue 6 https://doi.org/10.1063/1.3481411	journal	September 2010
Multiferroic Pb(Fe0.66W0.33)0.80Ti0.20O3 thin films: A room-temperature relaxor ferroelectric and weak ferromagnetic Kumar, Ashok; Rivera, I.; Katiyar, R. S. Applied Physics Letters, Vol. 92, Issue 13 https://doi.org/10.1063/1.2906371	journal	March 2008
Epitaxial growth and magnetoelectric relaxor behavior in multiferroic 0.8Pb(Fe1/2Nb1/2)O3–0.2Pb(Mg1/2W1/2)O3 thin films Peng, Wei; Lemée, N.; Dellis, J. -L. Applied Physics Letters, Vol. 95, Issue 13 https://doi.org/10.1063/1.3242377	journal	September 2009
Dielectric and magnetic enhancements in BiFeO3–PbTiO3 solid solutions with La doping Cheng, Jinrong; Yu, Shengwen; Chen, Jianguo Applied Physics Letters, Vol. 89, Issue 12 https://doi.org/10.1063/1.2353806	journal	September 2006
The Physical Chemistry of Materials Roque-Malherbe, Rolando CRC Press https://doi.org/10.1201/9781420082739	book	October 2009
Rietveld refinements of the paraelectric and ferroelectric structures of PbFe _0.5 Ta _0.5 O ₃ Lampis, Nathascia; Sciau, Philippe; Lehmann, Alessandra Geddo Journal of Physics: Condensed Matter, Vol. 12, Issue 11 https://doi.org/10.1088/0953-8984/12/11/303	journal	March 2000
Symmetry consideration of Raman modes in Nd-doped lead zirconate titanate thin films for structure characterization Frantti, J.; Lantto, V.; Lappalainen, J. Journal of Applied Physics, Vol. 79, Issue 2 https://doi.org/10.1063/1.360895	journal	January 1996
Room temperature multiferroic effects in superlattice nanocapacitors Dussan, S.; Kumar, A.; Scott, J. F. Applied Physics Letters, Vol. 97, Issue 25 https://doi.org/10.1063/1.3528210	journal	December 2010
Multiferroic properties of BiFeO3 doped Bi(MgTi)O3–PbTiO3 ceramic system Rai, Radheshyam; Kholkin, Andrei L.; Sharma, Seema Journal of Alloys and Compounds, Vol. 506, Issue 2 https://doi.org/10.1016/j.jallcom.2010.07.080	journal	September 2010
Probing the ferroelectric phase transition through Raman spectroscopy in Pb(Fe2∕3W1∕3)1∕2Ti1∕2O3 thin films Kumar, Ashok; Murari, N. M.; Katiyar, R. S. Applied Physics Letters, Vol. 90, Issue 26 https://doi.org/10.1063/1.2752535	journal	June 2007
Analysis of Phase Coexistence in Fe ₂ O ₃ -Doped 0.2PZN?0.8PZT Ferroelectric Ceramics by Raman Scattering Spectra Zhu, Man-Kang; Lu, Peng-Xian; Hou, Yu-Dong Journal of the American Ceramic Society, Vol. 89, Issue 12 https://doi.org/10.1111/j.1551-2916.2006.01281.x	journal	December 2006
Electron paramagnetic resonance of magnetoelectric Pb(Fe1∕2Nb1∕2)O3 Blinc, R.; Cevc, P.; Zorko, A. Journal of Applied Physics, Vol. 101, Issue 3 https://doi.org/10.1063/1.2432309	journal	February 2007
Preparation and characterisation of Pb(Fe1/2Ta1/2)O3 relaxor ferroelectric Zhu, W. Z.; Kholkin, A.; Mantas, P. Q. Journal of the European Ceramic Society, Vol. 20, Issue 12 https://doi.org/10.1016/S0955-2219(00)00094-7	journal	November 2000
Unit-cell refinement from powder diffraction scans Pawley, G. S. Journal of Applied Crystallography, Vol. 14, Issue 6 https://doi.org/10.1107/S0021889881009618	journal	December 1981
Observation of magnetoelectric coupling in glassy epitaxial PbFe0.5Nb0.5O3 thin films Correa, Margarita; Kumar, Ashok; Katiyar, R. S. Applied Physics Letters, Vol. 93, Issue 19 https://doi.org/10.1063/1.3021394	journal	November 2008
Preparation and electrical properties of high-Curie temperature ferroelectrics Fang, B. -J.; Ding, C. -L.; Liu, W. The European Physical Journal Applied Physics, Vol. 45, Issue 2 https://doi.org/10.1051/epjap/2009004	journal	January 2009
Proton-Phonon Coupling in Cs $H_{2}$ As $O_{4}$ and K $H_{2}$ As $O_{4}$ Katiyar, R. S.; Ryan, J. F.; Scott, J. F. Physical Review B, Vol. 4, Issue 8 https://doi.org/10.1103/PhysRevB.4.2635	journal	October 1971
Stability of PZT Piezoelectric Ceramics under Vibration Level Change Takahashi, Sadayuki; Hirose, Seiji; Uchino, Kenji Journal of the American Ceramic Society, Vol. 77, Issue 9 https://doi.org/10.1111/j.1151-2916.1994.tb04615.x	journal	September 1994
Magnetic field induced magnetoelectric effects, (ME)H, in the perovskites Pb2CoWO6 and Pb2FeTaO6 Brixel, Wolf; Rivera, Jean-Pierre; Steiner, Anton Ferroelectrics, Vol. 79, Issue 1 https://doi.org/10.1080/00150198808229431	journal	March 1988
Magnetic control of large room-temperature polarization Kumar, Ashok; Sharma, G. L.; Katiyar, R. S. Journal of Physics: Condensed Matter, Vol. 21, Issue 38 https://doi.org/10.1088/0953-8984/21/38/382204	journal	August 2009
Polarized Raman scattering of epitaxial Pb(Zr,Ti)O3 thin films in the tetragonal-phase field Lee, Sun-Hwa; Jang, Hyun M.; Sung, Hyun H. Applied Physics Letters, Vol. 81, Issue 13 https://doi.org/10.1063/1.1509859	journal	September 2002
Electronic structure of ${PbFe}_{1 / 2} {Ta}_{1 / 2} O_{3} :$ Crystallographic ordering and magnetic properties Lampis, Nathascia; Franchini, Cesare; Satta, Guido Physical Review B, Vol. 69, Issue 6 https://doi.org/10.1103/PhysRevB.69.064412	journal	February 2004
Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of ${PbZr}_{0.52} {Ti}_{0.48} O_{3}$ Noheda, B.; Gonzalo, J. A.; Cross, L. E. Physical Review B, Vol. 61, Issue 13 https://doi.org/10.1103/PhysRevB.61.8687	journal	April 2000
Dielectric and magnetic properties of sol-gel-derived lead iron niobate ceramics Majumder, S. B.; Bhattacharyya, S.; Katiyar, R. S. Journal of Applied Physics, Vol. 99, Issue 2 https://doi.org/10.1063/1.2158131	journal	January 2006
Nanoscale ordering and multiferroic behavior in $Pb ({Fe}_{1 / 2} {Ta}_{1 / 2}) O_{3}$ Martinez, R.; Palai, R.; Huhtinen, H. Physical Review B, Vol. 82, Issue 13 https://doi.org/10.1103/PhysRevB.82.134104	journal	October 2010
Effects of Niobium Addition on the Relaxor Ferroelectric Properties and Ordering Structures of Lead Iron Tantalates Woo, Byong-Chul; Kim, Byung-Kook Japanese Journal of Applied Physics, Vol. 42, Issue Part 1, No. 9B https://doi.org/10.1143/JJAP.42.6037	journal	September 2003
Dielectric relaxation and phase transitions at cryogenic temperatures in $0.65 [Pb ({Ni}_{1 ∕ 3} {Nb}_{2 ∕ 3}) O_{3}] - 0.35 Pb Ti O_{3}$ ceramics Singh, Satendra Pal; Singh, Akhilesh Kumar; Pandey, Dhananjai Physical Review B, Vol. 76, Issue 5 https://doi.org/10.1103/PhysRevB.76.054102	journal	August 2007
Mesoscopic model of a system possessing both relaxor ferroelectric and relaxor ferromagnetic properties Pirc, R.; Blinc, R.; Scott, J. F. Physical Review B, Vol. 79, Issue 21 https://doi.org/10.1103/PhysRevB.79.214114	journal	June 2009
Dielectric and Magnetic Properties of Pb(Fe _1/2 Ta _1/2 )O ₃ Nomura, Shōichiro; Takabayashi, Hitoshi; Nakagawa, Takehiko Japanese Journal of Applied Physics, Vol. 7, Issue 6 https://doi.org/10.1143/JJAP.7.600	journal	June 1968
Positive temperature coefficient of resistivity and negative differential resistivity in lead iron tunstate-lead zirconate titate Kumar, Ashok; Katiyar, Ram S.; Scott, J. F. Applied Physics Letters, Vol. 94, Issue 21 https://doi.org/10.1063/1.3138781	journal	May 2009
Domain distributions in tetragonal Pb(Zr,Ti)O3 thin films probed by polarized Raman spectroscopy Osada, Minoru; Nishida, Ken; Wada, Syunshuke Applied Physics Letters, Vol. 87, Issue 23 https://doi.org/10.1063/1.2139844	journal	December 2005
Central peak in light scattering from the relaxor ferroelectric ${PbMg}_{1 / 3} {Nb}_{2 / 3} O_{3}$ Siny, I. G.; Lushnikov, S. G.; Katiyar, R. S. Physical Review B, Vol. 56, Issue 13 https://doi.org/10.1103/PhysRevB.56.7962	journal	October 1997
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Electrical, Electromechanical and Structural Studies on Solid Solution Ceramic Pb(Fe _1/2 Nb _1/2 )O ₃ –Pb(Zn _1/3 Nb _2/3 )O ₃ Yokosuka, Masaru Japanese Journal of Applied Physics, Vol. 38, Issue Part 1, No. 9B https://doi.org/10.1143/JJAP.38.5488	journal	September 1999
Raman Phonon Modes and Ferroelectric Phase Transitions in Nanocrystalline Lead Zirconate Titanate Meng, J. F.; Katiyar, R. S.; Zou, G. T. physica status solidi (a), Vol. 164, Issue 2 https://doi.org/10.1002/1521-396X(199712)164:2<851::AID-PSSA851>3.0.CO;2-J	journal	December 1997
Near-room temperature relaxor multiferroic Sanchez, Dilsom A.; Kumar, A.; Ortega, N. Applied Physics Letters, Vol. 97, Issue 20 https://doi.org/10.1063/1.3519979	journal	November 2010

Similar Records

A quaternary lead based perovskite structured materials with diffuse phase transition behavior

Journal Article · Thu Dec 15 00:00:00 EST 2011 · Materials Research Bulletin · OSTI ID:1114948

Martinez, R.; Kumar, Ashok; Scott, J. F.

Structure and phase formation behavior and dielectric and magnetic properties of lead iron tantalate-lead zirconate titanate multiferroic ceramics

Journal Article · Tue Mar 15 00:00:00 EDT 2016 · Materials Research Bulletin · OSTI ID:1114948

Tipakontitikul, R.; Jantaratana, P.; Bootchanont, A.; +3 more

Neutron diffraction studies on chemical and magnetic structure of multiferroic PbFe{sub 0.67}W{sub 0.33}O{sub 3}

Journal Article · Thu Apr 24 00:00:00 EDT 2014 · AIP Conference Proceedings · OSTI ID:1114948

Matteppanavar, Shidaling; Angadi, Basavaraj; Rayaprol, Sudhindra

Related Subjects

36 MATERIALS SCIENCE

Title: Symmetries and multiferroic properties of novel room-temperature magnetoelectrics: Lead iron tantalate – lead zirconate titanate (PFT/PZT)

Citation Formats

References (41)

Similar Records

Related Subjects