Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Catalytic pyrolysis using UZM-44 aluminosilicate zeolite

Patent ·
OSTI ID:1110822
;
A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.
Research Organization:
UOP LLC, Des Plains, IL, USA
Sponsoring Organization:
USDOE
Assignee:
UOP LLC (Des Plaines, IL)
Patent Number(s):
8,609,911
Application Number:
13/792,879
OSTI ID:
1110822
Country of Publication:
United States
Language:
English

References (21)

Toluene Disproportionation and Methylation over Zeolites TNU-9, SSZ-33, ZSM-5, and Mordenite Using Different Reactor Systems journal February 2011
Deep oxidative desulfurization of fuels in redox ionic liquids based on iron chloride journal January 2009
A rational design of alkyl-aromatics dealkylation–transalkylation catalysts using C8 and C9 alkyl-aromatics as reactants journal October 2004
IM-5: A Highly Thermal and Hydrothermal Shape-Selective Cracking Zeolite journal February 2002
A profile refinement method for nuclear and magnetic structures journal June 1969
Comparison studies of xylene isomerization and disproportionation reactions between SSZ-33, TNU-9, mordenite and ZSM-5 zeolite catalysts journal January 2011
Synthesis of Mo/IM-5 catalyst and its catalytic behavior in methane non-oxidative aromatization journal April 2011
Synthesis, Structure Solution, Characterization, and Catalytic Properties of TNU-10:  A High-Silica Zeolite with the STI Topology journal April 2004
Synthesis, characterization, and catalytic properties of zeolites IM-5 and NU-88 journal April 2003
Synthesis of Mo/TNU-9 (TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization journal March 2011
Complex zeolite structure solved by combining powder diffraction and electron microscopy journal November 2006
Investigation into the shape selectivity of zeolite catalysts for biomass conversion journal April 2011
Conversion of methanol over 10-ring zeolites with differing volumes at channel intersections: comparison of TNU-9, IM-5, ZSM-11 and ZSM-5 journal January 2011
N,N-dialkylimidazolium dialkylphosphate ionic liquids: Their extractive performance for thiophene series compounds from fuel oils versus the length of alkyl group journal October 2008
Determination of the Pore Topology of Zeolite IM-5 by Means of Catalytic Test Reactions and Hydrocarbon Adsorption Measurements journal January 2000
A theoretical study of the stability of Cu2+ ion in IM-5 zeolite and the interaction of Cu-IM-5 with NO journal May 2009
Adsorption of Gases in Multimolecular Layers journal February 1938
Structure-reactivity relationship for aromatics transalkylation and isomerization process with TNU-9, MCM-22 and ZSM-5 zeolites, and their industrial implications journal February 2011
Synthesis, Crystal Structure, Characterization, and Catalytic Properties of TNU-9 journal August 2007
Co-Exchanged IM5, a Stable Zeolite for the Selective Catalytic Reduction of NO in the Presence of Water and SO 2 journal January 2003
Structure of the Polycrystalline Zeolite Catalyst IM-5 Solved by Enhanced Charge Flipping journal February 2007

Similar Records

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY