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Title: Observations of Co4+ in a Higher Spin State and the Increase in the Seebeck Coefficient of Thermoelectric Ca3Co4O9

Journal Article · · Physical Review Letters

Sponsoring Organization:
USDOE
OSTI ID:
1098895
Journal Information:
Physical Review Letters, Journal Name: Physical Review Letters Vol. 108 Journal Issue: 19; ISSN 0031-9007
Publisher:
American Physical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 45 works
Citation information provided by
Web of Science

References (24)

Scaling Behavior in Thermoelectric Misfit Cobalt Oxides journal July 2006
Does the orbital degeneracy play any role in the high thermopower of lamellar cobaltites? journal April 2007
Enhanced current transport at grain boundaries in high-Tc superconductors journal May 2005
Anisotropic thermopower and magnetothermopower in a misfit-layered calcium cobaltite journal May 2011
Direct measurement of charge transfer in thermoelectric Ca 3 Co 4 O 9 journal October 2008
Thermoelectric properties and microstructure of c-axis-oriented Ca3Co4O9 thin films on glass substrates journal October 2005
Direct measurement of Co-ion spin state transitions in Ca3Co4O9 using variable-temperature electron energy-loss spectroscopy journal March 2009
Importance of t 2 g e g hybridization in transition metal oxides journal March 2008
Direct Measurement of the Low-Temperature Spin-State Transition in LaCoO 3 journal July 2007
In situ growth of c-axis-oriented Ca3Co4O9 thin films on Si (100) journal February 2005
Electronic structure of misfit-layered calcium cobaltite journal October 2002
Clathrates of Group 14 with Alkali Metals: An Exploration journal August 2000
High-temperature transport and thermoelectric properties of Ca3Co4−xTixO9 journal July 2010
Complex thermoelectric materials journal February 2008
Effect of substrate on the atomic structure and physical properties of thermoelectric Ca 3 Co 4 O 9 thin films journal July 2011
Zintl Phases as Thermoelectric Materials: Tuned Transport Properties of the Compounds CaxYb1-xZn2Sb2 journal November 2005
Thin-film thermoelectric devices with high room-temperature figures of merit journal October 2001
Spin entropy as the likely source of enhanced thermopower in NaxCo2O4 journal May 2003
Thermoelectric properties of the Bi- and Na-substituted Ca3Co4O9 system journal May 2002
Cation substituted (Ca2CoO3)xCoO2 films and their thermoelectric properties journal June 2002
Enhanced spin fluctuations in Ca 3 Co 4 x Ti x O 9 single crystals journal October 2006
New Directions for Low-Dimensional Thermoelectric Materials journal April 2007
Large thermoelectric power in NaCo 2 O 4 single crystals journal November 1997
Misfit-layered cobaltite with an anisotropic giant magnetoresistance: Ca 3 Co 4 O 9 journal July 2000

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