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Preparation of cerium halide solvate complexes

Patent ·
OSTI ID:1089402

Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.

Research Organization:
LANL (Los Alamos National Laboratory (LANL), Los Alamos, NM (United States))
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-06NA25396
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
Patent Number(s):
8,501,484
Application Number:
13/420,159
OSTI ID:
1089402
Country of Publication:
United States
Language:
English

References (16)

An Ionic Liquid-Mediated Route to Cerium(III) Bromide Solvates journal May 2011
Phase transition and decomposition temperatures, heat capacities and viscosities of pyridinium ionic liquids journal June 2005
Competitive Complexation of Nitrates and Chlorides to Uranyl in a Room Temperature Ionic Liquid journal July 2010
Lanthanides and Actinides in Ionic Liquids journal June 2007
Controlled Hydrolysis of Lanthanide Complexes of the N-Donor Tripod Tris(2-pyridylmethyl)amine versus Bisligand Complex Formation journal May 2005
Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium( iii ) bromide journal January 2012
Oxidation in Nonclassical Organolanthanide Chemistry:  Synthesis, Characterization, and X-ray Crystal Structures of Cerium(III) and -(IV) Amides journal February 2004
A Convenient Route to Lanthanide Triiodide THF Solvates. Crystal Structures of LnI 3 (THF) 4 [Ln = Pr] and LnI 3 (THF) 3.5 [Ln = Nd, Gd, Y] journal January 2004
Room temperature ionic liquids of alkylimidazolium cations and fluoroanions journal September 2000
Synthesis of Heteroleptic Cerium(III) Anionic Amido-Tethered N-Heterocyclic Carbene Complexes journal April 2005
A short history of SHELX journal December 2007
CeBr/sub 3/ scintillators for gamma-ray spectroscopy journal December 2005
Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion journal October 1998
Speciation of Rare-Earth Metal Complexes in Ionic Liquids: A Multiple-Technique Approach journal January 2009
Dissolution of Lanthanide and Actinide Metals Using Iodine and 2-Propanol. Synthesis and x-ray Crystal Structures of LnI3(HO-i-Pr)4 (Ln = La, Ce) and Th2I4(O-i-Pr)4(HO-i-Pr)2 journal September 1995
Ionic Liquids for Lanthanide and Actinide Chemistry journal May 2010