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Office of Scientific and Technical Information
 

Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration

Patent ·
OSTI ID:1086955
;

Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Research Organization:
Northwestern University, Evanston, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-01ER15244
Assignee:
Northwestern University (Evanston, IL)
Patent Number(s):
8,470,075
Application Number:
13/608,940
OSTI ID:
1086955
Country of Publication:
United States
Language:
English

References (49)

Metal−Organic Frameworks Based on Double-Bond-Coupled Di-Isophthalate Linkers with High Hydrogen and Methane Uptakes journal May 2008
Strong H 2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg 3 (O 2 C-C 10 H 6 -CO 2 ) 3 journal July 2005
Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding journal August 2007
Effects of Surface Area, Free Volume, and Heat of Adsorption on Hydrogen Uptake in Metal−Organic Frameworks journal April 2006
Molecular Simulation of Carbon Dioxide/Methane/Hydrogen Mixture Adsorption in Metal−Organic Frameworks journal September 2006
Lithium-Doped Metal-Organic Frameworks for Reversible H2 Storage at Ambient Temperature journal June 2007
Click Chemistry: Diverse Chemical Function from a Few Good Reactions journal June 2001
Atomistic Simulations of CO 2 and N 2 Adsorption in Silica Zeolites:  The Impact of Pore Size and Shape † journal August 2002
High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites journal July 2005
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation journal January 2006
Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ] journal May 2005
Chiral porous coordination networks: rational design and applications in enantioselective processes journal November 2003
Immobilization of a Soluble Metal Complex in an Organic Network. Remarkable Catalytic Performance of a Porous Dialkoxyzirconium Polyphenoxide as a Functional Organic Zeolite Analogue journal May 1999
Alkali Metal Cation Effects on Hydrogen Uptake and Binding in Metal-Organic Frameworks journal September 2008
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites journal December 2006
Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks journal February 2008
Hydrogen storage in metal–organic frameworks journal January 2007
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane journal January 2008
Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents journal July 2006
Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials journal October 2007
The current status of hydrogen storage in metal–organic frameworks journal January 2008
A homochiral metal–organic porous material for enantioselective separation and catalysis journal April 2000
Hybrid porous solids past, present, future journal January 2008
Enhanced Hydrogen Uptake and the Electronic Structure of Lithium-Doped Metal−Organic Frameworks journal May 2008
Ligand-elaboration as a strategy for engendering structural diversity in porous metal–organic framework compounds journal January 2008
Li-decorated metal organic framework 5: A route to achieving a suitable hydrogen storage medium journal December 2007
Prospects for nanoporous metal-organic materials in advanced separations processes journal January 2004
Hydrogen-Bonded Supramolecular Architectures of Organic Salts Based on Aromatic Tetracarboxylic Acids and Amines journal November 2006
Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine journal February 1994
Why Li Doping in MOFs Enhances H 2 Storage Capacity? A Multi-scale Theoretical Study journal April 2008
Virial-type thermal equation of gas—solid adsorption journal January 1989
Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions journal July 2005
Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation journal May 2008
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n journal February 1999
Molecular simulation of separation of CO2 from flue gases in CU-BTC metal-organic framework journal January 2007
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition journal January 2008
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach journal July 2008
Separation of CO 2 from CH 4 Using Mixed-Ligand Metal−Organic Frameworks journal August 2008
Metal–Organic Frameworks as Efficient Materials for Drug Delivery journal September 2006
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal October 2007
Single-crystal structure validation with the program PLATON journal January 2003
Adsorption and separation of hydrogen isotopes in carbon nanotubes: Multicomponent grand canonical Monte Carlo simulations journal January 2002
A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis journal June 2005
Storage and Separation of CO 2 and CH 4 in Silicalite, C 168 Schwarzite, and IRMOF-1:  A Comparative Study from Monte Carlo Simulation journal January 2007
Chiral Porous Hybrid Solids for Practical Heterogeneous Asymmetric Hydrogenation of Aromatic Ketones journal September 2003
Matrix Isolation Chemistry in a Porous Metal−Organic Framework:  Photochemical Substitutions of N 2 and H 2 in Zn 4 O[(η 6 -1,4-Benzenedicarboxylate)Cr(CO) 3 ] 3 journal January 2008

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