Methods for thermodynamic evaluation of battery state of health

Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

Title: Methods for thermodynamic evaluation of battery state of health

Patent · Tue May 21 00:00:00 EDT 2013

OSTI ID:1083971

Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

View Patent

Cite

Export

Save

Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG03-00ER15035; FG02-03ER15425

Assignee:: California Institute of Technology (Pasadena, CA); Centre National de la Recherche Scientifique (Paris, FR)

Patent Number(s):: 8,446,127

Application Number:: 12/537,712

OSTI ID:: 1083971

Country of Publication:: United States

Language:: English

References (136)

Capacity fading of Li_xMn₂O₄ spinel electrodes studied by XRD and electroanalytical techniques Aurbach, D.; Levi, M. D.; Gamulski, K. Journal of Power Sources, Vol. 81-82, p. 472-479 https://doi.org/10.1016/S0378-7753(99)00204-9	journal	September 1999
Kinetics and thermodynamics of the Li/Li+ couple in tetrahydrofuran at low temperatures (195–295 K) Paddon, Christopher A.; Jones, Sarah E. Ward; Bhatti, Farrah L. Journal of Physical Organic Chemistry, Vol. 20, Issue 9 https://doi.org/10.1002/poc.1230	journal	January 2007
Thermal Modeling of Porous Insertion Electrodes Thomas, Karen E.; Newman, John Journal of The Electrochemical Society, Vol. 150, Issue 2 https://doi.org/10.1149/1.1531194	journal	January 2003
Subfluorinated graphite fluorides as electrode materials Yazami, Rachid; Hamwi, André https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7563542 US Patent Document 7,563,542	patent	July 2009
Thermodynamics and Phase Separation of Lithium Intercalation Materials Used in Lithium Ion Cells Yamaki, Jun-ichi; Egashira, Minato; Okada, Shigeto Electrochemistry, Vol. 69, Issue 9 https://doi.org/10.5796/electrochemistry.69.664	journal	January 2001
Entropy Changes Due to Structural Transformation in the Graphite Anode and Phase Change of the LiCoO[sub 2] Cathode Al Hallaj, S.; Venkatachalapathy, R.; Prakash, J. Journal of The Electrochemical Society, Vol. 147, Issue 7 https://doi.org/10.1149/1.1393549	journal	January 2000
Thermodynamics and Kinetics of Lithium Intercalation into Nb[sub 2]O[sub 5] Electrodes for a 2 V Rechargeable Lithium Battery Kumagai, Naoaki Journal of The Electrochemical Society, Vol. 146, Issue 9 https://doi.org/10.1149/1.1392455	journal	January 1999
Surface treatments of Li_1+xMn_2−xO₄ spinels for improved elevated temperature performance Amatucci, G. G.; Blyr, A.; Sigala, C. Solid State Ionics, Vol. 104, Issue 1-2, p. 13-25 https://doi.org/10.1016/S0167-2738(97)00407-4	journal	December 1997
Theoretical dependences of the free energyand chemical potential upon compositionin intercalation systems with repulsiveinteraction between guest ions Kudo, T.; Hibino, M. Electrochimica Acta, Vol. 43, Issue 7, p. 781-789 https://doi.org/10.1016/S0013-4686(97)00205-3	journal	January 1998
Study of the lithium insertion–deinsertion mechanism in nanocrystalline γ-Fe₂O₃ electrodes by means of electrochemical impedance spectroscopy Quintin, M.; Devos, O.; Delville, M. H. Electrochimica Acta, Vol. 51, Issue 28, p. 6426-6434 https://doi.org/10.1016/j.electacta.2006.04.027	journal	September 2006
EELS analysis of electrochemically deintercalated Li_1−xMn₂O₄ and substituted spinels LiMn_1.6M_0.4O₄ (M = Co, Cr, Ni) Shiraishi, Youhei; Nakai, Izumi; Kimoto, Koji Journal of Power Sources, Vol. 97-98, p. 461-464 https://doi.org/10.1016/S0378-7753(01)00693-0	journal	July 2001
Effect of sintering temperature on the characteristics of carbons based on mesocarbon microbeads Bhatia, G.; Aggarwal, R. K.; Punjabi, N. Journal of Materials Science, Vol. 32, Issue 1, p. 135-139 https://doi.org/10.1023/A:1018587418496	journal	January 1997
Thermodynamic assessment of the Al–Li system Hallstedt, Bengt; Kim, Olga International Journal of Materials Research, Vol. 98, Issue 10 https://doi.org/10.3139/146.101553	journal	October 2007
Understanding the voltage profile of Li insertion into LiNi_0.5−yFe_yMn_1.5O₄ in Li cells Vicente, C. Pérez; Lloris, J. M.; Tirado, J. L. Electrochimica Acta, Vol. 49, Issue 12, p. 1963-1967 https://doi.org/10.1016/j.electacta.2003.12.025	journal	May 2004
“Diamond-like” 3-fold coordinated amorphous carbon Wada, N.; Gaczi, P. J.; Solin, S. A. Journal of Non-Crystalline Solids, Vol. 35-36, p. 543-548 https://doi.org/10.1016/0022-3093(80)90651-1	journal	January 1980
Method for estimating states and parameters of an electrochemical cell Tate, Jr., Edward D.; Verbrugge, Mark W.; Koch, Brian J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7109685 US Patent Document 7,109,685	patent	September 2006
Characterization of commercial Li-ion batteries using electrochemical–calorimetric measurements Al Hallaj, S.; Prakash, J.; Selman, J. R. Journal of Power Sources, Vol. 87, Issue 1-2, p. 186-194 https://doi.org/10.1016/S0378-7753(99)00472-3	journal	April 2000
A thermodynamic, structural and kinetic study of the electrochemical lithium intercalation into the xerogel V₂O₅ · 1.6 H₂O in a propylene Baddour, R.; Pereira-Ramos, J. P.; Messina, R. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 314, Issue 1-2, p. 81-101 https://doi.org/10.1016/0022-0728(91)85430-W	journal	September 1991
Battery capacity measuring method and apparatus Thompson, Arthur; Ballester, Ricardo H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4295097 US Patent Document 4,295,097	patent	October 1981
Heat-Generation Rate and General Energy Balance for Insertion Battery Systems Rao, Lin Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837884	journal	January 1997
First-Principles Evidence for Stage Ordering in Li[sub x]CoO[sub 2] Van der Ven, Anton Journal of The Electrochemical Society, Vol. 145, Issue 6 https://doi.org/10.1149/1.1838610	journal	January 1998
Neutron scattering studies of disordered carbon anode materials Papanek, P.; Kamitakahara, W. A.; Zhou, P. Journal of Physics: Condensed Matter, Vol. 13, Issue 36 https://doi.org/10.1088/0953-8984/13/36/305	journal	August 2001
Role of elasticity forces in thermodynamics of intercalation compounds: Self-consistent mean-field theory and Monte Carlo simulations Kalikmanov, V. I.; de Leeuw, S. W. The Journal of Chemical Physics, Vol. 116, Issue 7 https://doi.org/10.1063/1.1436472	journal	February 2002
Lithium Insertion in Disordered Carbon−Hydrogen Alloys: Intercalation vs Covalent Binding Papanek, P.; Fischer, J. E. Chemistry of Materials, Vol. 8, Issue 7 https://doi.org/10.1021/cm960100x	journal	January 1996
Determination of the reversible and irreversible heats of LiNi_0.8Co_0.2O₂/mesocarbon microbead Li-ion cell reactions using isothermal microcalorimetery Lu, Wenquan; Yang, Hui; Prakash, Jai Electrochimica Acta, Vol. 51, Issue 7, p. 1322-1329 https://doi.org/10.1016/j.electacta.2005.06.028	journal	January 2006
Thermodynamics of spinel Li_xTiO₂ from first principles Wagemaker, M.; Van Der Ven, A.; Morgan, D. Chemical Physics, Vol. 317, Issue 2-3, p. 130-136 https://doi.org/10.1016/j.chemphys.2005.05.011	journal	October 2005
Enhanced Low-Temperature Performance of Li–CF[sub x] Batteries Whitacre, J. F.; West, W. C.; Smart, M. C. Electrochemical and Solid-State Letters, Vol. 10, Issue 7 https://doi.org/10.1149/1.2735823	journal	January 2007
Carbonization and graphitization Oberlin, A. Carbon, Vol. 22, Issue 6, p. 521-541 https://doi.org/10.1016/0008-6223(84)90086-1	journal	January 1984
Battery management system and battery simulator Notten, Petrus H. L.; Bergveld, Hendrik Johannes; Kruijt, Wanda S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6016047 US Patent Document 6,016,047	patent	January 2000
Computer simulation of a porous positive electrode for lithium batteries Doi, Takayuki; Fukudome, Hirotaka; Okada, Shigeto Journal of Power Sources, Vol. 174, Issue 2, p. 779-783 https://doi.org/10.1016/j.jpowsour.2007.06.089	journal	December 2007
Effects of the LiFePO4 content and the preparation method on the properties of (LiFePO4+AC)/Li4Ti5O12 hybrid batterycapacitors Hu, Xue; Lin, Zi; Liu, Li Journal of the Serbian Chemical Society, Vol. 75, Issue 9 https://doi.org/10.2298/JSC091228105H	journal	January 2010
LiMO₂ (M=Mn, Fe, and Co): Energetics, polymorphism and phase transformation Wang, Miaojun; Navrotsky, Alexandra Journal of Solid State Chemistry, Vol. 178, Issue 4, p. 1230-1240 https://doi.org/10.1016/j.jssc.2005.01.028	journal	April 2005
Revisited structures of dense and dilute stage II lithium-graphite intercalation compounds Billaud, D.; Henry, F. X.; Lelaurain, M. Journal of Physics and Chemistry of Solids, Vol. 57, Issue 6-8, p. 775-781 https://doi.org/10.1016/0022-3697(95)00348-7	journal	June 1996
First-Principles Investigation of Phase Stability in the O2-LiCoO ₂ System Carlier, D.; Van der Ven, A.; Delmas, C. Chemistry of Materials, Vol. 15, Issue 13 https://doi.org/10.1021/cm030002t	journal	July 2003
Thermodynamic Stability and Cathode Performance of LiMn_2-_xMg_xO₄ as Cathode Active Material for the Lithium Secondary Battery Idemoto, Yasushi; Ogawa, Syuhei; Koura, Nobuyuki Electrochemistry, Vol. 68, Issue 6 https://doi.org/10.5796/electrochemistry.68.469	journal	January 2000
Raman Spectrum of Graphite Tuinstra, F.; Koenig, J. L. The Journal of Chemical Physics, Vol. 53, Issue 3 https://doi.org/10.1063/1.1674108	journal	August 1970
Size effects on mass transport and storage in lithium batteries Maier, Joachim Journal of Power Sources, Vol. 174, Issue 2, p. 569-574 https://doi.org/10.1016/j.jpowsour.2007.06.246	journal	December 2007
Hexagonal to Cubic Spinel Transformation in Lithiated Cobalt Oxide Gabrisch, Heike; Yazami, Rachid; Fultz, Brent Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1738677	journal	January 2004
Relationship Between Calorimetric and Structural Characteristics of Lithium-Ion Cells I. Thermal Analysis and Phase Diagram Hong, Jong-Sung; Selman, J. R. Journal of The Electrochemical Society, Vol. 147, Issue 9 https://doi.org/10.1149/1.1393881	journal	January 2000
Self-diagnosis system for an energy storage device Vaillancourt, Jean-Pierre; Lague, Frederic; Richard, Monique N. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7132832 US Patent Document 7,132,832	patent	November 2006
Determination of Standard Free Energy of Formation for Niobium Silicides by EMF Measurements Fujiwara, Hiroyasu; Ueda, Yukitomi; Awasthi, Alok Journal of The Electrochemical Society, Vol. 150, Issue 8 https://doi.org/10.1149/1.1591757	journal	January 2003
Analysis of Heat Generation of Lithium Ion Rechargeable Batteries Used in Implantable Battery Systems for Driving Undulation Pump Ventricular Assist Device Okamoto, Eiji; Nakamura, Masatoshi; Akasaka, Yuhta Artificial Organs, Vol. 31, Issue 7 https://doi.org/10.1111/j.1525-1594.2007.00415.x	journal	July 2007
Average Voltage, Energy Density, and Specific Energy of Lithium-Ion Batteries Deiss, E. Journal of The Electrochemical Society, Vol. 144, Issue 11 https://doi.org/10.1149/1.1838105	journal	January 1997
Method for preparation of graphite fluoride by contact reaction between carbon and fluorine gas Aramaki, Minoru; Kita, Yasushi; Nakano, Hishagi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4438086 US Patent Document 4,438,086	patent	March 1984
Heats of mixing and of entropy in porous insertion electrodes Thomas, Karen E.; Newman, John Journal of Power Sources, Vol. 119-121, p. 844-849 https://doi.org/10.1016/S0378-7753(03)00283-0	journal	June 2003
A Nanocrystalline Ferric Oxide Cathode for Rechargeable Lithium Batteries John Xu, Jun; Jain, Gaurav Electrochemical and Solid-State Letters, Vol. 6, Issue 9 https://doi.org/10.1149/1.1595313	journal	January 2003
Battery test outputs adjusted based upon battery temperature and the state of discharge of the battery Klang, James K.; Fang, Gregpry P. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040046564 US Patent Application 10/654098; 20040046564	patent-application	March 2004
Hollandite cathodes for lithium ion batteries. 2. Thermodynamic and kinetics studies of lithium insertion into BaMMn7O16 (M=Mg, Mn, Fe, Ni) Barbato, S. Electrochimica Acta, Vol. 46, Issue 18 https://doi.org/10.1016/S0013-4686(01)00506-0	journal	May 2001
Crystal structure and cathode performance dependence on oxygen content of LiMn1.5Ni0.5O4 as a cathode material for secondary lithium batteries Idemoto, Yasushi; Narai, Hirosuke; Koura, Nobuyuki Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00140-X	journal	June 2003
Thermodynamics of Electrode Materials for Lithium-Ion Batteries Yazami, Rachid Lithium Ion Rechargeable Batteries: Materials, Technology, and New Applications https://doi.org/10.1002/9783527629022.ch5	book	June 2009
Dependence of Properties, Crystal Structure and Electrode Characteristics on Li Content for LixCo1/3Ni1/3Mn1/3O2+.DELTA. as a Cathode Active Material for Li Secondary Battery [Ｌｉ二次電池正極活物質ＬｉｘＣｏ１／３Ｎｉ１／３Ｍｎ１／３Ｏ２＋δの物性，結晶構造と電極特性のＬｉ組成依存] Idemoto, Yasushi; Sakaya, Taku; Koura, Nobuyuki Electrochemistry, Vol. 74, Issue 9 https://doi.org/10.5796/electrochemistry.74.752	journal	January 2006
Staging Phase Transitions in Li[sub x]CoO[sub 2] Chen, Zhaohui; Lu, Zhonghua; Dahn, J. R. Journal of The Electrochemical Society, Vol. 149, Issue 12 https://doi.org/10.1149/1.1519850	journal	January 2002
Isothermal calorimetry investigation of Li_1+xMn_2−yAl_zO₄ spinel Lu, W.; Belharouak, I.; Park, S. H. Electrochimica Acta, Vol. 52, Issue 19, p. 5837-5842 https://doi.org/10.1016/j.electacta.2007.03.005	journal	May 2007
Carbon fluoride particles, preparation process and users of the same Yamana, Masayuki; Kitahara, Takahiro; Isogai, Tomohiro https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6068921 US Patent Document 6,068,921	patent	May 2000
Voltage prediction from Coulomb potential created by atoms of spinel LiMn₂O₄ cathode active material for Li ion cells Yamaki, Jun-ichi; Egashira, Minato; Okada, Shigeto Journal of Power Sources, Vol. 97-98, p. 349-353 https://doi.org/10.1016/S0378-7753(01)00629-2	journal	July 2001
On the Synthesis of Ramsdellite LiTiMO4 (M = Ti, V, Cr, Mn, Fe): An Experimental and Computational Study of the Spinel–Ramsdellite Transformation Kuhn, Alois; Díaz-Carrasco, Pilar; Arroyo y. de Dompablo, María Elena European Journal of Inorganic Chemistry, Vol. 2007, Issue 21 https://doi.org/10.1002/ejic.200600993	journal	July 2007
Thermodynamic Aspects of the Reaction of Lithium with SnP[sub 2]O[sub 7] Based Positive Electrodes Attidekou, Pierrot S.; García-Alvarado, F.; Connor, Paul A. Journal of The Electrochemical Society, Vol. 154, Issue 3 https://doi.org/10.1149/1.2424410	journal	January 2007
Entropy measurements on Li _x TiS ₂ Dahn, J. R.; Haering, R. R. Canadian Journal of Physics, Vol. 61, Issue 7 https://doi.org/10.1139/p83-140	journal	July 1983
Microcalorimetric studies on lithium thionyl chloride cells: temperature effects between 25 °C and −40 °C Hill, I. R.; Sibbald, A. M.; Donepudi, V. S. Journal of Power Sources, Vol. 39, Issue 1, p. 83-94 https://doi.org/10.1016/0378-7753(92)85008-X	journal	January 1992
Double-layer and pseudocapacitance types of electrochemical capacitors and their applications to the development of hybrid devices Conway, B. E.; Pell, W. G. Journal of Solid State Electrochemistry, Vol. 7, Issue 9, p. 637-644 https://doi.org/10.1007/s10008-003-0395-7	journal	September 2003
Electrochemical intercalation of lithium species into disordered carbon prepared by the heat-treatment of poly (p-phenylene) at 650°C for anode in lithium-ion battery Gong, Jinbao; Wu, Haoqing Electrochimica Acta, Vol. 45, Issue 11, p. 1753-1762 https://doi.org/10.1016/S0013-4686(99)00400-4	journal	February 2000
Thermal studies of a lithium-ion battery Saito, Yoshiyasu; Kanari, Katsuhiko; Takano, Kiyonami Journal of Power Sources, Vol. 68, Issue 2 https://doi.org/10.1016/S0378-7753(96)02583-9	journal	October 1997
Method and apparatus for estimating state of charge of secondary battery Murakami, Yusai; Yamabe, Norito; Minamiura, Keiichi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050073315 US Patent Application 10/953013; 20050073315	patent-application	April 2005
Electronic Structure of Chemically-Delithiated LiCoO ₂ Studied by Electron Energy-Loss Spectrometry Graetz, J.; Hightower, A.; Ahn, C. C. The Journal of Physical Chemistry B, Vol. 106, Issue 6 https://doi.org/10.1021/jp0133283	journal	February 2002
Molecular thermodynamics approach for phase behaviors of solid polymer electrolytes/salt system in lithium secondary battery on the nonrandom mixing effect: Applicability of the group-contribution method Joo, Jae Ho; Bae, Young Chan Polymer, Vol. 47, Issue 20, p. 7153-7159 https://doi.org/10.1016/j.polymer.2006.05.072	journal	September 2006
Charging rate estimating method, charging rate estimating unit and battery system Iwane, Noriyasu; Watanabe, Yuichi; Sugimura, Takezo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060208704 US Patent Application 10/552674; 20060208704	patent-application	September 2006
Electrochemical-Calorimetric Studies of Lithium-Ion Cells Hong, Jong-Sung Journal of The Electrochemical Society, Vol. 145, Issue 5 https://doi.org/10.1149/1.1838509	journal	January 1998
Thermodynamics and kinetics of electrochemical intercalation of lithium into Li_0.50WO_3.25 with a hexagonal tungsten bronze structure Kumagai, Naoaki; Yu, Aishui; Yashiro, Hitoshi Solid State Ionics, Vol. 98, Issue 3-4, p. 159-166 https://doi.org/10.1016/S0167-2738(97)00114-8	journal	June 1997
Thermodynamics and crystal structure anomalies in lithium-intercalated graphite Yazami, Rachid; Reynier, Yvan Journal of Power Sources, Vol. 153, Issue 2, p. 312-318 https://doi.org/10.1016/j.jpowsour.2005.05.087	journal	February 2006
Lithium Manganese Oxides with Spinel Structure and Their Cathode Properties for Lithium Ion Battery Wakihara, Masataka Electrochemistry, Vol. 73, Issue 5 https://doi.org/10.5796/electrochemistry.73.328	journal	January 2005
Electrochemical Thermodynamic Measurement System Reynier, Yvan; Yazami, Rachid; Fultz, Brent T. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070182418 US Patent Application 11/462290; 20070182418	patent-application	August 2007
Effect of the ZnNi y Mn2– y O4 (0 ≤ y ≤ 1) spinel composition on electrochemical lithium insertion Gautier, J. L.; Meza, E.; Silva, E. Journal of Solid State Electrochemistry, Vol. 1, Issue 2 https://doi.org/10.1007/s100080050036	journal	September 1997
Crystallite growth in graphitizing and non-graphitizing carbons Franklin, Rosalind E. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 209, Issue 1097, p. 196-218 https://doi.org/10.1098/rspa.1951.0197	journal	October 1951
Charge-Discharge Characteristics of the Mesocarbon Miocrobeads Heat-Treated at Different Temperatures Mabuchi, Akihiro Journal of The Electrochemical Society, Vol. 142, Issue 4 https://doi.org/10.1149/1.2044128	journal	January 1995
Phase Diagrams for Systems with Low Free Energy Variation: A Coupled Theory/Experiments Method Applied to Li-Graphite Filhol, J. -S.; Combelles, C.; Yazami, R. The Journal of Physical Chemistry C, Vol. 112, Issue 10 https://doi.org/10.1021/jp076597n	journal	March 2008
Circuit and method for determining battery impedance increase with aging Barsoukov, Evgenij; Poole, Dan R.; Freeman, David L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040128089 US Patent Application 10/428659; 20040128089	patent-application	July 2004
Lithium Storage Mechanism of Disordered Mesophase Carbon Fibers Studied by [sup 7]Li-Nuclear Magnetic Resonance Kataoka, Hiroshi; Saito, Yuria; Omae, Osamu Electrochemical and Solid-State Letters, Vol. 5, Issue 1 https://doi.org/10.1149/1.1419704	journal	January 2002
The Mechanisms of Lithium and Sodium Insertion in Carbon Materials Stevens, D. A.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 148, Issue 8 https://doi.org/10.1149/1.1379565	journal	January 2001
Electrochemical thermodynamic measurement system Reynier, Yvan; Yazami, Rachid; Fultz, Brent T. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7595611 US Patent Document 7,595,611	patent	September 2009
Factors Influencing the Capacity Fade of Spinel Lithium Manganese Oxides Shin, Youngjoon; Manthiram, Arumugam Journal of The Electrochemical Society, Vol. 151, Issue 2 https://doi.org/10.1149/1.1634274	journal	January 2004
Thermal Model for a Li-Ion Cell Kumaresan, Karthikeyan; Sikha, Godfrey; White, Ralph E. Journal of The Electrochemical Society, Vol. 155, Issue 2 https://doi.org/10.1149/1.2817888	journal	January 2008
Kinetics and thermodynamics of the lithium insertion reaction in spinel phase Li_xMn₂O₄ Barker, J.; West, K.; Saidi, Y. Journal of Power Sources, Vol. 54, Issue 2, p. 475-478 https://doi.org/10.1016/0378-7753(94)02128-P	journal	April 1995
The elevated temperature performance of the LiMn₂O₄/C system: failure and solutions Amatucci, G.; Du Pasquier, A.; Blyr, A. Electrochimica Acta, Vol. 45, Issue 1-2, p. 255-271 https://doi.org/10.1016/S0013-4686(99)00209-1	journal	September 1999
Thermal simulation of large-scale lithium secondary batteries using a graphite–coke hybrid carbon negative electrode and LiNi_0.7Co_0.3O₂ positive electrode Funahashi, Atsuhiro; Kida, Yoshinori; Yanagida, Katsunori Journal of Power Sources, Vol. 104, Issue 2, p. 248-252 https://doi.org/10.1016/S0378-7753(01)00958-2	journal	February 2002
Thermal study on single electrodes in lithium-ion battery Huang, Qian; Yan, Manming; Jiang, Zhiyu Journal of Power Sources, Vol. 156, Issue 2, p. 541-546 https://doi.org/10.1016/j.jpowsour.2005.05.083	journal	June 2006
In Situ Thermal Study of Li[sub 1+x][Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]][sub 1−x]O[sub 2] Using Isothermal Micro-clorimetric Techniques Lu, W.; Belharouak, I.; Vissers, D. Journal of The Electrochemical Society, Vol. 153, Issue 11 https://doi.org/10.1149/1.2349287	journal	January 2006
Transmission Electron Microscope Studies of LiNi[sub 1/3]Mn[sub 1/3]Co[sub 1/3]O[sub 2] before and after Long-Term Aging at 70°C Gabrisch, Heike; Yi, Tanghong; Yazami, Rachid Electrochemical and Solid-State Letters, Vol. 11, Issue 7 https://doi.org/10.1149/1.2919713	journal	January 2008
Identity and thermodynamics of lithium intercalated in graphite Lee, Hsiang-Hwan; Wan, Chi-Chao; Wang, Yung-Yun Journal of Power Sources, Vol. 114, Issue 2, p. 285-291 https://doi.org/10.1016/S0378-7753(02)00606-7	journal	March 2003
Thermodynamic and kinetic approaches to lithium intercalation into a Li_1−δMn₂O₄ electrode using Monte Carlo simulation Kim, Sung-Woo; Pyun, Su-Il Electrochimica Acta, Vol. 46, Issue 7, p. 987-997 https://doi.org/10.1016/S0013-4686(00)00687-3	journal	January 2001
Effect of Mg-doping on the structural and electronic properties of LiCoO₂: A first-principles investigation Shi, Siqi; Ouyang, Chuying; Lei, Minsheng Journal of Power Sources, Vol. 171, Issue 2, p. 908-912 https://doi.org/10.1016/j.jpowsour.2007.07.005	journal	September 2007
First-principles studies of cation-doped spinel ${LiMn}_{2} O_{4}$ for lithium ion batteries Shi, Siqi; Wang, Ding-sheng; Meng, Sheng Physical Review B, Vol. 67, Issue 11 https://doi.org/10.1103/PhysRevB.67.115130	journal	March 2003
Potential and Thermodynamics of Graphite Anodes in Li-Ion Cells Yamaki, Jun-ichi; Egashira, Minato; Okada, Shigeto Journal of The Electrochemical Society, Vol. 147, Issue 2 https://doi.org/10.1149/1.1393218	journal	January 2000
Method of Detecting Condition of a Secondary Battery Tsuruta, Sho; Yanagida, Katsumori https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110121786 US Patent Application 12/953970; 20110121786	patent-application	May 2011
CoO₂, The End Member of the Li_xCoO₂ Solid Solution Amatucci, G. G.; Tarascon, J. M.; Klein, L. C. Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123 https://doi.org/10.1149/1.1836594	journal	January 1996
Correlating Capacity Loss of Stoichiometric and Nonstoichiometric Lithium Manganese Oxide Spinel Electrodes with Their Structural Integrity Huang, Haitao Journal of The Electrochemical Society, Vol. 146, Issue 10 https://doi.org/10.1149/1.1392528	journal	January 1999
Raman spectroscopic characterization of graphites: A re-evaluation of spectra/ structure correlation Nikiel, Leszek; Jagodzinski, Paul W. Carbon, Vol. 31, Issue 8, p. 1313-1317 https://doi.org/10.1016/0008-6223(93)90091-N	journal	January 1993
Thermodynamics of Lithium Intercalates in Carbonized Fabric Ol'shanskaya, L. N.; Astaf'eva, E. N. Russian Journal of Applied Chemistry, Vol. 75, Issue 5, p. 740-744 https://doi.org/10.1023/A:1020398126438	journal	January 2002
Evolution of lithiation thermodynamics with the graphitization of carbons Reynier, Y.; Yazami, R.; Fultz, B. Journal of Power Sources, Vol. 165, Issue 2, p. 552-558 https://doi.org/10.1016/j.jpowsour.2006.10.024	journal	March 2007
Method and apparatus for charging a rechargeable battery with monitoring of battery temperature rate of change Stuck Andersen, Kim Arthur; Rasmussen, Kim; Ostergaard, Kim https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20010001533 US Patent Application 09/747507; 20010001533	patent-application	May 2001
Le processus de la graphitation Mering, J.; Maire, J. Journal de Chimie Physique, Vol. 57 https://doi.org/10.1051/jcp/1960570803	journal	January 1960
Graphitization studies of anthracites by high resolution electron microscopy Oberlin, A.; Terriere, G. Carbon, Vol. 13, Issue 5, p. 367-376 https://doi.org/10.1016/0008-6223(75)90004-4	journal	January 1975
Cooperative research on safety fundamentals of lithium batteries Selman, J. Robert; Al Hallaj, Said; Uchida, Isamu Journal of Power Sources, Vol. 97-98, p. 726-732 https://doi.org/10.1016/S0378-7753(01)00732-7	journal	July 2001
Lithium ion rapid charging system and method Van Schalkwijk, Walter A.; Penn, Richard https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7227336 US Patent Document 7,227,336	patent	June 2007
Phase behaviors of solid polymer electrolytes/salt system in lithium secondary battery by group-contribution method: The pressure effect Joo, Jae Ho; Bae, Young Chan; Sun, Yang Kook Polymer, Vol. 47, Issue 1, p. 211-217 https://doi.org/10.1016/j.polymer.2005.11.022	journal	January 2006
Mathematical modeling of secondary lithium batteries Botte, Gerardine G.; Subramanian, Venkat R.; White, Ralph E. Electrochimica Acta, Vol. 45, Issue 15-16, p. 2595-2609 https://doi.org/10.1016/S0013-4686(00)00340-6	journal	May 2000
Lithium doping/undoping in disordered coke carbons Mori, Y.; Iriyama, T.; Hashimoto, T. Journal of Power Sources, Vol. 56, Issue 2, p. 205-208 https://doi.org/10.1016/0378-7753(95)80036-G	journal	August 1995
Thermodynamic and Kinetic Studies of Electrochemical Lithium Insertion into Quaternary Li-Mn-V-O Spinel as Positive Materials for Rechargeable Lithium Batteries Kumagai, Naoaki Journal of The Electrochemical Society, Vol. 140, Issue 11 https://doi.org/10.1149/1.2221009	journal	January 1993
First principles predictions for intercalation behaviour Koudriachova, M. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.09.050	journal	November 2004
Enthalpy of formation of LiNiO2, LiCoO2 and their solid solution, LiNi1−xCoxO2 Wang, M. Solid State Ionics, Vol. 166, Issue 1-2 https://doi.org/10.1016/j.ssi.2003.11.004	journal	January 2004
Method and apparatus for determining the state-of-charge of batteries particularly lithium batteries Peled, Emanuel; Yamin, Herzel; Reshef, Israel https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4725784 US Patent Document 4,725,784	patent	February 1988
Electrochemical intercalation of lithium into hexagonal tungsten trioxide Kumagai, Naoaki; Yu, Aishui; Kumagai, Nobuko Thermochimica Acta, Vol. 299, Issue 1-2, p. 19-25 https://doi.org/10.1016/S0040-6031(97)00131-7	journal	September 1997
Electrochemically-driven solid-state amorphization in lithium–metal anodes Limthongkul, Pimpa; Jang, Young-Il; Dudney, Nancy J. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00303-3	journal	June 2003
The entropy and enthalpy of lithium intercalation into graphite Reynier, Y.; Yazami, R.; Fultz, B. Journal of Power Sources, Vol. 119-121, p. 850-855 https://doi.org/10.1016/S0378-7753(03)00285-4	journal	June 2003
Battery operation for extended cycle life Barker, Jeremy; Gao, Feng https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6392385 US Patent Document 6,392,385	patent	May 2002
Thermal behavior of small lithium-ion secondary battery during rapid charge and discharge cycles Ohshima, Takamasa; Nakayama, Masato; Fukuda, Kenichi Electrical Engineering in Japan, Vol. 157, Issue 3 https://doi.org/10.1002/eej.20249	journal	January 2006
Thermodynamics of Lithium Intercalation into Graphites and Disordered Carbons Reynier, Y. F.; Yazami, R.; Fultz, B. Journal of The Electrochemical Society, Vol. 151, Issue 3 https://doi.org/10.1149/1.1646152	journal	January 2004
Structural determination of Li _1−y Ni _0.5 Mn _0.5 O ₂ (y = 0.5) using a combination of Rietveld analysis and the maximum entropy method Kobayashi, Hironori; Arachi, Yoshinori; Kageyama, Hiroyuki J. Mater. Chem., Vol. 14, Issue 1 https://doi.org/10.1039/B311827D	journal	January 2004
Structure and electron density analysis of electrochemically and chemically delithiated LiCoO₂ single crystals Takahashi, Yasuhiko; Kijima, Norihito; Dokko, Kaoru Journal of Solid State Chemistry, Vol. 180, Issue 1, p. 313-321 https://doi.org/10.1016/j.jssc.2006.10.018	journal	January 2007
First Principles Calculation of Electrode Material for Lithium Intercalation Batteries: TiS2 and LiTi2S4 Cubic Spinel Structures Benco, Ľubomı́r; Barras, Jean-Luc; Atanasov, Michail Journal of Solid State Chemistry, Vol. 145, Issue 2 https://doi.org/10.1006/jssc.1999.8195	journal	July 1999
Correlation between Volume Change and Cell Voltage Variation with Composition for Lithium Intercalated Amorphous Films Garcia-Belmonte, Germà; García-Cañadas, Jorge; Bisquert, Juan The Journal of Physical Chemistry B, Vol. 110, Issue 10 https://doi.org/10.1021/jp060171b	journal	March 2006
A First-Principles Approach to Studying the Thermal Stability of Oxide Cathode Materials Wang, L.; Maxisch, T.; Ceder, G. Chemistry of Materials, Vol. 19, Issue 3 https://doi.org/10.1021/cm0620943	journal	February 2007
Measurement of the Entropy of Reaction as a Function of State of Charge in Doped and Undoped Lithium Manganese Oxide Thomas, Karen E.; Bogatu, Christian; Newman, John Journal of The Electrochemical Society, Vol. 148, Issue 6 https://doi.org/10.1149/1.1369365	journal	January 2001
Ab initio study of lithium intercalation in metal oxides and metal dichalcogenides Aydinol, M. K.; Kohan, A. F.; Ceder, G. Physical Review B, Vol. 56, Issue 3 https://doi.org/10.1103/PhysRevB.56.1354	journal	July 1997
Lithium intercalation studies in hydrated molybdenum oxides Guzman, G.; Yebka, B.; Livage, J. Solid State Ionics, Vol. 86-88, p. 407-413 https://doi.org/10.1016/0167-2738(96)00338-4	journal	July 1996
Lithium Intercalation into Layered LiMnO[sub 2] Vitins, G. Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837869	journal	January 1997
Phase diagrams of lithium transition metal oxides: investigations from first principles Ceder, Gerbrand; Van der Ven, Anton Electrochimica Acta, Vol. 45, Issue 1-2, p. 131-150 https://doi.org/10.1016/S0013-4686(99)00199-1	journal	September 1999
The first in situ ⁷Li NMR study of the reversible lithium insertion mechanism in disorganised carbons Letellier, Michel; Chevallier, Frédéric; Béguin, François Journal of Physics and Chemistry of Solids, Vol. 65, Issue 2-3, p. 245-251 https://doi.org/10.1016/j.jpcs.2003.10.022	journal	March 2004
Thermodynamic equations for a model lithium-ion cell Sandhu, S. S.; Fellner, J. P. Electrochimica Acta, Vol. 45, Issue 6, p. 969-976 https://doi.org/10.1016/S0013-4686(99)00297-2	journal	December 1999
Fluorinated carbon nanofibres for high energy and high power densities primary lithium batteries Yazami, R.; Hamwi, A.; Guérin, K. Electrochemistry Communications, Vol. 9, Issue 7, p. 1850-1855 https://doi.org/10.1016/j.elecom.2007.04.013	journal	July 2007
State and parameter estimation for an electrochemical cell Plett, Gregory L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060100833 US Patent Application 10/985617; 20060100833	patent-application	May 2006
Thermodynamics of Oxides with Substitutional Disorder: A Microscopic Model and Evaluation of Important Energy Contributions Ceder, Gerbrand; Kohan, Adrian F.; Aydinol, Mehmet K. Journal of the American Ceramic Society, Vol. 81, Issue 3 https://doi.org/10.1111/j.1151-2916.1998.tb02369.x	journal	March 1998
Electrochemical cell Vitins, Girts; West, Keld; Koksbang, Rene https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6667131 US Patent Document 6,667,131	patent	December 2003
Solid-State Redox Reactions of LiCoO[sub 2] (R3m) for 4 Volt Secondary Lithium Cells Ohzuku, Tsutomu Journal of The Electrochemical Society, Vol. 141, Issue 11 https://doi.org/10.1149/1.2059267	journal	January 1994
Configurational Electronic Entropy and the Phase Diagram of Mixed-Valence Oxides: The Case of ${Li}_{x} {FePO}_{4}$ Zhou, Fei; Maxisch, Thomas; Ceder, Gerbrand Physical Review Letters, Vol. 97, Issue 15 https://doi.org/10.1103/PhysRevLett.97.155704	journal	October 2006
Lithium alloy negative electrodes Huggins, Robert A. Journal of Power Sources, Vol. 81-82, p. 13-19 https://doi.org/10.1016/S0378-7753(99)00124-X	journal	September 1999
Circuit and method for measurement of battery capacity fade Barsoukov, Evgenij; Poole, Dan R.; Freeman, David L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040220758 US Patent Application 10/428704; 20040220758	patent-application	November 2004

Similar Records

Methods and systems for thermodynamic evaluation of battery state of health

Patent · Tue Dec 02 00:00:00 EST 2014 · OSTI ID:1083971

Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; +1 more

Electrochemical thermodynamic measurement system

Patent · Tue Sep 29 00:00:00 EDT 2009 · OSTI ID:1083971

Reynier, Yvan; Yazami, Rachid; Fultz, Brent T

Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

Journal Article · Tue Dec 31 00:00:00 EST 2013 · Journal of Power Sources · OSTI ID:1083971

Hudak, Nicholas S.

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
36 MATERIALS SCIENCE

Title: Methods for thermodynamic evaluation of battery state of health

Citation Formats

References (136)

Similar Records

Related Subjects