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Title: Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography

Abstract

Activity coefficients of 52 organic compounds in four ionic liquids (ILs), 1,3-dimethoxyimidazolium bis((trifluoromethyl)sulfonyl)imide, 1-(methylethylether)-3-methylimidazolium bis((trifluoromethyl)sulfonyl) imide, 1-ethanol-3-methylimidazolium bis((trifluoromethyl)-sulfonyl)imide, and 1-(3-cyanopropyl)-3- methylimidazolium dicyanamide, were measured using inverse gas chromatography from (312 to 353) K. The retention data were also converted in gas-to-IL partition coefficients and water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the modified Abraham solvation parameter model. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within (0.09 and 0.14) log units, respectively.

Authors:
 [1];  [1];  [1];  [2];  [3];  [3];  [4]
  1. Laboratoire de Thermodynamique des Milieux Polyphases, Nancy-Universite, Nancy, France
  2. Laboratoire Reactions et Genie des Procedes CNRS UPR 3349, Nancy France
  3. University of North Texas
  4. ORNL
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1078198
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Journal Article
Journal Name:
Journal of Chemical & Engineering Data
Additional Journal Information:
Journal Volume: 55; Journal Issue: 7; Journal ID: ISSN 0021--9568
Country of Publication:
United States
Language:
English

Citation Formats

Revelli, Anne-Laure, Mutelet, Fabrice, Jaubert, Jean-Noel, Garcia-Martinez, Marina, Sprunger, Laura, Acree, William, and Baker, Gary A. Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography. United States: N. p., 2010. Web. doi:10.1021/je900838a.
Revelli, Anne-Laure, Mutelet, Fabrice, Jaubert, Jean-Noel, Garcia-Martinez, Marina, Sprunger, Laura, Acree, William, & Baker, Gary A. Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography. United States. https://doi.org/10.1021/je900838a
Revelli, Anne-Laure, Mutelet, Fabrice, Jaubert, Jean-Noel, Garcia-Martinez, Marina, Sprunger, Laura, Acree, William, and Baker, Gary A. 2010. "Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography". United States. https://doi.org/10.1021/je900838a.
@article{osti_1078198,
title = {Study of Ether-, Alcohol-, or Cyano-Functionalized Ionic Liquids Using Inverse Gas Chromatography},
author = {Revelli, Anne-Laure and Mutelet, Fabrice and Jaubert, Jean-Noel and Garcia-Martinez, Marina and Sprunger, Laura and Acree, William and Baker, Gary A},
abstractNote = {Activity coefficients of 52 organic compounds in four ionic liquids (ILs), 1,3-dimethoxyimidazolium bis((trifluoromethyl)sulfonyl)imide, 1-(methylethylether)-3-methylimidazolium bis((trifluoromethyl)sulfonyl) imide, 1-ethanol-3-methylimidazolium bis((trifluoromethyl)-sulfonyl)imide, and 1-(3-cyanopropyl)-3- methylimidazolium dicyanamide, were measured using inverse gas chromatography from (312 to 353) K. The retention data were also converted in gas-to-IL partition coefficients and water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the modified Abraham solvation parameter model. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within (0.09 and 0.14) log units, respectively.},
doi = {10.1021/je900838a},
url = {https://www.osti.gov/biblio/1078198}, journal = {Journal of Chemical & Engineering Data},
issn = {0021--9568},
number = 7,
volume = 55,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2010},
month = {Fri Jan 01 00:00:00 EST 2010}
}