skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Decoupling Charge Transport from the Structural Dynamics in Room Temperature Ionic Liquids.

Authors:
 [1];  [2];  [2];  [2];  [2];  [2];  [2]
  1. University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)
  2. ORNL
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1073652
DOE Contract Number:  
DE-AC05-00OR22725
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 135; Journal Issue: 11; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English

Citation Formats

Griffin, Phillip, Agapov, Alexander L, Kisliuk, Alexander, Sun, Xiao-Guang, Dai, Sheng, Novikov, Vladimir, and Sokolov, Alexei P. Decoupling Charge Transport from the Structural Dynamics in Room Temperature Ionic Liquids.. United States: N. p., 2011. Web. doi:10.1063/1.3638269.
Griffin, Phillip, Agapov, Alexander L, Kisliuk, Alexander, Sun, Xiao-Guang, Dai, Sheng, Novikov, Vladimir, & Sokolov, Alexei P. Decoupling Charge Transport from the Structural Dynamics in Room Temperature Ionic Liquids.. United States. doi:10.1063/1.3638269.
Griffin, Phillip, Agapov, Alexander L, Kisliuk, Alexander, Sun, Xiao-Guang, Dai, Sheng, Novikov, Vladimir, and Sokolov, Alexei P. Sat . "Decoupling Charge Transport from the Structural Dynamics in Room Temperature Ionic Liquids.". United States. doi:10.1063/1.3638269.
@article{osti_1073652,
title = {Decoupling Charge Transport from the Structural Dynamics in Room Temperature Ionic Liquids.},
author = {Griffin, Phillip and Agapov, Alexander L and Kisliuk, Alexander and Sun, Xiao-Guang and Dai, Sheng and Novikov, Vladimir and Sokolov, Alexei P},
abstractNote = {},
doi = {10.1063/1.3638269},
journal = {Journal of Chemical Physics},
issn = {0021-9606},
number = 11,
volume = 135,
place = {United States},
year = {2011},
month = {1}
}

Works referenced in this record:

Viscosity of a vitreous potassium nitrate - calcium nitrate mixture
journal, December 1969

  • Weiler, R.; Blaser, S.; Macedo, Pedro B.
  • The Journal of Physical Chemistry, Vol. 73, Issue 12
  • DOI: 10.1021/j100846a019

Ionic-liquid materials for the electrochemical challenges of the future
journal, July 2009

  • Armand, Michel; Endres, Frank; MacFarlane, Douglas R.
  • Nature Materials, Vol. 8, Issue 8, p. 621-629
  • DOI: 10.1038/nmat2448

Breakdown of Time−Temperature Superposition Principle and Universality of Chain Dynamics in Polymers
journal, May 2006

  • Ding, Yifu; Sokolov, Alexei P.
  • Macromolecules, Vol. 39, Issue 9
  • DOI: 10.1021/ma052607b

Self-Diffusion of Supercooled o -Terphenyl near the Glass Transition Temperature
journal, January 2006

  • Mapes, Marie K.; Swallen, Stephen F.; Ediger, M. D.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 1
  • DOI: 10.1021/jp0555955

Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 1. Variation of Anionic Species
journal, October 2004

  • Tokuda, Hiroyuki; Hayamizu, Kikuko; Ishii, Kunikazu
  • The Journal of Physical Chemistry B, Vol. 108, Issue 42
  • DOI: 10.1021/jp047480r

Dynamics of glass‐forming liquids. I. Temperature‐derivative analysis of dielectric relaxation data
journal, April 1995

  • Stickel, F.; Fischer, E. W.; Richert, R.
  • The Journal of Chemical Physics, Vol. 102, Issue 15
  • DOI: 10.1063/1.469071

Relaxation processes in supercooled liquids
journal, March 1992


Charge transport and mass transport in imidazolium-based ionic liquids
journal, May 2008


Crystal growth kinetics exhibit a fragility-dependent decoupling from viscosity
journal, January 2008

  • Ediger, M. D.; Harrowell, Peter; Yu, Lian
  • The Journal of Chemical Physics, Vol. 128, Issue 3
  • DOI: 10.1063/1.2815325

Inadequacies of Viscosity Theories for a Vitreous KNO3-Ca(NO3)2 Melt
journal, February 1971


Charge Transport and Dipolar Relaxations in Imidazolium-Based Ionic Liquids
journal, January 2010

  • Krause, C.; Sangoro, J. R.; Iacob, C.
  • The Journal of Physical Chemistry B, Vol. 114, Issue 1
  • DOI: 10.1021/jp908519u

Resolving the Mystery of the Chain Friction Mechanism in Polymer Liquids
journal, June 2009


A phenomenological model for the Meyer-Neldel rule
journal, October 1986


Indications for a change of diffusion mechanism in supercooled liquids
journal, September 1990


Unique Spatial Heterogeneity in Ionic Liquids
journal, September 2005

  • Wang, Yanting; Voth, Gregory A.
  • Journal of the American Chemical Society, Vol. 127, Issue 35
  • DOI: 10.1021/ja053796g

Dynamics of glass‐forming liquids. II. Detailed comparison of dielectric relaxation, dc‐conductivity, and viscosity data
journal, February 1996

  • Stickel, F.; Fischer, E. W.; Richert, R.
  • The Journal of Chemical Physics, Vol. 104, Issue 5
  • DOI: 10.1063/1.470961

Influence of molecular weight on dynamic crossover temperature in linear polymers
journal, June 2008


Self-Diffusion and Viscosity of Low Molecular Weight Polystyrene over a Wide Temperature Range
journal, February 2004

  • Urakawa, Osamu; Swallen, Stephen F.; Ediger, M. D.
  • Macromolecules, Vol. 37, Issue 4
  • DOI: 10.1021/ma0352025

Heterogeneity at the Glass Transition:  Translational and Rotational Self-Diffusion
journal, October 1997

  • Chang, Inyong; Sillescu, Hans
  • The Journal of Physical Chemistry B, Vol. 101, Issue 43
  • DOI: 10.1021/jp9640989

Appearance of a Debye process at the conductivity relaxation frequency of a viscous liquid
journal, March 2011

  • Richert, Ranko; Agapov, Alexander; Sokolov, Alexei P.
  • The Journal of Chemical Physics, Vol. 134, Issue 10
  • DOI: 10.1063/1.3565481

A short history of ionic liquids—from molten salts to neoteric solvents
journal, March 2002


Protic Ionic Liquids:  Properties and Applications
journal, January 2008

  • Greaves, Tamar L.; Drummond, Calum J.
  • Chemical Reviews, Vol. 108, Issue 1, p. 206-237
  • DOI: 10.1021/cr068040u

Ionic Liquids:  Ion Mobilities, Glass Temperatures, and Fragilities
journal, June 2003

  • Xu, Wu; Cooper, Emanuel I.; Angell, C. Austen
  • The Journal of Physical Chemistry B, Vol. 107, Issue 25
  • DOI: 10.1021/jp0275894

Electrical relaxation in a glass-forming molten salt
journal, March 1974

  • Howell, F. S.; Bose, R. A.; Macedo, P. B.
  • The Journal of Physical Chemistry, Vol. 78, Issue 6
  • DOI: 10.1021/j100599a016

Heterogeneous dynamics in liquids: fluctuations in space and time
journal, May 2002


Temperature Dependence of Segmental and Terminal Relaxation in Atactic Polypropylene Melts
journal, August 2001

  • Roland, C. M.; Ngai, K. L.; Santangelo, P. G.
  • Macromolecules, Vol. 34, Issue 18
  • DOI: 10.1021/ma002121p

Breakdown of time–temperature superposition: From experiment to the coupling model and beyond
journal, November 2007


Identification of Different Modes of Molecular Motion in Polymers That Cause Thermorheological Complexity
journal, July 1995

  • Ngai, K. L.; Plazek, D. J.
  • Rubber Chemistry and Technology, Vol. 68, Issue 3
  • DOI: 10.5254/1.3538749

Crossover in dynamics of polymeric liquids: Back toTll?
journal, January 2000


Physicochemical Properties and Structures of Room Temperature Ionic Liquids. 2. Variation of Alkyl Chain Length in Imidazolium Cation
journal, April 2005

  • Tokuda, Hiroyuki; Hayamizu, Kikuko; Ishii, Kunikazu
  • The Journal of Physical Chemistry B, Vol. 109, Issue 13
  • DOI: 10.1021/jp044626d

Electrical conductivity and translational diffusion in the 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid
journal, June 2008

  • Sangoro, J.; Iacob, C.; Serghei, A.
  • The Journal of Chemical Physics, Vol. 128, Issue 21
  • DOI: 10.1063/1.2921796

High-temperature dynamics in glass-forming liquids
journal, November 1995


Crossover region of dynamic glass transition: general trends and individual aspects
journal, February 2001


The Temperature Dependence of the Viscoelastic Behavior of Poly(vinyl acetate)
journal, January 1980


Universality of the dynamic crossover in glass-forming liquids: A “magic” relaxation time
journal, March 2003


Universal scaling of charge transport in glass-forming ionic liquids
journal, January 2009

  • Sangoro, J. R.; Iacob, C.; Serghei, A.
  • Phys. Chem. Chem. Phys., Vol. 11, Issue 6
  • DOI: 10.1039/b816106b

CHEMISTRY: Ionic Liquids--Solvents of the Future?
journal, October 2003


Ionic Liquids
journal, December 1999

  • Holbrey, J. D.; Seddon, K. R.
  • Clean Technologies and Environmental Policy, Vol. 1, Issue 4
  • DOI: 10.1007/s100980050036

Self-Diffusion of tris -Naphthylbenzene near the Glass Transition Temperature
journal, January 2003


Applications of functionalized ionic liquids
journal, October 2006

  • Li, Xuehui; Zhao, Dongbin; Fei, Zhaofu
  • Science in China Series B: Chemistry, Vol. 49, Issue 5
  • DOI: 10.1007/s11426-006-2020-y

S PATIALLY H ETEROGENEOUS D YNAMICS IN S UPERCOOLED L IQUIDS
journal, October 2000


The random free‐energy barrier model for ac conduction in disordered solids
journal, September 1988

  • Dyre, Jeppe C.
  • Journal of Applied Physics, Vol. 64, Issue 5
  • DOI: 10.1063/1.341681