Porosity and surface area evolution during weathering of two igneous rocks

Journal Article · Tue Jan 01 00:00:00 EST 2013 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/j.gca.2013.02.012· OSTI ID:1069347

Navarre-Sitchler, Alexis ^[1]; Cole, David ^[2]; Rother, Gernot ^[3]; Jin, Lixin ^[4]; Buss, Heather ^[5]; Brantley, S. L. ^[6]

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1. Colorado School of Mines, Golden
2. Ohio State University
3. ORNL
4. University of Texas, El Paso
5. University of Bristol, UK
6. Pennsylvania State University, University Park, PA

During weathering, rocks release nutrients and storewater vital for growth ofmicrobial and plant life. Thus, the growth of porosity as weathering advances into bedrock is a life-sustaining process for terrestrial ecosystems. Here, we use small-angle and ultra small-angle neutron scattering to show how porosity develops during initial weathering under tropical conditions of two igneous rock compositions, basaltic andesite and quartz diorite. The quartz diorite weathers spheroidally while the basaltic andesite does not. The weathering advance rates of the two systems also differ, perhaps due to this difference in mechanism, from 0.24 to 100 mm kyr1, respectively. The scattering data document how surfaces inside the feldspar-dominated rocks change as weathering advances into the protolith. In the unaltered rocks, neutrons scatter fromtwo types of featureswhose dimensions vary from6 nmto 40 lm: pores and bumps on pore grain surfaces. These features result in scattering data for both unaltered rocks that document multi-fractal behavior: scattering is best described by amass fractal dimension (Dm) and a surface fractal dimension (Ds) for features of length scales greater than and less than 1 lm, respectively. In the basaltic andesite, Dm is approximately 2.9 and Ds is approximately 2.7. The mechanism of solute transport during weathering of this rock is diffusion. Porosity and surface area increase from 1.5%to 8.5%and 3 to 23 m2 g1 respectively in a relatively consistent trend across themm-thick plagioclase reaction front. Across this front, both fractal dimensions decrease, consistentwith development of amoremonodisperse pore networkwith smoother pore surfaces. Both changes are consistent largely with increasing connectivity of pores without significant surface roughening, as expected for transport-limited weathering. In contrast, porosity and surface area increase from 1.3% to 9.5% and 1.5 to 13 m2 g1 respectively across a many cm-thick reaction front in the spheroidally weathering quartz diorite. In that rock, Dm is approximately 2.8 andDs is approximately 2.5 prior to weathering. These two fractals transform during weathering to multiple surface fractals as micro-cracking reduces the size of diffusion-limited subzones of thematrix.Across the reaction front of plagioclase in the quartz diorite, the specific surface area and porosity change very little until the pointwhere the rock disaggregates into saprolite. The different patterns in porosity development of the two rocks are attributed to advective infiltration plus diffusion in the rock that spheroidally fractures versus diffusion-only in the rock that does not. Fracturing apparently diminishes the size of the diffusion-limited parts of the spheroidally weathering rock system to promote infiltration of meteoric fluids, thereforeexplaining the faster weathering advance rate into that rock.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1069347
• Journal Information: Geochimica et Cosmochimica Acta, Vol. 109; ISSN 0016-7037
• Country of Publication: United States
• Language: English